可切换低共熔溶剂驱动机制及其在有机废弃物资源化中的应用

朱子乐; 纪富国; 张振亚; 左慧; 罗景阳

doi:10.13205/j.hjgc.202503011

可切换低共熔溶剂驱动机制及其在有机废弃物资源化中的应用

doi: 10.13205/j.hjgc.202503011

朱子乐^1,2,
纪富国^1,2,
张振亚^1,2,
左慧^1,2,
罗景阳^1,2, ,

1. 河海大学浅水湖泊综合治理与资源开发教育部重点实验室, 南京 210098;
2. 河海大学环境学院, 南京 210098

基金项目:

国家自然科学面上基金“胆碱类低共熔溶剂强化污泥厌氧消化效能的构效关系及其物质代谢与菌群行为的偶联机制研究”（52470146）；江苏省省级大学生创新创业训练计划（202410294122Y）

详细信息

作者简介:
朱子乐（2004-），男，本科生，主要研究方向为有机废物的资源化利用。2214040223@hhu.edu.cn

通讯作者:
罗景阳(1989-),男,工学博士,教授,主要研究方向为有毒有害污染物控制理论与技术及有机废物的资源化利用。luojy2016@hhu.

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出版历程
- 收稿日期: 2025-02-10
- 录用日期: 2025-02-26
- 修回日期: 2025-02-24
- 网络出版日期: 2025-06-07
- 刊出日期: 2025-03-01

Driving machanisms of switchable deep eutectic solvents and their application in the organic waste resource utilization

ZHU Zile^1,2,
JI Fuguo^1,2,
ZHANG Zhenya^1,2,
ZUO Hui^1,2,
LUO Jingyang^{1,2
, ,}

1. Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes of the Ministry of Education, Hohai University, Nanjing 210098, China;
2. College of Environment, Hohai University, Nanjing 210098, China

摘要

摘要: 可切换低共熔溶剂（SDES）因其高效分离回收的能力，在有机废弃物资源化处理等领域具有较大的应用潜力。概述了SDES的主要分类（基于不同驱动因子可分为CO₂/N₂驱动型、pH驱动型和温度驱动型）、合成原理和表征手段，阐明了不同SDES基于亲疏水性转变实现切换的驱动机制；分别阐明了3种驱动因子的调控对物质提取分离效果的影响。在此基础上，总结了SDES在果皮、工业废液等有机废弃物资源化处理中的应用现状及优势，并从SDES制备的优化（组成、摩尔比和体积）与辅助技术的结合（如超声辅助）等多角度阐释了提升SDES提取效果的强化策略。最后，针对不同废弃物的SDES提取参数优化确定以及如何提高SDES回收利用等方面进行了展望，可为其在有机废弃物资源化方面的应用研究提供参考。
- 可切换低共熔溶剂 /
- 有机废弃物 /
- 资源化利用 /
- 驱动机制 /
- 强化策略。
Abstract: Switchable deep-eutectic solvents （SDES） have great application potential in the resource recovery and utilization of organic wastes due to their efficient separation and recovery capabilities. The main classifications of SDES （devied into three types， CO₂/N₂-driven， pH-driven and temperature-driven， based on their driving factors）， their synthesis principles and characterization approaches are outlined， and the driving switchable mechanisms of different SDES based on hydrophilic-hydrophobic transition are elucidated. Also， the effects of the driving factors regulation on the extraction and separation of substances are demonstrated. Then the current application status and advantages of SDES in the organic waste treatment， such as fruit peels， industrial waste liquids， etc.， are summarized. Then the enhanced strategies to improve the extraction efficiency of SDES are illustrated from multiple perspectives， including the optimization of SDES preparation （i.e. composition， molar ratio and volume） and the combination of auxiliary technologies （i.e. ultrasound）. Future researches are suggested to focus on the SDES extraction parameters tailored to different categories of organic wastes， and the improvement of SDES recycling efficiency. This work can provide guidance for their large application in the resource recovery and utilization of organic wastes.
- switchable deep eutectic solvents /
- organic wastes /
- resource utilization /
- driving mechanism /
- optimization strategy

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参考文献(39)

[1]	YANG D H，HUA Y，WU B R，et al. Consideration on development of organic solid waste resource treatment and disposal technology under the background of double carbon［J］. Environmental Engineering，2022，40（12）：1-8，36. 杨东海，华煜，武博然，等. 双碳背景下有机固废资源化处理处置技术发展思考［J］. 环境工程，2022，40（12）：1-8，36.
[2]	LI M. Construction of 5-HMF integrated systembased on IL/DES-ATPS catalytic conversionand extraction［D］. Zhenjiang：Jiangsu University，2020. 李墨. 基于IL/DES双水相催化转化及萃取分离5-HMF的集成体系构建［D］. 镇江：江苏大学，2020.
[3]	LI Y H，MA K，FENG C H，et al. Research progress of high concentration organic wastewater treatment technology［J］. Advances in Environmental Protection，2021，11（4）：717-722. 李雁鸿，马凯，冯春晖，等. 高浓度有机废水处理技术研究进展［J］. 环境保护前沿，2021，11（4）：717-722.
[4]	BAI J L，YAN T F，GU J C，et al. Research progress on the properties and applications of deep eutectic solvents［J］. Industrial Catalysis，2024，32（9）：26-32. 白佳乐，燕童凡，谷嘉诚，等. 低共熔溶剂的性质与应用研究进展［J］. 工业催化，2024，32（9）：26-32.
[5]	CAO J，SU E. Hydrophobic deep eutectic solvents：the new generation of green solvents for diversified and colorful applications in green chemistry［J］. Journal of Cleaner Production，2021，314：127965.
[6]	LO C，SEMEREL J，BERG C，et al. Eutectic solvents with tuneable hydrophobicity：Lipid dissolution and recovery［J］. RSC Advances，2021，11（14）：8142-8149.
[7]	ZHANG M，ZHANG Z，GUL Z，et al. Advances of responsive deep eutectic solvents and application in extraction and separation of bioactive compounds［J］. Journal of Separation Science，2023，46（15）：2300098.
[8]	LEE T W，SU Y H，CHEN C. Recovery and repurposing of waste isopropanol with CO₂-switchable deep eutectic solvents［J］. Science of the Total Environment，2023，896：165053.
[9]	LIU F，XUE Z，LAN X，et al. CO₂ switchable deep eutectic solvents for reversible emulsion phase separation［J］. Chemical Communications，2021，57（5）：627-630.
[10]	ZHANG H，ZHAO W，LIU L，et al. Switchable deep eutectic solvents for sustainable extraction of β-carotene from millet［J］. Microchemical Journal，2023，187：108369.
[11]	SALAMAT Q，SOYLAK M. Novel reusable and switchable deep eutectic solvent for extraction and determination of curcumin in water and food samples［J］. Talanta，2024，269：125401.
[12]	DAMIRI S，GHORBANI J，POURETEDAL H R. Temperature-switchable ammonium acetate/diethylene glycol deep eutectic solvent for selective and green separation of cyclotetramethylenetetranitramine（HMX）and cyclotrimethylenetrinitramine（RDX）explosives［J］. Separation Science and Technology，2023，58（4）：682-694.
[13]	YAN X Y，CAI Z H，ZHAO P Q，et al. Application of a novel and green temperature-responsive deep eutectic solvent system to simultaneously extract and separate different polar active phytochemicals from Schisandra chinensis（Turcz.）Baill［J］. Food Research International，2023，165：112541.
[14]	ZHANG J，LI S，YAO L，et al. Responsive switchable deep eutectic solvents：a review［J］. Chinese Chemical Letters，2023，34（5）：107750.
[15]	ULLAH N，HASEEB A，TUZEN M. Application of recently used green solvents in sample preparation techniques：A comprehensive review of existing trends，challenges，and future opportunities［J］. Critical reviews in analytical chemistry，2023：1-20.
[16]	PŁOTKA-WASYLKA J，DE LA GUARDIA M，ANDRUCH V，et al. Deep eutectic solvents vs ionic liquids：Similarities and differences［J］. Microchemical Journal，2020，159：105539.
[17]	CHEN Y，XU F，PANG M，et al. Microwave-assisted hydrodistillation extraction based on microwave-assisted preparation of deep eutectic solvents coupled with GC-MS for analysis of essential oils from clove buds［J］. Sustainable Chemistry and Pharmacy，2022，27：100695.
[18]	LEVER T，HAINES P，ROUQUEROL J，et al. ICTAC nomenclature of thermal analysis（IUPAC Recommendations 2014）［J］. Pure and Applied Chemistry，2014，86（4）：545-553.
[19]	LU Y，WANG X，GU H，et al. Morphological transformation assisted switchable deep eutectic solvents combined with HPLC-DAD for the detection of six UV-filters in surface and bathing waters［J］. Microchemical Journal，2021，169：106626.
[20]	JING J，LI X，ZHANG Y，et al. pH-responsive regulation of a surfactant-free microemulsion based on hydrophobic deep eutectic solvents［J］. Langmuir，2022，38（26）：7898-7905.
[21]	STUPAR A，SEREGELJ V，RIBEIRO B D，et al. Recovery of β-carotene from pumpkin using switchable natural deep eutectic solvents［J］. Ultrasonics Sonochemistry，2021，76：105638.
[22]	BABU B H，VISWANATHAN G，MUNIASAMY R，et al. Sustainable valorization of papaya peels for thrombolytic cysteine protease isolation by ultrasound assisted disruptive liquid phase microextraction with task specific switchable natural deep eutectic solvents［J］. Microchemical Journal，2022，175：107118.
[23]	WAN W，XIONG D，ZHANG Q，et al. Miscible–immiscible transition of deep eutectic solvents in water switched by CO₂［J］. ACS Sustainable Chemistry& Engineering，2019，7（21）：17882-17887.
[24]	ZHANG K，REN S，YANG X，et al. Efficient absorption of low-concentration SO₂ in simulated flue gas by functional deep eutectic solvents based on imidazole and its derivatives［J］. Chemical Engineering Journal，2017，327：128-134.
[25]	YU X，LI M，YAGOUB A E A，et al. Switchable（pH driven）aqueous two-phase systems formed by deep eutectic solvents as integrated platforms for production-separation 5-HMF［J］. Journal of Molecular Liquids，2021，325：115158.
[26]	HOU Q，LI W，ZHEN M，et al. An ionic liquid–organic solvent biphasic system for efficient production of 5-hydroxymethylfurfural from carbohydrates at high concentrations［J］. RSC Advances，2017，7（75）：47288-47296.
[27]	WANG T，GUO Q，YANG H，et al. pH-controlled reversible deep-eutectic solvent based enzyme system for simultaneous extraction and in-situ separation of isoflavones from Pueraria lobata［J］. Separation and Purification Technology，2022，292：120992.
[28]	WANG T，WANG Q，LI P，et al. Temperature-responsive ionic liquids to set up a method for the simultaneous extraction and in situ preconcentration of hydrophilic and lipophilic compounds from medicinal plant matrices［J］. Green Chemistry，2019，21（15）：4133-4142.
[29]	HALL C C，RIVERA C A，LODGE T P. The effect of light penetration depth on the LCST phase behavior of a thermo-and photoresponsive statistical copolymer in an ionic liquid［J］. Journal of Polymer Science Part A：Polymer Chemistry，2019，57（3）：281-287.
[30]	SCHLITTER J. The second law of thermodynamics as a force law［J］. Entropy，2018，20（4）：234.
[31]	YANG W，WANG R，WANG L，et al. Switchable deep eutectic solvents for the extraction of phlorizin and trilobatin from sweet tea（Lithocarpus litseifolius（Hance）Chun）［J］. Separation and Purification Technology，2025，356：129898.
[32]	CAI C，WANG Y，YU W，et al. Temperature-responsive deep eutectic solvents as green and recyclable media for the efficient extraction of polysaccharides from Ganoderma lucidum［J］. Journal of Cleaner Production，2020，274：123047.
[33]	WANG K，WANG Z，ZHANG Y，et al. Liquid-liquid equilibrium for ternary mixture water +（n-propanol/isopropanol）+ cyclohexanone at 298.15 and 308.15 K［J］. Journal of Chemical& Engineering Data，2020，65（1）：233-238.
[34]	CHAIWUT P，PINTATHONG P，RAWDKUEN S. Extraction and three-phase partitioning behavior of proteases from papaya peels［J］. Process Biochemistry，2010，45（7）：1172-1175.
[35]	DOBBERPUHL D，JOHNSON L，MATTSON B. A colorful solvent extraction demonstration for teaching the concept of“like dissolves like”［J］. Journal of Chemical Education，2022，99（9）：3342-3345.
[36]	ZHANG H，ZHAO W，BAI T，et al. Sustainable extraction of polyphenols from millet using switchable deep eutectic solvents［J］. LWT，2022，170：114082.
[37]	SHI Z，LI X，TIAN Y，et al. Hydrophobicity-switchable deep eutectic solvent-based effervescence-assisted dispersive liquid–liquid microextraction with solidification of floating droplets for HPLC determination of anthraquinones in fried Cassiae semen tea infusions［J］. Analytical Methods，2021，13（40）：4739-4746.
[38]	YAO X H，ZHANG D Y，DUAN M H，et al. Preparation and determination of phenolic compounds from Pyrola incarnata Fisch. with a green polyols based-deep eutectic solvent［J］. Separation and Purification Technology，2015，149：116-123.
[39]	HAYYAN A，MJALLI F S，ALNASHEF I M，et al. Glucose-based deep eutectic solvents：Physical properties［J］. Journal of Molecular Liquids，2013，178：137-141.