施用硝酸钾和磷酸二氢钾对土壤镉污染钝化修复效应影响

徐奕; 蒋旭; 徐应明

doi:10.13205/j.hjgc.202412027

施用硝酸钾和磷酸二氢钾对土壤镉污染钝化修复效应影响

doi: 10.13205/j.hjgc.202412027

徐奕¹,
蒋旭¹,
徐应明^2, ,

1. 天津市勘察设计院集团有限公司, 天津 300191;
2. 农业农村部环境保护科研监测所, 天津 300191

基金项目:

天津市科技支撑计划项目(14ZCZDSF00004)

天津市农业科技成果转化与推广项目(201404100)

详细信息

作者简介:
徐奕(1994-),女,硕士,主要从事土壤污染调查与修复技术研究。279129258@qq.com

通讯作者:
徐应明(1964-),男,博士,研究员,主要研究方向为土壤重金属污染修复。ymxu1999@126.com

计量
- 文章访问数: 12
- HTML全文浏览量: 2
- PDF下载量: 0
- 被引次数: 0
出版历程
- 收稿日期: 2024-05-21
- 网络出版日期: 2025-01-18

EFFECT OF ADDING KNO₃ AND KH₂PO₄ ON IMMOBILIZATION REMEDIATION OF CADMIUM IN POLLUTED SOIL

XU Yi¹,
JIANG Xu¹,
XU Yingming^{2
, ,}

1. Tianjin Survey and Design Institute Group Co., Ltd., Tianjin 300191, China;
2. Ago-Environmental Protection Institute of Ministry of Agriculture and Rural Affairs, Tianjin 300191, China

摘要

摘要: 钝化修复是土壤镉(Cd)污染常用的修复方式。选取KNO₃(K₁)和KH₂PO₄(K₂)2种钾肥,通过盆栽试验,研究施加不同含量的2种钾肥对海泡石(S)钝化土壤Cd效应的影响。结果表明:与S处理相比,S+K1处理下,土壤有效态Cd含量增加22.58%~29.03%,但KNO₃不同添加量间并无显著差异;S+K₂L和S+K₂M处理时土壤有效态Cd含量增幅达到6.45%~32.26%,其增幅随着KH₂PO₄施加量的增加而降低。与S处理相比,在海泡石钝化处理中施加不同含量KNO₃,土壤有效态Cu、Zn和Mn含量分别增加7.83%~11.98%、0.54%~6.17%和49.13%~63.83%;施加不同含量KH₂PO₄可使土壤中有效态Cu、Zn和Mn含量分别增加8.99%~12.44%、25.20%~31.37%和86.65%~94.58%。与S处理相比,S+K₁处理显著增加模式植物油菜地上部中Cd含量,增加率为31.79%~43.16%(P<0.05),但S+K₂与S处理间无明显差异;此外,在海泡石钝化修复下,添加2种钾肥对油菜地上部Cu、Zn含量同样存在不同程度的影响。该研究结果对Cd污染耕地安全利用中科学施用钾肥提供了参考。
- 土壤 /
- 镉污染 /
- 海泡石 /
- 钝化
Abstract: Immobilization remediation is a commonly used remediation method for soil cadmium pollution, but there is poor research on the effect of fertilization on the immobilization remediation of soil Cd pollution. In this paper, KNO₃ (K₁) and KH₂PO₄ (K₂) were added in Cd polluted soil, and sepiolite was used as an amendment. Through the rape pot experiment, the effects of adding different doses of two potassium fertilizers on the remediation effect of soil Cd pollution under the condition of sepiolite immobilization (S) were studied. The results showed that compared with S treatment, in S+K₁ treatment, the soil available Cd content increased by 22.58% to 29.03%, but there was no significant difference between different doses of KNO₃ added. The soil available Cd content increased by 6.45% to 32.26% in S+K₂L and S+K₂M treatments, but decreased with the increase of KH₂PO₄ addition. Compared with S treatment, the content of available Cu, Zn and Mn in soil increased by 7.83% to 11.98%, 0.54% to 6.17% and 49.13% to 63.83%, respectively, when different doses of KNO₃ were added in sepiolite immobilization treatment. Adding different doses of KH₂PO₄ could increase the contents of available Cu, Zn and Mn in soil by 8.99% to 12.44%, 25.20% to 31.37%, and 86.65% to 94.58%, respectively. Compared with S treatment, S+K₁ treatment significantly increased the cadmium content in rape shoot, with an increased rate of 31.79% to 43.16% (P<0.05), but there was no significant difference between S+K₂ and S treatment. In addition, under the immobilization remediation of sepiolite, the addition of two types of potassium fertilizers also had a significant impact on Cu and Zn content in rape shoots. The research results can provide important references for scientific application of potassium fertilizer in the safe utilization of Cd-polluted farmland.
- soil /
- cadmium pollution /
- sepiolite /
- immobilization

HTML全文

参考文献(27)

[1]	李剑睿,徐应明,林大松,等. 农田重金属污染原位钝化修复研究进展[J]. 生态环境学报,2014,23(4):721-728.
[2]	毛欣宇,翟森茂,姜小三,等. 不同改性生物炭对农田土壤理化性质及铅、镉钝化的影响机制研究[J]. 环境工程,2023,41(2):113-121 ,139.
[3]	GUO G, ZHOU Q, MA L Q. Availability and assessment of fixing additives for the in situ remediation of heavy metal contaminated soils: a review[J]. Environmental Monitoring and Assessment, 2006, 116(3):513-528.
[4]	LIANG X F, HAN J, XU Y M, et al. In situ field-scale remediation of Cd polluted paddy soil using sepiolite and palygorskite[J]. Geoderma, 2014, 235: 9-18.
[5]	CHEN D, YE X Z, ZHANG Q, et al. The effect of sepiolite application on rice Cd uptake:a two-year field study in Southern China[J]. Journal of Environmental Management, 2020, 254: 109788.
[6]	ZHU Y G, SHAW G, NISBET A F, et al. Effect of potassium supply on the uptake of ¹³⁷Cs by spring wheat (Triticum aestivum, cv. Tonic): a lysimeter study[J]. Radiation Environmental. Biophysics, 2000, 39: 283-290.
[7]	ZHAO Z Q, ZHU Y G, LI H Y, et al. Effects of forms and rates of potassium fertilizers on cadmium uptake by two cultivars of spring wheat (Triticum aestivum. L)[J]. Environment International, 2004, 29(7): 973-978.
[8]	邹嘉成,牛莹新,宋付朋,等. 钾肥强化植物间作修复镉锌污染土壤效应研究[J]. 农业环境科学学报,2022,41(2):304-312.
[9]	衣纯真,傅桂平,张福锁,等.不同钾肥对水稻镉吸收和运移的影响[J].中国农业大学学报,1996,1(3): 65-70.
[10]	黄荣, 徐应明, 黄青青, 等. 二种钾肥对海泡石钝化修复镉污染土壤效应影响的研究[J]. 中国生态农业学报,2018,26(8): 1249-1256.
[11]	肖振林,王果,黄瑞卿,等. 酸性土壤中有效态镉提取方法研究[J]. 农业环境科学学报,2008,27(2):795-800.
[12]	OKAZAKI M, KIMURA S D, KIKUCHI T, et al. Suppressive effects of magnesium oxide materials on cadmium uptake and accumulation into rice grains Ⅰ: characteristics of magnesium oxide materials for cadmium sorption[J]. Journal of Hazardous Materials, 2008, 154(1): 294-299.
[13]	SUN Y B, XU Y, XU Y M et al. Reliability and stability of immobilization remediation of Cd polluted soils using sepiolite under pot and field trials[J]. Environmental Pollution, 2016, 208: 739-746.
[14]	王林,徐应明,孙扬,等. 海泡石及其复配材料钝化修复镉污染土壤[J]. 环境工程学报,2010,4(9):2093-2098.
[15]	李翔,杨驰浩,刘晔,等. 钝化剂对农田土壤Cd有效性及不同水稻品种吸收Cd的研究[J]. 环境工程,2021,39(9):211-216.
[16]	王磊,安志装,李虎群,等. 不同钾肥对辣椒品质及镉吸收累积的影响[J]. 山东农业大学学报(自然科学版),2021,52(3):371-376.
[17]	蒋田雨,姜军,徐仁扣,等. 稻草生物质炭对3种可变电荷土壤吸附Cd(Ⅱ)的影响[J]. 农业环境科学学报,2012,31(6):1111-1117.
[18]	徐仁扣,肖双成,赵安珍. 基于Zeta电位的水稻土吸附Pb(Ⅱ)和Cd(Ⅱ)能力的比较[J]. 环境化学,2008,27(6):742-745.
[19]	YIN X L, XU Y M, HUANG R, et al. Remediation mechanisms for Cd-contaminated soil using natural sepiolite at the field scale[J]. Environmental Science: Processes and Impacts, 2017, 19(12): 1563-1570.
[20]	姜军,徐仁扣. 离子强度对三种可变电荷土壤表面电荷和Zeta电位的影响[J]. 土壤,2015,47(2):422-426.
[21]	王碧玲,谢正苗. 磷对铅、锌和镉在土壤固相-液相-植物系统中迁移转化的影响[J]. 环境科学,2008,29(11):3225-3229.
[22]	ZWONITZER J C, PIERZYNSKI G M, HETTIARACHCHI G M.Effects of phosphorus additions on lead, cadmium, and zinc bioavailabilities in a metal contaminated soil[J]. Water Air and Soil Pollution, 2003, 143: 193-209.
[23]	ZHAO Z Q, ZHU Y G, LI H Y, et al. Effects of forms and rates of potassium fertilizers on cadmium uptake by two cultivars of spring wheat(Triticum aestivum L.)[J]. Environment International, 2003, 29: 973-978.
[24]	叶芳芳,崔振岭,陈新平,等. 枸溶性钾肥对铅镉污染土壤芹菜生长及铅镉吸收的影响[J]. 中国农学通报,2015,31(26):133-138.
[25]	王小晶,陈怡,王菲,等. 钾肥对镉污染土壤大白菜品质的效应研究[J]. 农业资源与环境学报,2015,32(1):40-47.
[26]	KIM C G, BELL J N B, POWER S A. Effects of soil cadmium on Pinus sylvestris L. seedlings[J]. Plant and Soil, 2003, 257(2):443-449.
[27]	FLOGEAC K, GUOLLON E, APLINCOURT M. Surface complexation of copper(Ⅱ) on soil particles: EPR and XAFS studies[J]. Environmental Science Technology, 2004, 38: 3098-3103.