PROMOTING DEWATERABILITY OF WASTE ACTIVATED SLUDGE BY ACTIVATED CARBON ACTIVATED PERSULFATE OXIDATION
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摘要: 采用废弃活性炭和K2S2O8对污泥进行预处理,发现不同配比的活性炭和K2S2O8可以破坏污泥结构,增强污泥脱水性能。当污泥中加入1.00 g/g VS活性炭和1.60 mmol/g VS S2O82-,反应20 min后进行抽滤实验,污泥经过60,120,180,240,300 s抽滤,失水量分别为(4.95±0.05),(6.65±0.15),(7.45±0.05),(7.90±0.10),(7.90±0.01)g;相比原始污泥,在相同时刻下,失水量分别上升了32.00%、20.91%、19.20%、17.04%和16.18%;抽滤后泥饼含水率为(62.63±1.09)%,相较原始污泥泥饼,含水率下降了19.97%。说明活性炭和K2S2O8可以大大提高污泥脱水性能,加快污泥脱水速率,降低泥饼含水率。在工业应用中,活性炭和K2S2O8具有成本低廉的优势,用于污泥脱水可降低污泥预处理费用,节约成本。同时,高效的污泥处理可降低污泥综合处理以及后续处置成本。Abstract: Waste-activated carbon and K2S2O8 were used to pretreat sludge, and different proportions of activated carbon and K2S2O8 could destroy the sludge structure and enhance the sludge dewatering performance. When 1.00 g/g VS activated carbon and 1.60 mmol/g VS S2O82- were added into the sludge, the sludge was filtered for 60, 120, 180, 240, 300 s after reaction for 20 min. The water loss was (4.95±0.05), (6.65±0.15), (7.45±0.05), (7.90±0.10), (7.90±0.01) g, respectively. Compared with the original sludge, the water loss at the same time increased by 32.00%, 20.91%, 19.20%, 17.04%, and 16.18%, respectively. The moisture content of the sludge cake was (62.63±1.09)%, which was 19.97% lower than that of the original sludge cake. These results showed that activated carbon and K2S2O8 can greatly improve the sludge dewatering performance, accelerate the sludge dewatering rate, and reduce the moisture content of the mud cake. In industrial applications, activated carbon and K2S2O8 have the advantage of low cost. When used for sludge dewatering, they can reduce sludge pretreatment costs, and an efficient sludge treatment effect can reduce sludge comprehensive treatment and subsequent disposal costs.
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Key words:
- sludge dewatering /
- activated carbon /
- persulfate /
- moisture content
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[1] ZHEN G Y, LU X Q, SU L H, et al. Unraveling the catalyzing behaviors of different iron species (Fe2+ vs. Fe0) in activating persulfate-based oxidation process with implications to waste activated sludge dewaterability[J]. Water Research,2018,134:101-114. [2] ZHEN G Y, LU X Q, ZHAO Y C, et al. Enhanced dewaterability of sewage sludge in the presence of Fe(Ⅱ)-activated persulfate oxidation[J]. Bioresource Technology,2012,116: 259-265. [3] LIU H, FANG H. Extraction of extracellular polymeric substances (EPS) of sludges[J]. Journal of Biotechnology,2002,95: 249-256. [4] NEYENS E, BAEYENS J, DEWIL R, et al. Advanced sludge treatment affects extracellular polymeric substances to improve activated sludge dewatering[J]. Journal of Hazardous Materials,2004,106:83-92. [5] YUAN H P, YAN X F, YANG C F, et al. Enhancement of waste activated sludge dewaterability by electro-chemical pretreatment[J]. Journal of Hazardous Materials,2011,187(1/2/3): 82-88. [6] MURUGESAN K, RAVINDRAN B, SELVAM A, et al. Enhanced dewaterability of anaerobically digested sewage sludge using Acidithiobacillus ferrooxidans culture as sludge conditioner[J]. Bioresource Technology,2014,169: 374-379. [7] WANG L P, LI A M, CHANG Y Z. Relationship between enhanced dewaterability and structural properties of hydrothermal sludge after hydrothermal treatment of excess sludge[J]. Water Research,2017,112: 72-82. [8] ZHEN G Y, LU X Q, WANG B Y, et al. Enhanced dewatering characteristics of waste activated sludge with Fenton pretreatment: effectiveness and statistical optimization[J].Frontiers of Environmental Science & Engineering,2014,8(2): 267-276. [9] ZHEN G Y, LU X Q, WANG B Y, et al. Synergetic pretreatment of waste activated sludge by Fe(Ⅱ)-activated persulfate oxidation under mild temperature for enhanced dewaterability[J].Bioresource Technology,2012,124: 29-36. [10] OH S Y, KANG S G, KIM D W, et al. Degradation of 2,4-dinitrotoluene by persulfate activated with iron sulfides[J]. Chemical Engineering Journal,2011,172(2/3):641-646. [11] WANG J H, TAN Y J, PAN Y, et al. Altering extracellular biopolymers and water distribution of waste activated sludge by Fe(Ⅱ) persulfate oxidation with natural zeolite and polyelectrolyte as skeleton builders for positive feedbacks to dewaterability[J]. ACS Sustainable Chemistry & Engineering,2019,7:16549-16559. [12] LIU H, YANG J K, ZHU N R, et al. A comprehensive insight into the combined effects of Fenton’s reagent and skeleton builders on sludge deep dewatering performance[J]. Journal of Hazardous Materials, 2013,258/259: 144-150.
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