以黄铁矿为电子供体的自养反硝化技术研究现状与展望

丁沛; 任之琪; 马佳莹; 褚华强; 周雪飞; 张亚雷

doi:10.13205/j.hjgc.202412013

以黄铁矿为电子供体的自养反硝化技术研究现状与展望

doi: 10.13205/j.hjgc.202412013

同济大学环境科学与工程学院, 上海 200092

基金项目:

国家重点研发计划"低碳约束下沿长江炼油化工行业废水近零排放技术与示范"(2023YFC3206900)

详细信息

作者简介:
丁沛(1999-),男,硕士研究生,主要研究方向为钢厂焦化废水处理。dingp@tongji.edu.cn

通讯作者:
褚华强(1982-),男,教授,主要研究方向为废水资源化处理技术、膜法水处理技术。chuhuaqiang@tongji.edu.cn

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出版历程
- 收稿日期: 2024-07-15
- 网络出版日期: 2025-01-18

RESEARCH STATUS AND PROSPECT ON AUTOTROPHIC DENITRIFICATION TECHNOLOGY UTILIZING PYRITE AS THE ELECTRON DONOR

College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

摘要

摘要: 黄铁矿(FeS₂)是地球表面最丰富的矿物,是提取硫和制造硫酸的主要矿物原料,也是一种天然的废水处理矿物材料。以其作为电子供体的自养反硝化是一种处理低C/N水的潜力巨大的生物处理技术,具有低成本、无需外加碳源、产泥少、副产物产出少、可与多种反硝化技术耦合等优点。提供了以黄铁矿为电子供体的自养反硝化原理的概述以及包括比表面积、pH、温度、溶解氧、水力停留时间以及有毒物质等因素对黄铁矿自养反硝化效率的影响。并对以黄铁矿自养反硝化为核心的处理工艺及应用现状进行了概述,包括基于黄铁矿自养反硝化的填充床、流化床、人工湿地和生物滤池等处理工艺,黄铁矿自养反硝化与厌氧氨氧化、异养反硝化的耦合技术,以及其在地下水修复与污水深度处理方面的应用。在此基础上,从多个角度讨论了当前应用的局限性,展望该技术的未来发展方向及研究重点。
- 黄铁矿 /
- 自养反硝化 /
- 生物脱氮 /
- 污水处理 /
- 地下水修复
Abstract: Pyrite (FeS₂) is one of the predominant minerals found on the Earth’s surface, commonly used as the fundamental mineral source for sulfur extraction and sulfuric acid production. Additionally, it serves as a natural material for wastewater treatment. Autotrophic denitrification, where pyrite acts as an electron donor, presents a bio-based treatment technology with significant potential for addressing low C/N water conditions. This approach offers advantages such as cost-effectiveness, independence from external carbon sources, reduced sludge generation, and minimal by-product formation. Furthermore, it can be synergistically integrated with various denitrification technologies. This paper provides a comprehensive examination of the principles underlying autotrophic denitrification utilizing pyrite as an electron donor, elucidating the effects of specific surface area, pH, temperature, dissolved oxygen concentration, hydraulic retention time, and the influence of toxic substances on the efficiency of pyrite-based autotrophic denitrification. Moreover, it offers a crucial overview of treatment processes and the current application landscape focused on pyrite-driven autotrophic denitrification. This includes detailed discussions on treatment methodologies such as filled bed, fluidized bed, constructed wetland, and biological filter systems that leverage pyrite autotrophic denitrification. The paper also explores the integration of pyrite autotrophic denitrification with anaerobic ammonia oxidation and heterotrophic denitrification, showcasing its efficacy in groundwater remediation and advanced sewage treatment scenarios. Lastly, the paper outlines prospective directions for advancing this technology, while critically evaluating the limitations of current application and recommending key research priorities from diverse perspectives.
- pyrite /
- autotrophic denitrification /
- biological nitrogen removal /
- wastewater treatment /
- groundwater remediation

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