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循环水冲式厕所黄水水质净化效果研究及处理系统设计

张金宇 沈玉君 王惠惠 贾懿曼 丁京涛 王黎明 李丹阳 周亚文 张爱琴 范盛远

张金宇,沈玉君,王惠惠,等.循环水冲式厕所黄水水质净化效果研究及处理系统设计[J].环境工程,2025,43(4):143-155. doi: 10.13205/j.hjgc.202504014
引用本文: 张金宇,沈玉君,王惠惠,等.循环水冲式厕所黄水水质净化效果研究及处理系统设计[J].环境工程,2025,43(4):143-155. doi: 10.13205/j.hjgc.202504014
ZHANG J Y,SHEN Y J,WANG H H,et al.Purification effect of yellow water in the water-circulating flush toilet and design of the treatment system [J].Environmental Engineering,2025,43(4):143-155. doi: 10.13205/j.hjgc.202504014
Citation: ZHANG J Y,SHEN Y J,WANG H H,et al.Purification effect of yellow water in the water-circulating flush toilet and design of the treatment system [J].Environmental Engineering,2025,43(4):143-155. doi: 10.13205/j.hjgc.202504014

循环水冲式厕所黄水水质净化效果研究及处理系统设计

doi: 10.13205/j.hjgc.202504014
基金项目: 

“双培”项目“我国寒旱区农村卫生厕所及粪污资源化关键技术产品研发与推广应用”(SP202103)

详细信息
    作者简介:

    张金宇(1997—),男,硕士研究生,主要从事农业废弃物资源化利用技术研究。1812164058@qq.com

    通讯作者:

    贾懿曼(1987-),女,高级工程师,主要研究方向为农村生活污水处理及资源化利用技术。jiayimansw@163.com
    王黎明(1967-),女,教授,主要研究方向为废弃物利用理论与技术研究。dljdxy@163.com

    贾懿曼(1987-),女,高级工程师,主要研究方向为农村生活污水处理及资源化利用技术。jiayimansw@163.com
    王黎明(1967-),女,教授,主要研究方向为废弃物利用理论与技术研究。dljdxy@163.com

Purification effect of yellow water in the water-circulating flush toilet and design of the treatment system

  • 摘要: 目前,我国农村常见的厕所类型普遍存在厕所粪污处理技术水平低、资源化利用效果差以及节水技术不足等问题,制约着农村“厕所革命”的顺利推进。基于粪尿分集式水冲厕所,采用填料吸附耦合土壤渗滤的方式处理厕所黄水,选用稻壳生物炭和沸石作为吸附系统的填料,沸石、煤灰渣、玉米芯、铁粒和园土作为土壤渗滤系统的填料,设计不同水力负荷、冲厕水量、干湿比等试验参数,研究其对黄水中氮、磷的吸附效果和水质净化能力,筛选出效果较优参数,并开展长期运行,评估系统运行的稳定性和试验填料更换周期。结果表明,在水力负荷为0.34 m3/(m2·d)、冲厕水量3 L、干湿比2∶1的参数下,处理系统对黄水的养分回收及污染物净化效果最好。在此条件下进行的连续98 d运行试验,系统运行稳定,未出现断流堵塞的情况。总出水TN、TP的平均去除率均大于94%,COD平均浓度为21.57 mg/L,满足ISO 30500 《无下水道厕所安全及性能测试国际标准》出水标准。依照此试验参数,以农村单户家庭应用为基础,对关键部件进行参数设计,并集成开展厕所整体设计,最终形成新型循环水冲式厕所。研究为我国农村黄水就地资源化利用和资源循环型节水厕所技术提供重要参考。
  • 1  黄水处理系统工作原理

    1.  Working principle diagram of the yellow water treatment system

    2  黄水处理系统装置

    2.  Yellow water treatment system devices

    3  进出水TN、NH4+-N、TP与COD浓度变化

    3.  Variations of TN, NH4+-N, TP and COD concentrations in inlet and outlet water

    4  循环水冲式厕所的工作原理

    4.  How recirculating flush toilets work

    5  黄水储存箱 mm

    5.  Diagram of the yellow water storage tank

    6  一级养分回收单元 mm

    6.  Primary nutrient recovery unit

    7  二级污染物去除单元 mm

    7.  Secondary pollutant removal unit

    8  净水水箱 mm

    8.  Pure water tank

    9  循环水冲式厕所整体示意

    1—厕屋 2—粪尿分集式便器 3—厕纸(架) 4—纸篓 5—上水管6—粪便导管 7—黄水下水管 8—粪便堆肥箱 9—黄水储存箱 10—蠕动泵 11—一级养分回收单元 12—二级污染物去除单元 13—净水出水管 14—紫外线杀菌 15—净水水箱 16—洗手台 17—镜子

    9.  Overall schematic diagram of a water-recirculating flush toilet

    1  黄水的初始水质

    1.   Initial properties of yellow water

    pHρ(TN)/(mg/L)ρ(TP)/(mg/L)ρ(NH4+-N)/(mg/L)ρ(COD)/(mg/L)
    8.415185.54937.75319.310660
    下载: 导出CSV

    2  填料的基本性质

    2.   Basic properties of the fillers

    填料粒径/mm密度/(g/cm3
    稻壳生物炭2~40.40
    沸石2~41.40
    煤灰渣1~31.20
    玉米芯1~32.70
    铁粒27.85
    园土0.5~1.01.30
    下载: 导出CSV

    3  工艺参数及数值

    3.   Process parameters and values

    水力负荷/[m³/(m2·d)]冲厕水量/L干湿比
    0.071.51∶1
    0.143.02∶1
    0.276.03∶1
    0.341∶2
    下载: 导出CSV

    4  填料对NH4+-N和TP的吸附动力学参数

    4.   Kinetic parameters of the adsorption of NH4+-N and TP by fillers

    水质指标填料一级动力学模型二级动力学模型
    qe /(mg·g-1)K1R12qe/(mg·g-1)K2R22
    NH4+-N稻壳生物炭1.6590.6430.9982.0441.1770.995
    园土1.6730.7050.9991.8382.1260.998
    沸石1.7720.7910.9992.0422.0100.996
    煤灰渣1.6400.7270.9992.1643.2430.999
    TP稻壳生物炭1.6580.6600.9981.6516.9240.996
    园土1.6730.6870.9991.6672.0400.998
    沸石1.7710.7970.9981.7483.8760.998
    煤灰渣1.6410.7290.9981.6355.0040.998
    下载: 导出CSV

    5  填料对NH4+-N和TP的吸附等温拟合参数

    5.   Isothermal fitting parameters for the adsorption of NH4+-N and TP by fillers

    水质指标填料Langmuir模型Freundlich模型
    qmKLR2nKFR2
    NH4+-N稻壳生物炭1583.6956.6610.9805.1760.6700.964
    园土993.2439.2210.9906.5240.6150.982
    沸石2510.2773.3240.9912.5510.7920.994
    煤灰渣2111.8303.2260.9822.2120.7850.991
    TP稻壳生物炭259.6440.0020.9162.8760.6140.865
    园土299.2990.0010.9431.5350.7050.909
    沸石319.4500.0020.9581.8690.6890.924
    煤灰渣273.8970.0020.9772.9370.6180.941
    下载: 导出CSV

    6  不同水力负荷下进出水平均浓度及养分去除率

    6.   Inlet and outlet water mean concentrations and nutrient removal rates under different hydraulic loads

    污染物水力负荷/[m³/(m2·d)]平均进水浓度/(mg/L)平均一级出水浓度/(mg/L)平均总出水浓度/(mg/L)一级去除率/%二级去除率/%总去除率/%
    TN0.07444.29181.6211.7959.1293.5197.35
    0.14193.1718.1356.5290.6195.92
    0.27217.8120.4750.9890.6095.39
    0.34245.7724.1444.6890.1794.55
    NH4+-N0.07195.9954.833.9472.0292.8297.99
    0.1474.817.0861.8390.5396.39
    0.2790.289.2353.9489.7895.29
    0.34109.0411.9844.3789.0293.89
    TP0.07284.59105.902.6762.7993.5099.06
    0.14115.393.9259.4595.0598.62
    0.27126.536.2655.5496.6097.80
    0.34126.118.2155.0897.4897.11
    COD0.07397.92130.55.6867.2095.9598.57
    0.14156.112.1460.7792.2296.95
    0.2716718.5058.0388.9395.35
    0.34181.9929.5054.2683.7992.59
    下载: 导出CSV

    7  不同冲厕水量下进出水平均浓度及养分去除率

    7.   Inlet and outlet water mean concentrations and nutrient removal rates under different flushing water volume

    指 标冲厕水量/L平均进水浓度/(mg/L)平均一级出水浓度/(mg/L)平均总出水浓度/(mg/L)一级去除率/%二级去除率/%总去除率/%
    TN1.5719.98395.55185.2845.0629.2174.27
    3.0450.87252.8561.5343.9275.6786.35
    6.0352.38138.0626.0860.8281.1192.60
    NH4+-N1.5613.26225.5655.2363.3575.5590.99
    3.0368.52164.8529.7155.2781.9891.94
    6.0187.6180.357.6157.1790.5395.94
    TP1.5319.87153.2231.4252.1079.4990.18
    3.0177.5683.1611.5953.1686.0693.47
    6.082.8740.544.2551.0789.5294.87
    COD1.5870.77347.10144.6760.1458.3283.39
    3.0447.80149.8391.5066.5438.9379.57
    6.0207.90110.5647.7746.8256.8077.02
    下载: 导出CSV

    8  不同干湿比下进出水平均浓度及养分去除率

    8.   Inlet and outlet water mean concentrations and nutrient removal rates at different wet/dry ratios

    指 标干湿比平均进水浓度/(mg/L)平均一级出水浓度/(mg/L)平均总出水浓度/(mg/L)一级去除率/%二级去除率/%总去除率/%
    TN1∶2396.92250.2333.3136.9686.6991.61
    1∶1224.5136.2843.4383.8490.86
    2∶1224.9623.0943.5189.7394.18
    3∶1227.9333.6542.5885.2491.52
    NH4+-N1∶2178.3779.5612.5255.3984.2592.98
    1∶181.7811.3254.1586.1693.65
    2∶174.279.1758.3687.6694.86
    3∶183.5113.2253.1884.1792.59
    TP1∶2280.60152.7411.0545.5792.7796.06
    1∶1150.8110.2546.2693.2196.35
    2∶1135.944.9951.5596.3398.22
    3∶1137.199.1651.1193.3396.74
    COD1∶2459.50262.50105.8042.8759.7076.97
    1∶1245.80103.2046.5158.0177.54
    2∶1242.3093.9047.2761.2579.56
    3∶1237.20104.9048.3855.7877.17
    下载: 导出CSV

    9  各级养分处理效果及回收率

    9.   Nutrient treatment recovery rates at various levels

    指标一级养分回收率/%二级污染物去除率/%总去除率/%填料初始氮含量/(mg/g)处理后氮含量/(mg/g)氮回收率/%
    TN44.8190.0694.5200.3535
    NH4+-N42.6390.4994.540
    TP48.7796.8698.39
    COD39.8591.0594.62
    下载: 导出CSV

    10  农村单户家庭黄水日产量

    10.   Daily yellow water production in rural single-family households

    成人单次小便量/L小便次数/(次/d)人数冲水/L稀释倍数/倍产生、处理黄水量/(L/d)
    0.2164315.2977.04
    下载: 导出CSV

    11  黄水性质

    11.   Yellow water properties

    pHρ(TN)/(mg/L)ρ(TP)/(mg/L)ρ(NH4+-N)/(mg/L)ρ(COD)/(mg/L)
    8.1418.4173.2368.3427
    下载: 导出CSV
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  • 收稿日期:  2024-02-04
  • 录用日期:  2024-06-19
  • 修回日期:  2024-04-12
  • 刊出日期:  2025-04-01

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