电化学阻抗谱技术表征纳滤和反渗透膜污染及膜传质过程研究与应用进展

孔琬婷; 李雪松; 王志伟

doi:10.13205/j.hjgc.202409005

电化学阻抗谱技术表征纳滤和反渗透膜污染及膜传质过程研究与应用进展

doi: 10.13205/j.hjgc.202409005

孔琬婷¹,
李雪松^1,2,3,
王志伟^1,2,3, ,

1. 同济大学环境科学与工程学院, 上海 200092;
2. 同济大学污染控制与资源化研究国家重点实验室, 上海 200092;
3. 同济大学先进膜技术研究中心, 上海 200092

基金项目:

国家自然科学基金项目“污水处理与资源化”(51925806)

详细信息

作者简介:
孔琬婷(2000-),女,硕士研究生,主要研究方向为膜传质过程的电化学表征。wtkong@tongji.edu.cn

通讯作者:
王志伟(1980-),男,教授,博士生导师,主要研究方向为膜法污水处理与资源化技术。zwwang@tongji.edu.cn

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出版历程
- 收稿日期: 2024-07-04
- 网络出版日期: 2024-12-02

RECENT ADVANCES IN ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY TECHNOLOGY FOR CHARACTERIZATION OF FOULING AND MASS TRANSFER PROCESSES ON NANOFILTRATION AND REVERSE OSMOSIS MEMBRANES

KONG Wanting¹,
LI Xuesong^1,2,3,
WANG Zhiwei^{1,2,3
, ,}

1. School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China;
2. State key Laboratory of Pollution Control and Resource Research, Tongji University, Shanghai 200092, China;
3. Advanced Membrane Technology Center, Tongji University, Shanghai 200092, China

摘要

摘要: 近年来,纳滤(NF)和反渗透(RO)技术在饮用水净化、污水处理及脱盐等领域得到了广泛应用。然而,膜污染和低传质分离效率是制约NF/RO技术发展的主要挑战。解决这些问题需要借助灵敏、精确的表征分析技术深入解析其内在机制,电化学阻抗谱(electrochemical impedance spectroscopy,EIS)作为一种高灵敏的分析检测技术,能够实现实时、原位表征,在膜污染和膜分离传质过程研究中展现出独特的优势。系统综述了EIS技术在表征分析NF/RO膜污染和传质过程中的研究与应用进展,介绍了EIS的工作原理、等效电路模型,总结了其在膜污染类型识别、膜污染在线监测以及膜分离传质过程表征等方面的研究动态,最后讨论了EIS在膜分离领域应用中存在的局限性,并展望了EIS技术的未来发展方向。
- 电化学阻抗谱 /
- 纳滤 /
- 反渗透 /
- 膜污染 /
- 膜传质 /
- 表征技术
Abstract: In recent years, nanofiltration (NF) and reverse osmosis (RO) technologies have been widely utilized in drinking water purification, wastewater treatment, and desalination. However, membrane fouling and low mass transfer separation efficiency remain major challenges limiting their development. Addressing these issues requires sensitive and precise characterization techniques to probe the underlying mechanisms. Electrochemical impedance spectroscopy (EIS), as a highly sensitive analysis technique, enables real-time, in-situ characterization. It offers unique advantages in the study of membrane fouling and mass transfer processes. This review systematically summarizes the research and application advances of EIS in characterizing the fouling and mass transfer processes in NF and RO membranes. The working principles and equivalent circuit models are first introduced. The research advancements in fouling type identification, online monitoring, and mass transfer characterization in membrane separation are also reviewed. Finally, the limitations of EIS application in the membrane field are discussed and future development directions are also outlined.
- electrochemical impedance spectroscopy /
- NF /
- RO /
- membrane fouling /
- membrane mass transfer /
- characterization technology

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