高铁酸盐在饮用水处理中的研究进展

赵晓娜; 李洋; 王鲁; 刘玉蕾; 黄壮松; 马军

doi:10.13205/j.hjgc.202309003

高铁酸盐在饮用水处理中的研究进展

doi: 10.13205/j.hjgc.202309003

哈尔滨工业大学环境学院, 哈尔滨 150090

基金项目:

国家重点研发计划"生物安全理化防护及复杂环境洗消技术与装备"（2021YFC2600303）

详细信息

作者简介:
赵晓娜(1997-),女,研究生,主要研究方向为高铁酸盐氧化技术。

通讯作者:
王鲁(1988-),男,教授,主要研究方向为水处理功能材料制备与应用。wanglu9195@163.com

计量
- 文章访问数: 384
- HTML全文浏览量: 68
- PDF下载量: 23
- 被引次数: 0
出版历程
- 收稿日期: 2023-08-10
- 网络出版日期: 2023-11-15

RESEARCH PROGRESS OF FERRATE IN DRINKING WATER TREATMENT

School of Environment, Harbin Institute of Technology, Harbin 150090, China

摘要

摘要: 随着水生态环境污染问题的加重和人们对饮用水安全的日益重视，亟需研发更高效、低碳、能够适用于复杂污染水体的水处理工艺。作为一种绿色多功能的水处理药剂，高铁酸盐在饮用水处理中具有广阔的应用前景。主要综述了近年来高铁酸盐Fe （Ⅵ）在饮用水处理领域的研究进展，重点介绍了Fe （Ⅵ）的氧化特性和反应机制，以及Fe （Ⅵ）还原生成的铁（氢）氧化物颗粒的吸附特性，阐述了强化Fe （Ⅵ）氧化和吸附效能的调控策略，综合讨论了Fe （Ⅵ）在氧化去除有机污染物、控制消毒副产物生成、去除水中重金属离子、强化混凝和缓解膜污染等方面的处理效果和作用机制，并对Fe （Ⅵ）在饮用水处理中的应用前景和发展趋势进行了展望。
- 高铁酸盐 /
- 饮用水处理 /
- 氧化 /
- 吸附 /
- 膜污染
Abstract: With the aggravation of water pollution and the increasing attention to the safety of drinking water, it is urgent to develop more efficient and low-carbon water treatment processes that could be applied to complex and polluted aquatic environment. As a green and multifunctional agent for water treatment, ferrate has broad application prospects in drinking water treatment. In this paper, the research results of Fe(Ⅵ) in the field of drinking water treatment in recent years were reviewed. The oxidation characteristics and reaction mechanisms of Fe(Ⅵ), as well as the adsorption characteristics of iron oxide/hydroxide particles generated via Fe(Ⅵ) reduction were introduced here. The strategies to enhance the oxidation and adsorption efficiency of Fe(Ⅵ) for pollutants removal were expounded. The efficiency and mechanism of Fe(Ⅵ) to oxidize organic pollutants, to control the formation of disinfection by-products, to remove heavy metal ions in water, to enhance coagulation and to mitigate membrane pollution were discussed. Finally, the application prospect and development trend of Fe(Ⅵ) in drinking water treatment were prospected.
- ferrate /
- drinking water treatment /
- oxidation /
- adsorption /
- membrane fouling

HTML全文

参考文献(66)

[1]	SUN S, LIU Y, MA J, et al. Transformation of substituted anilines by ferrate(Ⅵ):kinetics, pathways, and effect of dissolved organic matter[J]. Chemical Engineering Journal, 2018, 332:245-252.
[2]	LEE Y, VON GUNTEN U. Quantitative structure-activity relationships (QSARs) for the transformation of organic micropollutants during oxidative water treatment[J]. Water Research, 2012, 46(19):6177-6195.
[3]	KAMACHI T, KOUNO T, YOSHIZAWA K. Participation of multioxidants in the pH dependence of the reactivity of ferrate(Ⅵ)[J]. The Journal of Organic Chemistry, 2005, 70(11):4380-4388.
[4]	LEE Y, YOON J, VON GUNTEN U. Kinetics of the oxidation of phenols and phenolic endocrine disruptors during water treatment with ferrate (Fe(Ⅵ))[J]. Environmental Science & Technology, 2005, 39(22):8978-8984.
[5]	KARLESA A, de VERA G A D, DODD M C, et al. Ferrate(Ⅵ) oxidation of β-lactam antibiotics:reaction kinetics, antibacterial activity changes, and transformation products[J]. Environmental Science and Technology, 2014, 48(17):10380-10389.
[6]	SHARMA V K, MISHRA S K, NESNAS N. Oxidation of sulfonamide antimicrobials by ferrate(Ⅵ)[J]. Environmental Science & Technology, 2006, 40(23):7222-7227.
[7]	SUN S, JIANG J, PANG S, et al. Oxidation of theophylline by Ferrate (Ⅵ) and formation of disinfection byproducts during subsequent chlorination[J]. Separation and Purification Technology, 2018, 201:283-290.
[8]	HU L, MARTIN H M, ARCE-BULTED O, et al. Oxidation of carbamazepine by Mn(Ⅶ) and Fe(Ⅵ):reaction kinetics and mechanism[J]. Environmental Science & Technology, 2009, 43(2):509-515.
[9]	ISLAM A, JEON D, RA J, et al. Transformation of microcystin-LR and olefinic compounds by ferrate(Ⅵ):oxidative cleavage of olefinic double bonds as the primary reaction pathway[J]. Water Research, 2018, 141:268-278.
[10]	CHEN J, WU N, XU X, et al. Fe(Ⅵ)-mediated single-electron coupling processes for the removal of chlorophene:a combined experimental and computational Study[J]. Environmental Science & Technology, 2018, 52(21):12592-12601.
[11]	ZHAO X N, HUANG Z S, WANG G J, et al. Highly efficient utilization of ferrate(Ⅵ) oxidation capacity initiated by Mn(Ⅱ) for contaminant oxidation:role of manganese species[J]. Environmental Science & Technology, 2023, 57(6):2527-2537.
[12]	KYRIAKOS M, GEORGE N, K. R A, et al. Oxidation of caffeine by acid-activated ferrate(Ⅵ):effect of ions and natural organic matter[J]. AIChE Journal, 2017, 63(11):4998-5006.
[13]	FENG M, BAUM J C, NESNAS N, et al. Oxidation of sulfonamide antibiotics of six-membered heterocyclic moiety by ferrate(Ⅵ):kinetics and mechanistic insight into SO₂ extrusion[J]. Environmental Science & Technology, 2019, 53(5):2695-2704.
[14]	ZHANG X, FENG M, LUO C, et al. Effect of metal ions on oxidation of micropollutants by ferrate(Ⅵ):enhancing role of Fe(Ⅳ) species[J]. Environmental Science & Technology, 2020, 55(1):623-633.
[15]	ZHU J, YU F, MENG J, et al. Overlooked role of Fe(Ⅳ) and Fe(Ⅴ) in organic contaminant oxidation by Fe(Ⅵ)[J]. Environmental Science & Technology, 2020, 54(15):9702-9710.
[16]	WANG S, DENG Y, SHAO B, et al. Three kinetic patterns for the oxidation of emerging organic contaminants by Fe(Ⅵ):the critical roles of Fe(Ⅴ) and Fe(Ⅳ)[J]. Environmental Science & Technology, 2021, 55(16):11338-11347.
[17]	HUANG Z S, WANG L, LIU Y L, et al. Ferrate self-decomposition in water is also a self-activation process:role of Fe(Ⅴ) species and enhancement with Fe(Ⅲ) in methyl phenyl sulfoxide oxidation by excess ferrate[J]. Water Research, 2021, 197:117094.
[18]	SHARMA V K, ZBORIL R, VARMA R S. Ferrates:Greener oxidants with multimodal action in water treatment technologies[J]. Accounts of Chemical Research, 2015, 48(2):182-191.
[19]	Sharma V K. Oxidation of inorganic contaminants by ferrates(Ⅵ, Ⅴ, and Ⅳ)-kinetics and mechanisms:a review[J]. Journal of Environmental Management, 2011, 92(4):1051-1073.
[20]	FENG M, JINADATHA C, MCDONALD T J, et al. Accelerated oxidation of organic contaminants by ferrate(Ⅵ):the overlooked role of reducing additives[J]. Environmental Science & Technology, 2018, 52(19):11319-11327.
[21]	黄壮松. K₂FeO₄氧化污染物过程高价态铁的转化行为及其强化机制[D]. 哈尔滨:哈尔滨工业大学, 2022.
[22]	SHAO B, DONG H, SUN B, et al. Role of ferrate(Ⅳ) and ferrate(Ⅴ) in activating ferrate(Ⅵ) by calcium sulfite for enhanced oxidation of organic contaminants[J]. Environmental Science & Technology, 2019, 53(2):894-902.
[23]	TIAN S Q, WANG L, LIU Y L, et al. Degradation of organic pollutants by ferrate/biochar:enhanced formation of strong intermediate oxidative iron species[J]. Water Research, 2020, 183:116054.
[24]	PAN B, FENG M, MCDONALD T J, et al. Enhanced ferrate(Ⅵ) oxidation of micropollutants in water by carbonaceous materials:elucidating surface functionality[J]. Chemical Engineering Journal, 2020, 398:125607.
[25]	LUO M, ZHANG H, ZHOU P, et al. Graphite (GP) induced activation of ferrate(Ⅵ) for degradation of micropollutants:the crucial reduction role of carbonyl groups on GP surface[J]. Journal of Hazardous Materials, 2022, 434:128827.
[26]	SUN S F, JIANG J, QIU L P, et al. Activation of ferrate by carbon nanotube for enhanced degradation of bromophenols:kinetics, products, and involvement of Fe(Ⅴ)/Fe(Ⅳ)[J]. Water Research, 2019, 156:1-8.
[27]	LEE Y, KISSNER R, VON GUNTEN U. Reaction of ferrate(Ⅵ) with ABTS and self-decay of ferrate(Ⅵ):kinetics and mechanisms[J]. Environmental Science & Technology, 2014, 48(9):5154-5162.
[28]	LUO M, ZHOU H, ZHOU P, et al. Insights into the role of in-situ and ex-situ hydrogen peroxide for enhanced ferrate(Ⅵ) towards oxidation of organic contaminants[J]. Water Research, 2021, 203:117548.
[29]	WU S, LI H, LI X, et al. Performances and mechanisms of efficient degradation of atrazine using peroxymonosulfate and ferrate as oxidants[J]. Chemical Engineering Journal, 2018, 353:533-541.
[30]	韩琦. 臭氧和高铁酸盐氧化降解水中四溴双酚A的效能与机制[D]. 深圳:哈尔滨工业大学(深圳), 2018.
[31]	HE H, LIU Y, WANG L, et al. Novel activated system of ferrate oxidation on organic substances degradation:Fe(Ⅵ) regeneration or Fe(Ⅵ) reduction[J]. Separation and Purification Technology, 2023, 304:122322.
[32]	LUO M, ZHANG H, ZHOU P, et al. Efficient activation of ferrate(Ⅵ) by colloid manganese dioxide:comprehensive elucidation of the surface-promoted mechanism[J]. Water Research, 2022, 215:118243.
[33]	MANOLI K, LI R, KIM J, et al. Ferrate(Ⅵ)-peracetic acid oxidation process:rapid degradation of pharmaceuticals in water[J]. Chemical Engineering Journal, 2022, 429:132384.
[34]	WANG J, KIM J, ASHLEY D C, et al. Peracetic acid enhances micropollutant degradation by ferrate(Ⅵ) through promotion of electron transfer efficiency[J]. Environmental Science & Technology, 2022, 56(16):11683-11693.
[35]	YANG T, MAI J, CHENG H, et al. UVA-LED-assisted activation of the ferrate(Ⅵ) process for enhanced micropollutant degradation:important role of ferrate(Ⅳ) and ferrate(Ⅴ)[J]. Environmental Science & Technology, 2021, 56(2):1221-1232.
[36]	MAI J, YANG T, MA J. Novel solar-driven ferrate(Ⅵ) activation system for micropollutant degradation:elucidating the role of Fe(Ⅳ) and Fe(Ⅴ)[J]. Journal of Hazardous Materials, 2022, 437:129428.
[37]	GAN W, SHARMA V K, ZHANG X, et al. Investigation of disinfection byproducts formation in ferrate(Ⅵ) pre-oxidation of NOM and its model compounds followed by chlorination[J]. Journal of Hazardous Materials, 2015, 292:197-204.
[38]	JIANG Y, GOODWILL J E, TOBIASON J E, et al. Comparison of ferrate and ozone pre-oxidation on disinfection byproduct formation from chlorination and chloramination[J]. Water Research, 2019, 156:110-124.
[39]	LIU J, LUJAN H, DHUNGANA B, et al. Ferrate(Ⅵ) pretreatment before disinfection:an effective approach to controlling unsaturated and aromatic halo-disinfection byproducts in chlorinated and chloraminated drinking waters[J]. Environment international, 2020, 138:105641.
[40]	HUANG X, DENG Y, LIU S, et al. Formation of bromate during ferrate(Ⅵ) oxidation of bromide in water[J]. Chemosphere, 2016, 155:528-533.
[41]	JIANG Y, GOODWILL J E, TOBIASON J E, et al. Bromide oxidation by ferrate(Ⅵ):the formation of active bromine and bromate[J]. Water Research, 2016, 96:188-197.
[42]	LI G, JIANG J, HE M, et al. Enhancing ferrate oxidation of micropollutants via inducing Fe(Ⅴ)/Fe(Ⅳ) formation needs caution:increased conversion of bromide to bromate[J]. Environmental Science & Technology, 2023.
[43]	DONG H, QIANG Z, RICHARDSON S D. Formation of iodinated disinfection byproducts (I-DBPs) in drinking water:emerging concerns and current issues[J]. Accounts of Chemical Research, 2019, 52(4):896-905.
[44]	SHIN J, VON GUNTEN U, RECKHOW D A, et al. Reactions of ferrate(Ⅵ) with iodide and hypoiodous acid:kinetics, pathways, and implications for the fate of iodine during water treatment[J]. Environmental Science & Technology, 2018, 52(13):7458-7467.
[45]	WANG X, LIU Y, HUANG Z, et al. Rapid oxidation of iodide and hypoiodous acid with ferrate and no formation of iodoform and monoiodoacetic acid in the ferrate/I^-/HA system[J]. Water Research, 2018, 144:592-602.
[46]	WANG X S, LIU Y L, XU S Y, et al. Ferrate oxidation of phenolic compounds in iodine-containing water:control of iodinated aromatic products[J]. Environmental Science & Technology, 2019, 54(3):1827-1836.
[47]	WANG X S, LIU Y L, LI M, et al. Occurrence of iodophenols in aquatic environments and the deiodination of organic iodine with ferrate(Ⅵ)[J]. Environmental Science & Technology, 2022, 56(22):16104-16114.
[48]	YANG T, WANG L, LIU Y, et al. Removal of organoarsenic with ferrate and ferrate resultant nanoparticles:oxidation and adsorption[J]. Environmental Science & Technology, 2018, 52(22):13325-13335.
[49]	GOODWILL J E, JIANG Y, RECKHOW D A, et al. Characterization of particles from ferrate preoxidation[J]. Environmental Science & Technology, 2015, 49(8):4955-4962.
[50]	何世鼎, 李海宁, 王凯凯, 等. 高铁酸盐去除废水中重金属及其他污染物的研究进展[J]. 工业水处理, 2019, 39(5):5-9.
[51]	KRALCHEVSKA R P, PRUCEK R, KOLARIK J, et al. Remarkable efficiency of phosphate removal:ferrate(Ⅵ)-induced in situ sorption on core-shell nanoparticles[J]. Water Research, 2016, 103:83-91.
[52]	LAN B, WANG Y, WANG X, et al. Aqueous arsenic(As) and antimony(Sb) removal by potassium ferrate[J]. Chemical Engineering Journal, 2016, 292:389-397.
[53]	PRUCEK R, TUČEK J, KOLAŘÍK J, et al. Ferrate(Ⅵ)-prompted removal of metals in aqueous media:mechanistic delineation of enhanced efficiency via metal entrenchment in magnetic oxides[J]. Environmental Science & Technology, 2015, 49(4):2319-2327.
[54]	VIKTOR Z, WANG L, MA J. Promotional effect of Mn(Ⅱ)/K₂FeO₄ applying onto Se(Ⅳ) removal[J]. Journal of Hazardous Materials, 2020, 384:121264.
[55]	刘玉蕾. 高铁酸钾的制备及去除水中铊、吲哚和处理污水厂污泥的效果与机理[D]. 哈尔滨:哈尔滨工业大学, 2018.
[56]	MA J, LIU W. Effectiveness of ferrate (Ⅵ) preoxidation in enhancing the coagulation of surface waters[J]. Water Research, 2002, 36(20):4959-4962.
[57]	曲久辉, 林谡, 田宝珍, 等. 高铁酸盐氧化絮凝去除水中腐殖质的研究[J]. 环境科学学报, 1999, (5):510-514.
[58]	李春娟, 马军, 梁涛. 高铁酸盐预氧化对松花江水混凝效果的影响[J]. 环境科学, 2008, (6):1550-1554.
[59]	MA J, LIU W. Effectiveness and mechanism of potassium ferrate(Ⅵ) preoxidation for algae removal by coagulation[J]. Water Research, 2002, 36(4):871-878.
[60]	张忠祥, 宋浩然, 张伟, 等. 高铁酸钾预氧化强化混凝除藻效能及机理研究[J]. 中国给水排水, 2019, 35(15):31-36.
[61]	LIU J, HE K, TANG S, et al. A comparative study of ferrous, ferric and ferrate pretreatment for ceramic membrane fouling alleviation in reclaimed water treatment[J]. Separation and Purification Technology, 2019, 217:118-127.
[62]	LIU J, ZHANG Z, LIU Z, et al. Integration of ferrate (Ⅵ) pretreatment and ceramic membrane reactor for membrane fouling mitigation in reclaimed water treatment[J]. Journal of Membrane Science, 2018, 552:315-325.
[63]	LIU J, ZHANG Z, CHEN Q, et al. Synergistic effect of ferrate (Ⅵ)-ozone integrated pretreatment on the improvement of water quality and fouling alleviation of ceramic UF membrane in reclaimed water treatment[J]. Journal of Membrane Science, 2018, 567:216-227.
[64]	HE H Y, QIU W, LIU Y L, et al. Ferrate preoxidation alleviating membrane fouling through the formation of a hydrophilic prefiltration layer[J]. ACS ES&T Engineering, 2021, 1(11):1576-1586.
[65]	YU W, YANG Y, GRAHAM N. Evaluation of ferrate as a coagulant aid/oxidant pretreatment for mitigating submerged ultrafiltration membrane fouling in drinking water treatment[J]. Chemical Engineering Journal, 2016, 298:234-242.
[66]	HE H Y, QIU W, LIU Y L, et al. Effect of ferrate pre-oxidation on algae-laden water ultrafiltration:attenuating membrane fouling and decreasing formation potential of disinfection byproducts[J]. Water Research, 2021, 190:116690.