SELF-CONSISTENT CYCLIC UTILIZATION OF RESIDUAL VALUABLE COMPONENTS IN IRON AND STEEL PROCESS
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摘要: 钢铁流程赋存有丰富的余存有价组元,其来源广泛,成分和组成均十分复杂,必须对其高效资源化利用。基于冶金流程学理论,分析了钢铁流程余存组元的来源、转化及迁移规律,揭示了余存组元无序化与钢铁流程碳污排放的逻辑关系,提出了钢铁流程余存有价组元自洽循环利用的理论观点,即输入一定的治理物质流和能量流(负熵流),促使无序化的余存组元及其携带的余能自洽地回到钢铁主工艺流程,或成为其他工业流程原料进行资源化循环利用。同时,基于钢铁流程物能自洽资源化利用的理论观点,介绍了非金属有机组元、非金属无机组元以及重(碱)金属组元等有价组元自洽循环利用的典型工艺方法和应用案例。Abstract: The steel process contains abundant residual valuable components, which come from a wide range of sources and have a complex composition. It is necessary to utilize these components as resources efficiently. This article is based on the theory of metallurgical processes, analyzes the sources, transformation, and migration laws of residual components in the steel process, reveals the causal relationship between the disorder of residual components and carbon pollution emissions in the steel process, and proposes the theoretical viewpoint of self-consistent recycling of valuable components in the steel process, that is, inputting a certain amount of governance material flow and energy flow (negative entropy flow) to promote the disordered residual components and their carried residual energy to return to the main process of steel, or become raw materials for resource recycling in other industrial processes. At the same time, based on the theoretical viewpoint of self-consistent resource utilization of material energy in the steel process, typical process methods and application cases of self-consistent recycling of valuable components, such as non-metallic organic components, non-metallic inorganic components, and heavy (alkali) metal components are introduced.
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[1] 向郁雪,梁导伦,王晓佳,等. 钢铁冶炼固废与垃圾焚烧飞灰共燃处置过程气相污染物生成特性[J]. 环境工程,2023,41(12):197-205. [2] 王会刚,吴龙,邱桂博,等. 冶金含钾除尘灰中钾资源提取现状综述[J]. 环境工程,2024,42(1):119-125. [3] 郭伟伟,刘杰,高艳甲,等. 有害金属及烧结矿碱度对高炉冶炼的影响[J]. 山西冶金,2024,47(3):135-136. [4] 任可飘, 王静松, 李岩,等. 铊在冶金过程中的迁移和富集[J]. 有色金属科学与工程,2024,15(3):311-321,82. [5] 兰臣臣,张淑会,刘小杰,等. 高炉内氯元素对焦炭高温冶金性能的影响[J]. 太原理工大学学报,2016,47(1):5-10. [6] 林文龙,张玉柱,刘超,等. 烧结烟气污染物治理工艺研究进展[J]. 环境工程,2023,41(6):248-258. [7] 杨大正, 李宇梁, 于丰浩, 等. 热轧油泥处理技术现状及发展趋势[J]. 鞍钢技术,2022(3):6-9,14. [8] 叶恒棣,李谦,魏进超,等. 钢铁炉窑协同处置冶金及市政难处理固废技术路线[J]. 钢铁,2021,56(11):141-147. [9] 张雪凯,贺颖捷,李佳,等. 钢铁含铊高盐固废/废水协同水洗技术研究[J]. 有色金属(冶炼部分),2024(4):87-93. [10] FAN C L, DING C Y, YANG T, et al. Disposal of zinc extraction residues via iron ore sintering process: an innovative resource utilization[J]. Journal of Iron Steel Research International, 2024, 31(7):1636-1645. [11] 沈维民,叶恒棣,张志波,等. 钢铁工业含锌尘泥回转窑处置技术的应用进展[J]. 烧结球团,2024,49(1):11-18. [12] YS/T 1343—2019 锌冶炼用氧化锌富集物[S]. 北京:中国计划出版社,2019. [13] 叶恒棣,李俊杰,倪桂虎,等. 碳基多污染物净化工艺SO2,HCl的迁移及转化规律[J]. 钢铁,2024,59(5):172-184. [14] 李俊杰,魏进超,刘昌齐. 活性炭法多污染物控制技术的工业应用[J]. 烧结球团,2017,42(3):79-85. [15] GB 50427—2015. 高炉炼铁工程设计规范[S]. 北京:中国计划出版社,2015. [16] YE H, LI Q, YU H, et al. Pyrolysis behaviors and residue properties of iron-rich rolling sludge from steel smelting[J]. International Journal of Environmental Research and Public Health, 2022, 19:2152. [17] 姜涛. 烧结球团生产技术手册[M]. 北京: 冶金工业出版社,2014. [18] 叶恒棣,蔡飞翔,丁成义,等. 热解与烧结协同处置富碳有机固废的新工艺[J]. 烧结球团,2022,47(6):49-56.
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