高碱度高溴难降解反渗透浓盐水处理工程案例分析

张乐乐; 郭磊; 程志刚; 杨志林; 马悦; 秦鑫; 杨超思

doi:10.13205/j.hjgc.202312029

高碱度高溴难降解反渗透浓盐水处理工程案例分析

doi: 10.13205/j.hjgc.202312029

江苏方洋水务有限公司, 江苏连云港 222000

基金项目:

连云港市科技发展计划SF2129

详细信息

作者简介:
张乐乐(1983-),男,硕士,主要从事工业污水污染控制和运行等研究工作。Zll18205132151@126.com

通讯作者:
郭磊,男,博士,高级工程师,主要从事水污染控制技术固体废物的处理与综合利用等研究工作。gljscn@tom.com

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出版历程
- 收稿日期: 2023-03-08
- 网络出版日期: 2024-03-08

A CASE STUDY ON TREATMENT OF REFRACTORY REVERSE OSMOSIS CONCENTRATED BRINE WITH HIGH ALKALINITY, HIGH BROMINE BY DUAL MEMBRANE TECHNOLOGY

Jiangsu Fangyang Water Co., Ltd., Lianyungang 222000, China

摘要

摘要: 高盐难降解的反渗透浓水能否达标处理,严重制约着中水回用双膜技术的推广应用。以江苏某工业园区高碱度、高溴的反渗透浓盐水达标处理的实际工程为例,探讨了影响工艺出水达标的主要因素,并确定了最佳的工艺运行参数。工程运行结果表明:Br^-浓度和碱度过高时会影响臭氧生化耦合系统的处理效果。适当投加H₂O₂可对Br^-产生掩蔽效应,降低高浓度Br^-对O₃利用效率的影响。H₂O₂投加量为80 mg/L,且控制碱度<2000 mg/L时,臭氧生化耦合系统对COD去除效率可由10%提高到46%,整套系统出水满足达标排放标准。该项目对高碱度、高溴难降解的反渗透浓盐水的达标处理,可为同类废水的处理提供指导和借鉴。
- 双膜技术 /
- 高盐废水 /
- 高溴离子 /
- 工程运行 /
- 臭氧生化耦合工艺
Abstract: The popularization and application of the dual membrane technology for reclaimed water reuse are seriously restricted by whether the high salinity and refractory reverse osmosis concentrated water can be treated to meet the emission standard. In this paper, taking an actual project of high alkalinity and high bromine reverse osmosis concentrated brine treatment in an industrial park in Jiangsu Province as an example, the main factors affecting the effluent quality were discussed, and the best process operation parameters were determined. The project operation results showed that the treatment effect of the ozone biochemical coupling system will be affected, when Br^- concentration and alkalinity were too high. Properly adding hydrogen peroxide can provide a masking effect on bromine ions and reduce the impact of high-concentration bromine ions on ozone utilization efficiency. When the dosage of hydrogen peroxide was 80 mg/L and the alkalinity was controlled less than 2000 mg/L, the COD removal efficiency of the ozone biochemical coupling system increased from 10% to 46%, and the effluent of the whole system met the emission standard. The treatment of RO-concentrated brine in this project can provide guidance and reference for the treatment of similar wastewater.
- dual membrane technology /
- high salinity brine /
- bromine ion /
- project operation /
- ozone biochemical coupling system

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参考文献(12)

[1]	CHEN X T, WANG Z L, SHE J, et al. Reflections on optimizing operation and maintenance of sewage treatment plant in urban industrial park[J]. Environmental Study and Monitoring,2019,32(3):28-31.
[2]	ZENG H Y. An upgrading and reconstructing project case of treatment facilities for landfill leachate[J]. Industrial Water Treatment,2021,41(3):120-124.
[3]	YUAN Y C, LIU J D, GAO B, et al. Ozone direct oxidation pretreatment and catalytic oxidation post-treatment coupled with ABMBR for landfill leachate treatment[J]. Science of the Total Environment,2021,794:148557.
[4]	杨建宇,张瑞玲,陈林林,等. 微纳米气泡复合高级氧化技术降解污染物研究进展[J].2022,48(3):25-29.
[5]	梁杰,周五端,等.废水中存在双氧水时如何准确测试化学需氧量[J]. 广州化工, 2020,48(2):98-100.
[6]	PAŹDZIOR K, BILIŃSKA L, LEDAKOWICZ S. A review of the existing and emerging technologies in the combination of AOPs and biological processes in industrial textile wastewater treatment[J]. Chemical Engineering Journal,2019,376:120597.
[7]	ZHANG Z Y, AI H Y, FU M L, et al. A new insight into catalytic ozonation of ammonia by MgO/CO₃O4 composite: the effects, reaction kinetics and mechanism[J]. Chemical Engineering Journal,2021,418:129461.
[8]	曹国民,盛梅,钟晨,等.工业废水中溴离子对COD测定的影响[J].中国给水排水,2007,23(20):85-88.
[9]	俞潇婷,张家辉,潘循皙,等. 水溶液中臭氧和溴离子的反应研究[J]. 2012,33(9):3139-3143.
[10]	VON GUNTEN U. Ozonation of drinking water: Parr Ⅰ. Oxidation kinetics and product formation[J]. Water Research,2003,37(7): 1443-1467.
[11]	张惠琼,郭玲. 碳酸钠和碳酸氢钠混合碱滴定曲线变化规律[J].海南大学学报(自然科学版),1992,10(4): 77-80.
[12]	LARSON R A, ZEPP R G. Reactivity of the carbonate radical with aniline derivatives[J]. Environmental Toxicology and Chemistry, 1988, 7(4):265-274.