石油烃污染土壤生物修复的强化增溶剂研究

丁宁; 左世伟; 张瑞波; 王朝辉; 李克文; 尚尔顺

doi:10.13205/j.hjgc.202401023

石油烃污染土壤生物修复的强化增溶剂研究

doi: 10.13205/j.hjgc.202401023

中石化炼化工程(集团)股份有限公司洛阳技术研发中心, 河南洛阳 471003

基金项目:

中石化科技开发项目“土壤中石油烃污染强化增溶-微生物修复工程技术开发”(21129A290)

详细信息

通讯作者:
丁宁(1994-),男,博士研究生,工程师,主要研究方向为土壤地下水修复。dingning.segr@sinopec.com

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出版历程
- 收稿日期: 2022-12-01
- 网络出版日期: 2024-04-29

SOLUBILIZER DESIGN FOR INTENSIFYING REMEDIATION OF SOIL WITH PETROLEUM HYDROCARBON POLLUTANTS

Sinopec Engineering Group Luoyang R&D Center of Technologies, Luoyang 471003, China

摘要

摘要: 石油烃是一种典型的石化场地特征污染物,具有较强的人体健康和生态系统毒性。在各类修复技术中,原位生物修复技术扰动小、成本低、安全性好,适合在役场地污染土壤修复,但该类技术存在修复周期长、去除效率低等问题。针对石油烃污染土壤生物修复技术存在的制约问题,制备了4种用于强化石油烃污染物微生物降解的新型增溶剂,其临界胶束浓度均为100~120 mg/kg,表面张力约为30 mN/m。淋洗试验的条件下,LAS-1、LIS-1、LAS-2 3种增溶剂均能将27000 mg/kg的石油烃含量降低至4500 mg/kg以下,污染物溶出效果主要取决于增溶剂与污染土壤的用量比。微生物-增溶试验中,增溶剂强化效果明显,淋洗处理方式与增溶处理效果一致,对提高增溶剂性能评价效率有着良好的借鉴意义。
- 土壤修复 /
- 石油烃 /
- 增溶剂 /
- 临界胶束浓度 /
- 生物修复
Abstract: Several remediation technologies have been exploited and developed to remove petroleum hydrocarbons, a typical pollutant in the petrochemical industry. Bio-remediation has been considered an appropriate one to treat the in-service sites for its advantages in difficulty, cost, and security. Nevertheless, the application of this technology was still restricted by tedious periods and limited efficiency. Thus, 4 kinds of solubilizers were designed and tested in this paper. To all solubilizers, the critical micelle concentration(CMC) was determined within 100~120 mg/kg and the corresponding surface tension was around 30 mN/m. In a typical soil-flushing process, the total petroleum hydrocarbons(TPHs) could be decreased from 27000 mg/kg to 4500 mg/kg or less by LIS-1, LAS-1, and LIS-2, and the TPH removal was proved to depend mainly on the ratio of solubilizers to the polluted soil. The intensification of the solubilizer was confirmed by the micro-biological degradation process, and the results were proved consistent with that of the soil-flushing process. Further, such consistency could help reduce the design period of more new types of solubilizers and improve the development efficiency of soil solubilization technology.
- soil remediation /
- petroleum hydrocarbons /
- solubilizer /
- critical micelle concentration(CMC) /
- bio-remediation

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参考文献(22)

[1]	马强,林爱军,马薇,等.土壤中总石油烃污染(TPH)的微生物降解与修复研究进展[J].生态毒理学报,2008,3(1):1-8.
[2]	李洪梅,郜玉环,江丽华,等.不同浓度石油烃对油菜产量、土壤中石油烃残留量及土壤微生物的影响[J].中国农学通报,2010(17):382-385.
[3]	孙艺萍,魏巍,赵敏.石油烃类污染土壤的微生物修复技术[J],东北林业大学学报,2009(10):63-66.
[4]	PAWLIK M,CANIA B,THIJS S,et al.Hydrocarbon degradation potential and plant growth-promoting activity of culturable endophytic bacteria of Lotus corniculatus and Oenothera biennis from a long-term polluted site[J].Environmental Science and Pollution Research,2017,24(24):19640-19652.
[5]	潘云飞,唐正,彭欣怡,等.石油烃污染土壤微生物修复技术研究现状及进展[J].化工进展,2021,40(8):4562-4572.
[6]	RAJU M N,SCALVENZI L,VENKATESWARLU K.Microbial degradation of total petroleum hydrocarbons in crude oil:a field-scale study at the low-land rainforest of Ecuador[J].Environmental Technology,2017,38(17):2543-2550.
[7]	陈俊华,祝红,单晖峰,等.表面活性剂强化好氧生物修复PAHs污染土壤效果研究[J].环境工程,2020,38(5):185-190.
[8]	郭伟,何孟常,杨志峰.土壤/沉积物中石油烃微生物降解研究综述[J].矿物岩石地球化学通报,2007,26(3):276-283.
[9]	TALVENMAKI H,LALLILLA N,SURVO S,et al.Fenton’s reaction-based chemical oxidation in suboptimal conditions can lead to mobilization of oil hydrocarbons but also contribute to the total removal of volatile compounds[J].Environmental science and pollution research international,2019,26(33):34670-34684.
[10]	李援,王亭,王岽,等.石油烃污染土壤微生物修复促进技术[J].化工环保,2018,38(3):349-352.
[11]	王世杰,王翔,卢桂兰,等.低温微生物修复石油烃类污染土壤研究进展[J].应用生态学报,2011,22(4):1082-1088.
[12]	ZHANG S,MAO G,CRITTENDEN J,et al.Groundwater remediation from the past to the future:a bibliometric analysis[J].Water Research,2017,119:114-125.
[13]	柳晓东,余天飞,艾加敏,等.石油污染对土壤微生物群落影响及石油降解菌的筛选鉴定[J].环境工程,2022,40(7):61-68.
[14]	ZHANG P,LIU Y,LI Z,et al.Sorption and desorption characteristics of anionic surfactants to soil sediments[J].Chemosphere,2018(211):1183-1192.
[15]	丁明山,刘京煊,孙楠,等.退役井场老化油污土壤的生物强化修复技术[J].环境工程,2022,40(5):159-165.
[16]	BOURDEL G,ROY-BOLDUC A,ST-ARNAUD M,et al.Concentration of petroleum-hydrocarbon contamination shapes fungal endophytic community structure in plant roots[J].Frontiers in Microbiology,2016,217:643-656.
[17]	DATTA P,TIWARI P,PANDEY L M.Oil washing proficiency of biosurfactant produced by isolated Bacillus tequilensis MK 729017 from Assam reservoir soil[J].Journal of Petroleum Science and Engineering,2020,195:107612-107624.
[18]	KAUSTUYMANI P,RUPSHIKHA P,KALITA M C,et al.Characterization of biosurfactant produced during degradation of hydrocarbons using crude oil as sole source of carbon[J].Frontiers in Microbiology,2017,8:279-285.
[19]	史作然,单广波,闫松,等.生物质修复石油污染土壤的研究进展[J].当代化工,2016,45(5):992-994.
[20]	陈思莉,易仲源,王骥,等.淋洗-抽提技术修复柴油污染土壤及地下水案例分析[J].环境工程,2020,38(1):178-182.
[21]	王永剑,单广波,徐佰青,等.表面活性剂在石油烃污染土壤修复中的应用研究进展[J].当代化工,2021,50(6):1425-1430.
[22]	赵东维.生物表面活性剂产生菌对石油的降解及对石油烃的增溶作用研究[D].青岛:中国海洋大学,2014.