Abstract: At present, large-scale environmental NIMBY facilities have been strongly resisted by the public due to their potential environmental pollution. Considering the correlation between factors influencing NIMBY facility location and residents' rejection of NIMBY facilities in terms of spatial distance, a two-stage location optimal model was constructed based on GIS and multi-objective decision-making theory. In the first stage, a comprehensive evaluation index system including geographic information factors was established, and the influence relationship between indicators was determined by the DEMATEL method to calculate the weight of the indicators. Then, GIS technology was used to superimpose geographical layers to obtain alternative areas. In the second stage, the concept of a multi-valued neutrosophic set was introduced to evaluate the alternative areas, and the expert weight calculation method based on the deviation measure was proposed. The interactive multi-criteria decision method (TODIM) based on the prospect theory was extended to the probabilistic multi-valued intelligent cluster decision-making environment, and then the candidate regions were ranked. Finally, a waste-to-energy project in Beijing was taken as an example, to verify the feasibility and reliability of the model, which provides a powerful reference for the decision-making of large-scale environmental NIMBY facilities in urban planning and layout.