磷石膏基稳定材料性能劣化后污染物释放及环境风险评价

李龙媛; 吴钦楠; 凌海波; 王琪; 赵小蓉; 黄绪泉

doi:10.13205/j.hjgc.202403020

磷石膏基稳定材料性能劣化后污染物释放及环境风险评价

doi: 10.13205/j.hjgc.202403020

李龙媛¹,
吴钦楠^2,3,
凌海波¹,
王琪¹,
赵小蓉^2,3,4,5,
黄绪泉^2,3,4,5, ,

1. 湖北省生态环境科学研究院, 武汉 430072;
2. 三峡库区生态环境教育部工程研究中心, 湖北宜昌 443002;
3. 三峡大学水利与环境学院,湖北宜昌 443002;
4. 固体废物处置与资源化利用宜昌市重点实验室, 湖北宜昌 443002;
5. 湖北省磷石膏资源化综合利用企校联合创新中心, 湖北宜昌 443002

基金项目:

宜昌市自然科学研究项目(A21-3-003)

三峡库区生态环境教育部工程研究中心开放基金课题(KF2022-11)

宜昌市长江生态环境保护技术与方案研究(2019-LHYJ-01-0208-25)

详细信息

作者简介:
李龙媛(1988-),女,工程师,主要研究方向为环境监测。2092200914@qq.com

通讯作者:
黄绪泉(1975-),男,副教授,主要研究方向为固体废物处置与资源化。huangxuquan@126.com

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- 文章访问数: 54
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- 被引次数: 0
出版历程
- 收稿日期: 2023-02-23
- 网络出版日期: 2024-05-31

ENVIRONMENTAL RISK ASSESSMENT OF APPLICATION AND POLLUTANT RELEASE OF PHOSPHOGYPSUM-BASED STABILIZED MATERIALS AFTER DEGRADATION

LI Longyuan¹,
WU Qinnan^2,3,
LING Haibo¹,
WANG Qi¹,
ZHAO Xiaorong^2,3,4,5,
HUANG Xuquan^{2,3,4,5
, ,}

1. Hubei Provincial Academy of Eco-Environmental Sciences, Wuhan 430072, China;
2. Research Center of Eco-environment in Three Gorges Reservoir Region, Ministry of Education, China Three Gorges University, Yichang 443002, China;
3. College of Hydraulic & Environmental Engineering, China Three Gorges University, Yichang 443002, China;
4. Yichang Key Laboratory of Solid Waste Disposal and Resource Utilization, Yichang 443002, China;
5. Hubei Province College-enterprise Cooperation Innovation Center for Comprehensive Utilization of Phosphogypsum, Yichang 443002, China

摘要

摘要: 通过研究磷石膏基稳定材料在酸雨淋溶、淡水浸泡、碳化和冻融等极端情况下性能劣化后污染物浸出和现场路段主要环境敏感点污染物检出情况,评价其可能的环境风险。实验室劣化模拟试验分析表明:所有性能劣化试验浸出液中TP均满足GB 3838—2002《地表水环境质量标准》Ⅳ类水质标准;重金属含量始终低于GB 3838—2002中Ⅰ类水质标准;在整个试验周期内,pH均优于普通水泥稳定材料;氟含量除了在碳化劣化之外,其他条件劣化后浸出液均满足GB/T 14848—2017《地下水质量标准》的Ⅳ类或GB 5084—2021《农田灌溉水质标准》。现场试验路段环境敏感点污染物检测结果表明:周边环境中氟化物浓度显著降低,土壤和周边地表水中TP及重金属浓度呈无规则统计规律,试验路段环境中TP及重金属浓度与磷石膏基稳定材料之间不存在明显的关联关系。因此,磷石膏基稳定材料应做好配方设计,科学管理施工过程,定期进行适当养护,才能在道路上推广应用时保持环境污染风险可控。
- 磷石膏 /
- 稳定材料 /
- 劣化 /
- 污染物释放 /
- 环境风险评价
Abstract: The possible environmental risks were evaluated by studying the pollutants leaching of phosphogypsum-based stabilized materials after degradation in extreme conditions, including acid rain leaching, immersion in freshwater, carbonization, and freeze-thawing, and the distribution of pollutants in the main environmentally sensitive points of the site road sections. The results of degradation simulation experiments in the laboratory showed that the total phosphorus in the leachate of all the performance degradation tests could reach the quality standard of Class Ⅳ of Environmental Quality Standards for Surface Water (GB 3838—2002). In the whole test period, the pH value of leaching from phosphogypsum-based stabilized materials was always better than that from cement-stabilized material and the heavy metal content was always better than that of Class Ⅰ in GB 3838—2002. The fluoride ion concentration of leaching was up to the quality standards of Class Ⅳ of Standard for Groundwater Quality (GB/T 14848—2017) or Standard for Irrigation Water Quality (GB 5084—2021) except for that of the leaching after degradation of carbonization. The analysis of the testing road section showed that the concentration of fluoride in the surrounding environment was significantly reduced, but the total phosphorus and heavy metal concentrations in the soil and surrounding surface water showed no statistical rules, all of which indicated the uncertain relationship between total phosphorus and heavy metal concentrations in the environment and phosphogypsum-based stabilized materials. Therefore, for phosphogypsum based stabilized materials, optimizing the formula design, scientifically managing the construction process, and appropriate maintenance can control the environmental pollution risk when being applied on roads.
- phosphogypsum /
- stabilized materials /
- degradation /
- pollutant release /
- environmental risk assessment

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参考文献(15)

[1]	LIU S, WU F H, QU G F, et al. Preparation of high-performance lightweight materials based on the phosphogypsum-inorganic material system[J]. Sustainable Chemistry and Pharmacy, 2023, 30:100901.
[2]	曹建新, 陈前林, 刘毅, 等. 磷石膏中杂质的形态及水溶性磷对水泥物理性能的影响[J]. 环境工程, 2001,19(5):40-43 ,4.
[3]	张厚记, 宗炜, 郑武西, 等. 工业固废磷石膏复合稳定基层材料研究[J]. 武汉理工大学学报, 2021, 43(12):7-12.
[4]	HENG L, FANG X, BIN L, et al. Investigation on mechanical properties of excess-sulfate phosphogypsum slag cement:from experiments to molecular dynamics simulation[J]. Construction and Building Materials, 2022, 315:125685.
[5]	赵德强, 张昺榴, 朱文尚. 道路基层复合胶凝材料的性能调控[J]. 建筑材料学报, 2020, 23(5):1137-1143.
[6]	DING J W, SHI M L, LIU W Z, et al. Failure of roadway subbase Induced by overuse of phosphogypsum[J]. Journal of Performance of Constructed Facilities, 2019, 33(2):04019013.
[7]	DING J W, SHI M L, LIU W Z. In situ stabilization of problematic mixtures in a failed roadway subbase[J]. Journal of Performance of Constructed Facilities, 2017, 31(3):1-7.
[8]	HUONG T T N, VIET Q D, LANH S H, et al. Utilization phosphogypsum as a construction material for road base:a case study in Vietnam[J]. Innovative Infrastructure Solutions, 2022, 7(1):88.
[9]	MESKINI S, REMMAL T, EJJAOUANI H, et al. Formulation and optimization of a phosphogypsum-fly ash-lime composite for road construction:a statistical mixture design approach[J]. Construction and Building Materials, 2022, 315:125786.
[10]	尧俊凯, 叶阳升, 王鹏程, 等. 硫酸盐侵蚀水泥改良路基段上拱研究[J]. 岩土工程学报, 2019, 41(4):782-788.
[11]	李北星, 钱兴. 王凯. 酸雨-冻融耦合侵蚀作用下混凝土性能劣化规律[J]. 硅酸盐通报, 2019, 38(11):3559-3564.
[12]	宿晓萍, 王清. 复合盐浸-冻融-干湿多因素作用下的混凝土腐蚀破坏[J]. 吉林大学学报(工学版), 2015, 45(1):112-120.
[13]	葛勇, 杨文萃, 袁杰, 等. 硫酸盐溶液中混凝土抗冻融干湿循环性能[J]. 东南大学学报(自然科学版), 2006(增刊2):234-237.
[14]	梁贺之, 陈伟, 杨贺. 盐冻作用下高钛重矿渣混凝土耐久性试验研究[J]. 钢铁钒钛, 2022, 43(4):100-106.
[15]	张又弛, 黄杨华, 邓晟宁,等. 降雨对磷基材料修复镉铅污染土壤稳定性的影响研究[J]. 环境污染与防治, 2023, 45(3):285-291 ,299.