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高锰酸钾氧化氨基三亚甲基膦酸的效能

彭娟娟 刘少敏 朱敬林

彭娟娟, 刘少敏, 朱敬林. 高锰酸钾氧化氨基三亚甲基膦酸的效能[J]. 环境工程, 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016
引用本文: 彭娟娟, 刘少敏, 朱敬林. 高锰酸钾氧化氨基三亚甲基膦酸的效能[J]. 环境工程, 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016
PENG Juanjuan, LIU Shaomin, ZHU Jinglin. OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016
Citation: PENG Juanjuan, LIU Shaomin, ZHU Jinglin. OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016

高锰酸钾氧化氨基三亚甲基膦酸的效能

doi: 10.13205/j.hjgc.202404016
基金项目: 

安徽省自然科学基金项目(2208085QB63)

安徽理工大学高层次引进人才科研启动基金(2021yjrc04)

安徽省高校科学研究项目(KJ2021A0442)

详细信息
    作者简介:

    彭娟娟(1999-),女,硕士,主要从事水资源与水处理等方面的研究。3134461553@qq.com

    通讯作者:

    刘少敏(1972-),男,博士,教授,主要从事水资源与水处理等方面的研究。shmliu@aust.edu.cn

OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE

  • 摘要: 高锰酸钾(KMnO4)能有效降解水中有机污染物,但其氧化有机膦酸过程尚不明确。以氨基三亚甲基膦酸(NTMP)为例,采用自由基捕获实验和电子顺磁共振波谱(EPR)探究其在KMnO4体系下降解的主要活性氧化物种,并考察了溶液化学性质(如pH、共存物质、实际水体等)对KMnO4氧化降解NTMP的影响。结果表明:KMnO4直接氧化是NTMP降解的主要途径,且NTMP降解受pH影响较大。当pH=5.0时,KMnO4氧化NTMP的效果最佳,其中51.4% NTMP被氧化生成PO3-4,远高于UV/H2O2和UV/过硫酸钾(PDS)体系。水体中共存物质(SO2-4、NO-3、HCO-3和腐植酸)对NTMP的降解抑制作用较小。此外,在实际水体中KMnO4对NTMP仍有较高的降解效率,且其选择性优于自由基体系。研究结果可为实际废水中有机膦酸的高效去除提供重要参考。
  • [1] WANG S, ZHANG B L, SHAN C, et al. Occurrence and transformation of phosphonates in textile dyeing wastewater along full-scale combined treatment processes[J].Water Research,2020,184:116173.
    [2] MANGHI M C, MASIOL M, CALZAVARA R, et al. The use of phosphonates in agriculture. Chemical, biological properties and legislative issues[J].Chemosphere,2021,283:131187.
    [3] WANG Z, CHEN G D, PATTON S, et al. Degradation of nitrilotris-methylenephosphonic acid (NTMP) antiscalant via persulfate photolysis: implications on desalination concentrate treatment[J].Water Research,2019,159:30-37.
    [4] ROTT E, MINKE R, STEINMETZ H, et al. Removal of phosphorus from phosphonate-loaded industrial wastewaters via precipitation/flocculation[J].Journal of Water Process Engineering,2017,17:188-196.
    [5] HUANG N, XU Z B, WANG W L, et al. Ozonation of phosphonate antiscalant l-hydroxyethane-1,1-diphosphonic acid in reverse osmosis concentrate: kinetics, phosphorus transformation, and anti-precipitation property changes[J].Separation and Purification Technology,2022,297:121385.
    [6] WANG X X, ZHANG T Y, DAO G H, et al. Assessment and mechanisms of microalgae growth inhibition by phosphonates: effects of intrinsic toxicity and complexation[J].Water Research,2020,186:116333.
    [7] VELKI M, MEYER-ALERT H, SEILER T B, et al. Enzymatic activity and gene expression changes in zebrafish embryos and larvae exposed to pesticides diazinon and diuron[J].Aquatic Toxicology,2017,193:187-200.
    [8] SARAILOO M, AFSHARI S, ASGHARIAZAR V, et al. Cognitive impairment and neurodegenerative diseases development associated with organophosphate pesticides exposure: a review study[J].Neurotoxicity Research,2022,40(5):1624-1643.
    [9] 孟秀柔,宋青梅,王飞,等.草铵膦和草甘膦在水环境中的行为和毒性效应研究进展[J].生态毒理学报,2021,16(3):144-154.
    [10] 高瑾,熊六凤,阮记明,等.草甘膦的水环境行为及其对水生生物毒性的研究进展[J].生态毒理学报,2022,17(3):422-433.
    [11] 刘帅,王腾,王孜晔,等.草甘膦的水生生物水质基准及其生态风险评估[J].生态毒理学报,2023,18(1):335-350.
    [12] 王婷庭,刘敏,崔桂榕,等.五种改性纳米纤维素吸附剂的制备及除磷性能比较[J].化工进展,2017,36(11):4279-4285.
    [13] 吕景花,袁振祥,李婉婷,等.混凝沉淀法处理含油清洗废水中磷的实验研究[J].工业水处理,2019,39(5):37-41.
    [14] 胡昊,潘顺龙,聂溪,等.CoFe2O4的制备及其对有机膦酸的去除性能研究[J].环境科学学报,2022,42(8):156-165.
    [15] 刘丽娅,刘丹丹,莫华荣,等.城镇污水生物脱氮除磷研究进展[J].净水技术,2023,42(3):49-59.
    [16] ROTT E, MINKE R, BALI U, et al. Removal of phosphonates from industrial wastewater with UV/FeⅡ, fenton and UV/Fenton treatment[J].Water Research,2017,122:345-354.
    [17] XU Z B, WANG W L, HUANG N, et al. 2-Phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) degradation by ozonation: kinetics, phosphorus transformation, anti-precipitation property changes and phosphorus removal[J].Water Research,2019,148:334-343.
    [18] MUTKE X A M, TAVICHAIYUTH K, DREES F, et al. Oxidation of the nitrogen-free phosphonate antiscalants HEDP and PBTC in reverse osmosis concentrates: reaction kinetics and degradation rate[J].Water Research,2023,233:119571.
    [19] SUN S H, SHAN C, YANG Z C, et al. Self-enhanced selective oxidation of phosphonate into phosphate by Cu(Ⅱ)/H2O2: performance, mechanism, and validation[J].Environmental Science and Technology,2022,56(1):634-641.
    [20] ZHU J L, WANG S, LI H C, et al. Degradation of phosphonates in Co(Ⅱ)/peroxymonosulfate process: performance and mechanism[J].Water Research,2021,202:117397.
    [21] 陈菊香,代彩琼.强化高锰酸钾氧化技术去除铜绿微囊藻的研究进展[J].广东化工,2022,49(14):67-68.
    [22] CAO W M, WU N N, QU R J, et al. Oxidation of benzophenone-3 in aqueous solution by potassium permanganate: kinetics, degradation products, reaction pathways, and toxicity assessment[J].Environmental Science and Pollution Research,2021,28(24):31301-31311.
    [23] 柯水洲,章彩霞,袁辉洲.高锰酸钾去除水中甲硫醚的效能及动力学研究[J].安全与环境学报,2017,17(3):1099-1105.
    [24] ZHUANG J G, WANG S Y, TAN Y, et al. Degradation of sulfadimethoxine by permanganate in aquatic environment: influence factors, intermediate products and theoretical study[J].Science of The Total Environment,2019,671:705-713.
    [25] CHEN J, QU R J, PAN X X, et al. Oxidative degradation of triclosan by potassium permanganate: kinetics, degradation products, reaction mechanism, and toxicity evaluation[J].Water Research,2016,103:215-223.
    [26] XU K, BEN W W, LING W C, et al. Impact of humic acid on the degradation of levofloxacin by aqueous permanganate: kinetics and mechanism[J].Water Research,2017,123:67-74.
    [27] CAO W M, YU Y, WEI J Y, et al. KMnO4-mediated reactions for hexachlorophene in aqueous solutions: direct oxidation, self-coupling, and cross-coupling[J].Chemosphere,2020,259:127422.
    [28] PENG J L, ZHOU P, ZHOU H Y, et al. Insights into the electron-transfer mechanism of permanganate activation by graphite for enhanced oxidation of sulfamethoxazole[J].Environmental Science & Technology,2021,55(13):9189-9198.
    [29] WANG L H, JIANG J, PANG S Y, et al. Oxidation of bisphenol A by nonradical activation of peroxymonosulfate in the presence of amorphous manganese dioxide[J].Chemical Engineering Journal,2018,352:1004-1013.
    [30] WANG L H, JIANG J, PANG S Y, et al. Further insights into the combination of permanganate and peroxymonosulfate as an advanced oxidation process for destruction of aqueous organic contaminants[J].Chemosphere,2019,228:602-610.
    [31] LI H C, YUAN N, QIAN J S, et al. Mn2O3 as an electron shuttle between peroxymonosulfate and organic pollutants: the dominant role of surface reactive Mn(Ⅳ) species[J].Environmental Science & Technology,2022,56(7):4498-4506.
    [32] 张静,张宏龙,王定祥,等.强化高锰酸钾氧化体系中自由基的产生与利用研究进展[J].环境化学,2021,40(2):487-496.
    [33] TAYLOR J E, GREEN R et al. Permanganate peroxidation of cyclohexene. Ⅲ. Hydroxide ion and salt effect studies[J].Canadian Journal of Chemistry,1985,62(10):3777-3780.
    [34] XIE Y W, XU R Y, LI R, et al. Adsorbable organic halogens formed during treatment of Cl--containing wastewater by sulfate and hydroxyl radical-based advanced oxidation processes[J].Chemical Engineering Journal,2020,389:124457.
    [35] 颉亚玮,徐冉云,丁伟,等.含氯离子苯酚废水高级氧化过程AOX生成研究[J].环境工程,2022,40(5):1-8.
    [36] 杨庆云,李青松,陈泽铭,等.UV/PMS、UV/PDS、UV/SPC工艺降解尼泊金甲酯[J].化工学报,2023,74(3):1322-1331.
    [37] GU D M, GUO C S, FENG Q Y, et al. Degradation of ketamine and methamphetamine by the UV/H2O2 system: kinetics, mechanisms and comparison[J].Water,2020,12(11):2999.
    [38] 杜振齐,王永磊,田立平,等.UV/H2O2工艺降解饮用水中有机微污染物研究进展[J].山东建筑大学学报,2019,34(4):50-57.
    [39] 许芬,张如锋,沈芷璇,等.UV/H2O2降解美罗培南的影响因素及毒性研究[J].环境科学学报,2019,39(12):4031-4038.
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  • 收稿日期:  2023-04-26
  • 网络出版日期:  2024-06-01

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