能耗视角下挥发性有机物催化氧化技术述评

易天立; 田俊泰; 刘月; 聂紫萌; 王紫薇; 赵晓雅; 乔飞扬; 叶代启

doi:10.13205/j.hjgc.202510013

能耗视角下挥发性有机物催化氧化技术述评

doi: 10.13205/j.hjgc.202510013

易天立¹,
田俊泰¹,
刘月¹,
聂紫萌¹,
王紫薇¹,
赵晓雅¹,
乔飞扬¹,
叶代启^1,2,3,4, ,

1. 华南理工大学环境与能源学院, 广州 510006;
2. 挥发性有机物污染治理技术与装备国家工程实验室, 广州 510006;
3. 广东省大气环境与污染控制重点实验室, 广州 510006;
4. 广东省环境风险防控与应急处置工程技术研究中心, 广州 510006

详细信息

作者简介:
易天立（1993—），男，博士研究生，主要研究方向为大气污染控制。861192351@qq.com

通讯作者:
叶代启（1965—），男，博士，教授，主要研究方向为大气环境与污染控制。cedqye@scut.edu.com

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出版历程
- 收稿日期: 2024-12-23
- 录用日期: 2025-02-06
- 修回日期: 2025-01-21
- 网络出版日期: 2025-12-03
- 刊出日期: 2025-10-01

Review of catalytic oxidation technology of volatile organic compounds from the perspective of energy consumption

1. School of Environment and Energy, South China University of Technology, Guangzhou 510006, China;
2. National Engineering Laboratory for Volatile Organic Compounds Pollution Control Technology and Equipment, Guangzhou 510006, China;
3. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, China;
4. Guangdong Provincial Engineering and Technology Research Centre for Environmental Risk Prevention and Emergency Disposal, Guangzhou 510006, China

摘要

摘要: 在“双碳”战略背景下，高效、经济、低能耗的挥发性有机物（VOCs）催化氧化技术是国家重大需求。聚焦于VOCs热催化氧化和非热催化氧化技术的能耗，总结了热催化氧化芳香烃、脂肪烃、含氧VOCs以及含氯、氮、硫VOCs的能耗特征，概述了等离子体催化氧化、光催化氧化、光热催化氧化、臭氧催化氧化等非热催化氧化技术的能耗现状。结果表明，含氯、氮、硫VOCs难以实现常温催化燃烧，研究者应着眼于提高产物选择性，避免有毒副产物的生成；芳香烃催化燃烧温度距离常温仍有较大差距，含氧VOCs和脂肪烃未来有望实现低温或近常温催化燃烧；与不同的非热催化氧化技术相比，热催化氧化技术的平均比摩尔能耗最低。热催化氧化技术仍然是未来工业销毁VOCs的主流技术，非热催化氧化技术因在特定场景下具有独特优势，地会占据一席之地。
- 挥发性有机物 /
- 热催化氧化 /
- 非热催化氧化 /
- 技术 /
- 能耗
Abstract: Under the background of the Dual-Carbon Goals， the catalytic oxidation of volatile organic compounds （VOCs） with high efficiency， economy， and low-energy-consumption is a big demand in China. This review focuses on the energy consumption of thermal and non-thermal catalytic oxidation technologies of VOCs， summarizes the energy consumption characteristics of thermal catalytic oxidation of aromatic hydrocarbons， aliphatic hydrocarbons， oxygenated VOCs， and chlorine-containing， nitrogen-containing， and sulfur-containing VOCs， and provides an overview of the energy consumption of non-thermal catalytic oxidation technologies， such as plasma-catalytic oxidation， photocatalytic oxidation， photothermal catalytic oxidation， and ozone-catalytic oxidation. The results show that it is difficult to achieve room temperature catalytic combustion for chlorine-containing， nitrogen-containing， and sulfur-containing VOCs， and researchers should focus on improving product selectivity and avoiding the generation of toxic by-products. The catalytic combustion temperature of aromatic hydrocarbons is still far beyond the room temperature， and the catalytic combustion of oxygenated VOCs and aliphatic hydrocarbons are expected to achieve low temperature or near room temperature catalytic combustion in the future. Thermal catalytic oxidations have the lowest average specific molar energy consumption， compared with different non-thermal catalytic oxidations. Thermal catalytic oxidation technology is still the mainstream technology for the industrial destruction of VOCs in the future， and non-thermal catalytic oxidation technology will occupy a place， because of its unique advantages in specific scenarios.
- volatile organic compounds /
- thermal catalytic oxidation /
- non-thermal catalytic oxidation /
- technology /
- energy consumption

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