中国科学引文数据库（CSCD）来源期刊
中国科技核心期刊
环境科学领域高质量科技期刊分级目录T2级期刊
RCCSE中国核心学术期刊
美国化学文摘社（CAS）数据库 收录期刊
日本JST China 收录期刊
世界期刊影响力指数（WJCI）报告 收录期刊

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

缺陷Zr基金属有机框架材料的制备、表征及其对四环素的吸附性能研究

黄继明,  刘润清,  吴思展,  秦航道,  陈 静

downloadPDF
文章导航 > 环境工程  > 2024 >  42(3): 33-40
向虹霖, 刘力, 梁国宾, 张焕伟, 李聪明, 周畅, 韩思宇, 蒋建国. 有机垃圾水解固相残渣制备RDF及性能优化[J]. 环境工程, 2021, 39(3): 189-194,147. doi: 10.13205/j.hjgc.202103027
引用本文: 黄继明, 刘润清, 吴思展, 秦航道, 陈 静. 缺陷Zr基金属有机框架材料的制备、表征及其对四环素的吸附性能研究[J]. 环境工程, 2024, 42(3): 33-40. doi: 10.13205/j.hjgc.202403004
shu
XIANG Hong-lin, LIU Li, LIANG Guo-bin, ZHANG Huan-wei, LI Cong-ming, ZHOU Chang, HAN Si-yu, JIANG Jian-guo. PREPARATION OF RDF BY HYDROLYSIS RESIDUES FROM ORGANIC WASTE AND PROPERTIES OPTIMIZATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 189-194,147. doi: 10.13205/j.hjgc.202103027
Citation: HUANG Jiming, LIU Runqing, WU Sizhan, QIN Hangdao, CHEN Jing. PREPARATION AND CHARACTERIZATION OF DEFECTIVE Zr-BASED METAL-ORGANIC FRAMEWORKS AND THEIR ADSORPTION PROPERTIES FOR TETRACYCLINE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(3): 33-40. doi: 10.13205/j.hjgc.202403004
shu

缺陷Zr基金属有机框架材料的制备、表征及其对四环素的吸附性能研究

doi: 10.13205/j.hjgc.202403004

  • 铜仁学院 材料与化学工程学院, 贵州 铜仁 554300

基金项目: 

铜仁学院博士启动基金(trxyDH2202,trxyDH1506)

详细信息
    作者简介:

    黄继明(1986-),男,博士,副教授,主要研究方向为环境修复材料与技术。jim_huang@foxmail.com

    通讯作者:

    黄继明(1986-),男,博士,副教授,主要研究方向为环境修复材料与技术。jim_huang@foxmail.com

PREPARATION AND CHARACTERIZATION OF DEFECTIVE Zr-BASED METAL-ORGANIC FRAMEWORKS AND THEIR ADSORPTION PROPERTIES FOR TETRACYCLINE

  • School of Material and Chemical Engineering, Tongren Unversity, Tongren 554300, China

摘要

    摘要
  • 摘要: 吸附具有成本低、能耗小、操作方便和环境友好等优点,在污水净化领域具有广泛应用潜力。通过简单的溶剂热法制备了缺陷Zr基金属有机框架(UiO-66-NH2)吸附剂,并将其用于去除废水中四环素。利用X射线衍射仪(XRD)、场发射扫描电子显微镜(FESEM)、傅立叶变换红外光谱(FT-IR)、氮气吸附-脱附和X射线光电子能谱等手段对吸附剂进行表征。为获得吸附剂去除废水中四环素最佳条件,以四环素的吸附量为响应值,在单因素实验基础上,采用Box-Behnken设计(BBD)响应曲面法(RSM)考察吸附剂投加量、溶液pH值、四环素初始浓度以及吸附时间等因素相互作用和影响。结果表明,经实验修正后的最佳吸附条件:吸附剂投加量为10 mg,pH=3.80,四环素初始浓度为27 mg/L,吸附时间为3 h;此条件下,吸附剂对四环素的吸附量可达71.85 mg/g。此外,再生实验表明,经过5次循环吸附后,吸附剂仍具有较强的吸附能力(68.33 mg/g),是一种相对稳定的吸附材料。
    Abstract: Adsorption has the potential to be broadly applied in the field of sewage purification due to advantages such as low costs, less energy consumption, ease of operation and environmental friendliness. In this work, Zr-based metal-organic frameworks (UiO-66-NH2) with defects were successfully prepared by a facile solvothermal method, which was used to removal tetracycline from wastewater. Defective UiO-66-NH2 was characterized by X-ray diffraction (XRD), field emission electron microscope (FESEM), Fourier transform infrared (FT-IR), nitrogen adsorption-desorption and X-ray photoelectron spectroscopy. In order to achieve optimum conditions of tetracycline from aqueous solutions,based on single-factor tests, response surface methodology (RSM) and Box-Behnken design (BBD) were employed to examine the interaction of factors and optimize the adsorption operation parameters, including adsorbent dose, the initial concentration of tetracyclines, pH and contact time. The optimum conditions of maximum adsorption (71.85 mg/g) were found as follows: 10 mg of adsorbent dosage, initial tetracycline concentration of 27 mg/L, pH=3.8 and adsorption time of 3 h. In addition, regeneration experiments showed that the adsorption efficiency of tetracycline after five adsorption-desorption cycles with good uptake efficiency (68.33 mg/g) and UiO-66-NH2 exhibited quite a good cyclic stability.
    • HTML全文
    • 参考文献(20)
  • [1] 王丹, 隋倩, 赵文涛, 等. 中国地表水环境中药物和个人护理品的研究进展[J]. 科学通报, 2014, 59(9):743-751.
    [2] WANG Z, KOIRALA B, HERNANDEZ Y, et al. A naturally inspired antibiotic to target multidrug-resistant pathogens[J]. Nature, 2022, 601(7894):606-611.
    [3] ROJAS S, HORCAJADA P. Metal-organic frameworks for the removal of emerging organic contaminants in water[J]. Chem Rev, 2020, 120(16):8378-8415.
    [4] KANDIAH M, NILSEN MH, USSEGLIO S, et al. Synthesis and stability of tagged UiO-66 Zr-MOFs[J]. Chem Mater, 2010, 22(24):6632-6640.
    [5] QIN M, SHI Y, LU D, et al. High-performance Hf/Ti-doped defective Zr-MOFs for cefoperazone adsorption:behavior and mechanisms[J]. Appl Surf Sci, 2022, 595:153494.
    [6] 李莉, 张赛, 何强, 等. 响应面法在试验设计与优化中的应用[J]. 实验室研究与探索, 2015, 34(8):41-45.
    [7] WITEK-KROWIAK A, CHOJNACKA K, PODSTAWCZYK D, et al. Application of response surface methodology and artificial neural network methods in modelling and optimization of biosorption process[J]. Bioresour Technol, 2014, 160:150-160.
    [8] CLARK C A, HECK K N, POWELL C D, et al. Highly defective UiO-66 materials for the adsorptive removal of perfluorooctanesulfonate[J]. ACS Sustainable Chem Eng, 2019, 7(7):6619-6628.
    [9] SHEN L, LIANG S, WU W, et al. Multifunctional NH2-mediated zirconium metal-organic framework as an efficient visible-light-driven photocatalyst for selective oxidation of alcohols and reduction of aqueous Cr(Ⅵ)[J]. Dalton Trans, 2013, 42(37):13649-13657.
    [10] HE X, DENG F, SHEN T, et al. Exceptional adsorption of arsenic by zirconium metal-organic frameworks:engineering exploration and mechanism insight[J]. J Colloid Interface Sci, 2019, 539:223-234.
    [11] SARKER M, SONG J Y, JHUNG S H. Carboxylic-acid-functionalized UiO-66-NH2:a promising adsorbent for both aqueous and non-aqueous-phase adsorptions[J]. Chem Eng J, 2018, 331:124-131.
    [12] HUANG J, XUE P, WANG S, et al. Fabrication of zirconium-based metal-organic frameworks@tungsten trioxide (UiO-66-NH2@WO3) heterostructure on carbon cloth for efficient photocatalytic removal of tetracycline antibiotic under visible light[J]. J Colloid Interface Sci, 2022, 606:1509-1523.
    [13] LIANG Q, CUI S, LIU C, et al. Construction of CdS@UiO-66-NH2 core-shell nanorods for enhanced photocatalytic activity with excellent photostability[J]. J Colloid Interface Sci, 2018, 524:379-387.
    [14] LU X, SHAO Y, GAO N, et al. Adsorption and removal of clofibric acid and diclofenac from water with MIEX resin[J]. Chemosphere, 2016, 161:400-411.
    [15] LIANG X, CHI J, YANG Z. The influence of the functional group on activated carbon for acetone adsorption property by molecular simulation study[J]. Microporous Mesoporous Mater, 2018, 262:77-88.
    [16] 刘希, 张宇峰, 罗平. 改性花生壳对四环素类抗生素的吸附特性研究[J]. 环境污染与防治, 2013, 35(5):35-39

    ,44.
    [17] KIM H G, CHOI K, LEE K, et al. Controlling the structural robustness of zirconium-based metal organic frameworks for efficient adsorption on tetracycline antibiotics[J]. Water, 2021, 13(13):1869.
    [18] KANG J K, KIM Y G, LEE S C, et al. Artificial neural network and response surface methodology modeling for diclofenac removal by quaternized mesoporous silica SBA-15 in aqueous solutions[J]. Microporous Mesoporous Mater, 2021, 328:111497.
    [19] DALVAND A, NABIZADEH R, REZA GANJALI M, et al. Modeling of reactive Blue 19 azo dye removal from colored textile wastewater using L-arginine-functionalized Fe3O4 nanoparticles:optimization, reusability, kinetic and equilibrium studies[J]. J Magn Magn Mater, 2016, 404:179-189.
    [20] YANG Y, LI X, GU Y, et al. Adsorption property of fluoride in water by metal organic framework:optimization of the process by response surface methodology technique[J]. Surf Interfaces, 2022, 28:101649.
    • 相关文章
    • 施引文献

  • 期刊类型引用(2)

    1. 乔欢，贾文飞. 基于一维河网模型的崇明岛水环境容量计算. 绿色科技. 2024(10): 127-131+142 . 百度学术
    2. 伏凤艳. 平洲水道流量监测结果及污染来源初步分析. 皮革制作与环保科技. 2024(21): 132-134+137 . 百度学术

    其他类型引用(0)

    • 资源附件(0)
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  128
  • HTML全文浏览量:  24
  • PDF下载量:  4
  • 被引次数: 2
出版历程
  • 收稿日期:  2022-11-07
  • 网络出版日期:  2024-05-31

目录

摘要
HTML全文
    参考文献(20)
    相关文章
    施引文献
    资源附件(0)

    /

    返回文章
    返回

    期刊在线

    作者中心

    友情链接

    版权所有 ©《工业建筑》杂志社有限公司 京ICP备11033253号-1

    本系统由北京仁和汇智信息技术有限公司 设计开发   百度统计