中低温CO<sub>2</sub>-CH<sub>4</sub>重整资源化技术研究进展与挑战

王征程; 李金花; 郑齐颖; 张姗姗; 朱晓晓; 田程程

doi:10.13205/j.hjgc.202510014

中低温CO₂-CH₄重整资源化技术研究进展与挑战

doi: 10.13205/j.hjgc.202510014

1. 华东理工大学资源与环境工程学院, 上海 200237

基金项目:

国家自然科学基金面上项目（52170109）；上海市教委科研创新计划重大项目（2023ZKZD41）；上海市碳中和专项（22DZ1208600）

详细信息

作者简介:
王征程（1998—），女，博士研究生，主要研究方向为CO₂资源化利用技术。wangzc1020@outlook.com

通讯作者:
田程程（1986—），女，教授，主要研究方向为CO₂资源化利用技术。cctian@ecust.edu.cn

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出版历程
- 收稿日期: 2025-04-01
- 录用日期: 2025-05-29
- 修回日期: 2025-05-02
- 网络出版日期: 2025-12-03
- 刊出日期: 2025-10-01

Research progress and challenges of low/moderate temperature CO₂-CH₄ reforming resource utilization technology

1. School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China

摘要

摘要: 全球气候变化加剧背景下，CO₂和CH₄等温室气体的减排与资源化利用成为实现“双碳”目标的关键路径。CO₂-CH₄重整反应作为将温室气体转化为合成气（H₂和CO）的战略性技术，兼具减排与创值潜力。然而其强吸热特性导致传统工艺需在高温条件下运行，易引发催化剂烧结失活、反应器成本高昂及能耗过大等瓶颈问题。因此，开发能够在中低温（<700 ℃）下高效催化该反应的催化剂逐渐成为研究热点。聚焦中低温（<700 ℃）催化体系创新，系统综述了贵金属、Ni基、Co基以及双金属催化剂的最新研究进展，从活性位点、载体结构、表界面特性等多维度分析不同催化体系在反应路径调控和抗积碳机制方面的构效关系，并提出了基于协同效应的催化剂理性设计策略。研究为突破中低温反应动力学限制提供了理论视角，旨在助力中低温重整技术的突破工业化瓶颈，有望推动温室气体资源化利用技术的工程化应用。
- 温室气体 /
- CO₂-CH₄重整 /
- 中低温 /
- CO₂活化 /
- 积碳
Abstract: The issue of global climate change is becoming increasingly severe， and the reduction and resource utilization of CO₂ and CH₄， as major greenhouse gases， are crucial for achieving the carbon neutrality goals. As a key technology that transforms greenhouse gases into syngas （H₂ and CO）， the CO₂-CH₄ reforming reaction has the dual potential for emissions reduction and value creation. However， the reaction's highly endothermic nature necessitates high-temperature conditions， leading to catalyst sintering， high reactor cost， and significant energy consumption. Therefore， the development of catalysts that can efficiently catalyze this reaction at low/moderate temperature （<700 ℃） becomes a research focus. This work centers on innovations in catalytic systems for low/moderate temperature （<700 ℃） reaction， reviewing the latest progress in precious metal， Ni-based， Co-based， and bimetallic catalysts. It analyzes the structure-performance relationships of different systems across active sites， support structures， and interfacial properties， focusing on reaction pathway modulation and anti-coking mechanisms. Strategies for rational catalyst design based on synergistic effects are also proposed. The findings provide a theoretical perspective to overcome kinetic limitations of low/moderate temperatures， aiming to help advance the engineering application of greenhouse gas resource utilization technologies.
- greenhouse gases /
- CO₂-CH₄ reforming /
- low/moderate temperature /
- CO₂ activation /
- carbon deposition

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参考文献(90)

[1]	SU J Z，WEN M，DING Y H，et al. Hiatus of global warming:a review［J］. Chinese Journal of Atmospheric Sciences，2016，40（6）:1143-1153. 苏京志，温敏，丁一汇，等. 全球变暖趋缓研究进展［J］. 大气科学，2016，40（6）:1143-1153.
[2]	LIU Z，DENG Z，DAVIS S J，et al. Monitoring global carbon emissions in 2021［J］. Nature Reviews Earth & Environment，2022，3（4）:217-219.
[3]	TONG D，ZHANG Q，ZHENG Y，et al. Committed emissions from existing energy infrastructure jeopardize 1.5 ℃ climate target［J］. Nature，2019，572（7769）:373-377.
[4]	LU X，TONG D，HE K B. China's carbon neutrality:an extensive and profound systemic reform［J］. Frontiers of Environmental Science & Engineering，2023，17（2）:14.
[5]	ETMINAN M，MYHRE G，HIGHWOOD E J，et al. Radiative forcing of carbon dioxide，methane，and nitrous oxide:a significant revision of the methane radiative forcing［J］. Geophysical Research Letters，2016，43（24）:12614-12623.
[6]	WANG W，GAO J，QIN H，et al. The study on greenhouse effect，Emission quantification and control of methane［J］. Urban Gas，2020（4）:4-9. 汪维，高霁，秦虎，等. 甲烷的温室效应及排放、控制［J］. 城市燃气，2020（4）:4-9.
[7]	CHEN B J，YANG G G. Research progress on methane reforming technology［J］. Modern Chemical Industry，2021，41（8）:19-23. 陈彪杰，杨国刚. 甲烷重整技术研究进展［J］. 现代化工，2021，41（8）:19-23.
[8]	XU X Y，LI H B，CHEN C，et al. Research Progress on methane generation and emission from urban sewage systems［J］. Environmental Engineering，2024，42（11）:29-39. 徐祥雨，李怀波，陈灿，等. 城市污水系统甲烷产生与排放研究进展［J］. 环境工程，2024，42（11）:29-39.
[9]	HEPBURN C，ADLEN E，BEDDINGTON J，et al. The technological and economic prospects for CO₂ utilization and removal［J］. Nature，2019，575（7781）:87-97.
[10]	XU J，CHENG J，HE R T，et al. Revealing the GHG reduction potential of emerging biomass-based CO₂ utilization with an iron cycle system［J］. Frontiers of Environmental Science & Engineering，2023，17（10）:127.
[11]	LAVOIE J M. Review on dry reforming of methane，a potentially more environmentally-friendly approach to the increasing natural gas exploitation［J］. Frontiers in Chemistry，2014，2:81.
[12]	WANG J Q，WANG Q Y，ZHU T H，et al. A review on research status of hydrogen production by methane reforming［J］. Modern Chemical Industry，2020，40（7）:15-20. 王嘉琦，王秋颖，朱桐慧，等. 甲烷重整制氢的研究现状分析［J］. 现代化工，2020，40（7）:15-20.
[13]	WANG F G，HAN K H，YU W S，et al. Low temperature CO₂ reforming with methane reaction over CeO₂-modified Ni@SiO₂ catalysts［J］. ACS Applied Materials & Interfaces，2020，12（31）:35022-35034.
[14]	WANG Y，YAO L，WANG Y N，et al. Low-temperature catalytic CO₂ dry reforming of methane on Ni-Si/ZrO₂ catalyst［J］. ACS Catalysis，2018，8（7）:6495-6506.
[15]	SHEN D Y，LI Z，SHAN J，et al. Synergistic Pt-CeO₂ interface boosting low temperature dry reforming of methane［J］. Applied Catalysis B:Environmental，2022，318:121809.
[16]	LIANG D F，WANG Y S，WANG Y L，et al. Dry reforming of methane for syngas production over noble metals modified M-Ni@S-1 catalysts（M = Pt，Pd，Ru，Au）［J］. International Journal of Hydrogen Energy，2024，51:1002-1015.
[17]	SINGHA R K，YADAV A，SHUKLA A，et al. Low temperature dry reforming of methane over Pd-CeO₂ nanocatalyst［J］. Catalysis Communications，2017，92:19-22.
[18]	LEE J A，BAE Y，HONG K，et al. Comparative evaluation of Ni-based bimetallic catalysts for dry reforming of methane at low temperature:The effect of alloy itself on performance［J］. International Journal of Energy Research，2022，46（8）:11228-11249.
[19]	WANG Y，LI L，LI G Y，et al. Synergy of oxygen vacancies and Ni⁰ species to promote the stability of a Ni/ZrO₂ catalyst for dry reforming of methane at low temperatures［J］. ACS Catalysis，2023，13（10）:6486-6496.
[20]	LIU H，WIERZBICKI D，DEBEK R，et al. La-promoted Ni-hydrotalcite-derived catalysts for dry reforming of methane at low temperatures［J］. Fuel，2016，182:8-16.
[21]	SELVARAJAH K，PHUC N H H，ABDULLAH B，et al. Syngas production from methane dry reforming over Ni/Al₂O₃ catalyst［J］. Research on Chemical Intermediates，2016，42（1）:269-288.
[22]	JANG W J，SHIM J O，KIM H M，et al. A review on dry reforming of methane in aspect of catalytic properties［J］. Catalysis Today，2019，324:15-26.
[23]	TIAN L，ZHAO X H，LIU B S，et al. Preparation of an industrial Ni-based catalyst and investigation on CH₄/CO₂ reforming to syngas［J］. Energy & Fuels，2009，23（1/2）:607-612.
[24]	LU J Y，GUO Y，LIU Q R，et al. Co-based catalysts for carbon dioxide reforming of methane to synthesis gas［J］. Progress in Chemistry，2017，29:1471-1479. 卢君颖，郭禹，刘其瑞，等. 甲烷二氧化碳重整制合成气钴基催化剂［J］. 化学进展，2017，29（12）:1471-1479.
[25]	ZHANG M，ZHANG J F，ZHOU Z L，et al. Effects of the surface adsorbed oxygen species tuned by rare-earth metal doping on dry reforming of methane over Ni/ZrO₂ catalyst［J］. Applied Catalysis B:Environmental，2020，264:118522.
[26]	THEOFANIDIS S A，GALVITA V V，POELMAN H，et al. Mechanism of carbon deposits removal from supported Ni catalysts［J］. Applied Catalysis B:Environmental，2018，239:502-512.
[27]	YU J Q，LE T，JING D P，et al. Balancing elementary steps enables coke-free dry reforming of methane［J］. Nature Communications，2023，14（1）:7514.
[28]	WANG Z Y，CAO X M，ZHU J H，et al. Activity and coke formation of nickel and nickel carbide in dry reforming:a deactivation scheme from density functional theory［J］. Journal of Catalysis，2014，311:469-480.
[29]	YOON Y，YOU H M，KIM H J，et al. Computational catalyst design for dry reforming of methane:a review［J］. Energy & Fuels，2022，36（17）:9844-9865.
[30]	ZHANG S S，YING M，YU J，et al. Ni_xAl₁O_2-δ mesoporous catalysts for dry reforming of methane:The special role of NiAl₂O₄ spinel phase and its reaction mechanism［J］. Applied Catalysis B:Environmental，2021，291:120074.
[31]	ELSAYED N H，ROBERTS N R M，JOSEPH B，et al. Low temperature dry reforming of methane over Pt-Ni-Mg/ceria-zirconia catalysts［J］. Applied Catalysis B:Environmental，2015，179:213-219.
[32]	NIKOO M K，AMIN N A S. Thermodynamic analysis of carbon dioxide reforming of methane in view of solid carbon formation［J］. Fuel Processing Technology，2011，92（3）:678-691.
[33]	WANG Y，YAO L，WANG S H，et al. Low-temperature catalytic CO₂ dry reforming of methane on Ni-based catalysts:a review［J］. Fuel Processing Technology，2018，169:199-206.
[34]	SHARIFIANJAZI F，ESMAEILKHANIAN A，BAZLI L，et al. A review on recent advances in dry reforming of methane over Ni-and Co-based nanocatalysts［J］. International Journal of Hydrogen Energy，2022，47（100）:42213-42233.
[35]	ABDULLAH B，GHANI N A A，VO D V N. Recent advances in dry reforming of methane over Ni-based catalysts［J］. Journal of Cleaner Production，2017，162:170-185.
[36]	KIM H M，KIM B J，JANG W J，et al. Effect of support materials and Ni loading on catalytic performance for carbon dioxide reforming of coke oven gas［J］. International Journal of Hydrogen Energy，2019，44（16）:8233-8242.
[37]	HAN J W，PARK J S，CHOI M S，et al. Uncoupling the size and support effects of Ni catalysis for dry reforming of methane［J］. Applied Catalysis B:Environmental，2017，203:625-632.
[38]	ZHAO H H，ZHANG W Z，SONG H L，et al. Highly coke-resistant Ni-La₂O₂CO₃ catalyst with low Ni loading for dry reforming of methane with carbon dioxide［J］. Catalysis Today，2022，402:189-201.
[39]	BIAN Z F，KAWI S. Sandwich-like silica@Ni@silica multicore-shell catalyst for the low-temperature dry reforming of methane:Confinement effect against carbon formation［J］. ChemCatChem，2018，10（1）:320-328.
[40]	ZHU L Y，LV Z Z，HUANG X，et al. Understanding the role of support structure in methane dry reforming for syngas production［J］. Fuel，2022，327:125163.
[41]	WANG F G，HAN B L，ZHANG L J，et al. CO₂ reforming with methane over small-sized Ni@SiO₂ catalysts with unique features of sintering-free and low carbon［J］. Applied Catalysis B:Environmental，2018，235:26-35.
[42]	KIM S，LAUTERBACH J，SASMAZ E. Yolk-shell Pt-NiCe@SiO₂ single-atom-alloy catalysts for low-temperature dry reforming of methane［J］. ACS Catalysis，2021，11（13）:8247-8260.
[43]	WANG Q Q，WANG W，CAO M，et al. Effect of interstitial carbon atoms in core-shell Ni₃ZnC_0.7/Al₂O₃ catalyst for high-performance dry reforming of methane［J］. Applied Catalysis B:Environmental，2022，317:121806.
[44]	SONG Z W，WANG Q Q，GUO C，et al. Improved effect of Fe on the stable NiFe/Al₂O₃ catalyst in low-temperature dry reforming of methane［J］. Industrial & Engineering Chemistry Research，2020，59（39）:17250-17258.
[45]	WANG Y H，LIU H M，XU B Q. Durable Ni/MgO catalysts for CO₂ reforming of methane:Activity and metal-support interaction［J］. Journal of Molecular Catalysis A:Chemical，2009，299（1-2）:44-52.
[46]	DANGHYAN V，KUMAR A，MUKASYAN A，et al. An active and stable NiOMgO solid solution based catalysts prepared by paper assisted combustion synthesis for the dry reforming of methane［J］. Applied Catalysis B:Environmental，2020，273:119056.
[47]	CáRDENAS-ARENAS A，BAILóN-GARCíA E，LOZANO-CASTELLó D，et al. Stable NiO-CeO₂ nanoparticles with improved carbon resistance for methane dry reforming［J］. Journal of Rare Earths，2022，40（1）:57-62.
[48]	LI R J，ZHANG J P，SHI J，et al. Regulation of metal-support interface of Ni/CeO₂ catalyst and the performance of low temperature chemical looping dry reforming of methane［J］. Journal of Fuel Chemistry and Technology，2022，50（11）:1458-1470. 李睿杰，章菊萍，史健，等. Ni/CeO₂催化剂的金属-载体界面调控及其低温化学链甲烷干重整性能研究［J］. 燃料化学学报，2022，50（11）:1458-1470.
[49]	ZHANG M，ZHANG J F，WU Y Q，et al. Insight into the effects of the oxygen species over Ni/ZrO₂ catalyst surface on methane reforming with carbon dioxide［J］. Applied Catalysis B:Environmental，2019，244:427-437.
[50]	YAO L，GALVEZ M E，HU C W，et al. Synthesis gas production via dry reforming of methane over manganese promoted nickel/cerium-zirconium oxide catalyst［J］. Industrial & Engineering Chemistry Research，2018，57（49）:16645-16656.
[51]	CAI G B，CHU W，WANG J J，et al. Zinc-zirconia composite oxide supported nickel catalysts for methane dry reforming reaction［J］. Chemical Research and Application，2023，35（9）:2205-2216. 蔡国兵，储伟，王佳杰，等. 锌锆复合氧化物担载镍基催化剂用于甲烷干重整反应［J］. 化学研究与应用，2023，35（9）:2205-2216.
[52]	LI W Z，ZHAO Z K，WANG G R. Modulating morphology and textural properties of ZrO₂ for supported Ni catalysts toward dry reforming of methane［J］. AIChE Journal，2017，63（7）:2900-2915.
[53]	ZHAN H J，SHI X Y，HUANG X，et al. Highly coke-resistant ordered mesoporous Ni/SiC with large surface areas in CO₂ reforming of CH₄［J］. Journal of Fuel Chemistry and Technology，2019，47（8）:942-948. 詹海鹃，石晓燕，黄鑫，等. 高比表面积有序介孔Ni/SiC催化CH₄-CO₂重整反应［J］. 燃料化学学报，2019，47（8）:942-948.
[54]	LI X Y，LI D，TIAN H，et al. Dry reforming of methane over Ni/La₂O₃ nanorod catalysts with stabilized Ni nanoparticles［J］. Applied Catalysis B:Environmental，2017，202:683-694.
[55]	DAS S，SENGUPTA M，PATEL J，et al. A study of the synergy between support surface properties and catalyst deactivation for CO₂ reforming over supported Ni nanoparticles［J］. Applied Catalysis A:General，2017，545:113-126.
[56]	PARK J H，YEO S，CHANG T S. Effect of supports on the performance of Co-based catalysts in methane dry reforming［J］. Journal of CO₂ Utilization，2018，26:465-475.
[57]	SONG D H，JUNG U H，KIM Y E，et al. Influence of supports on the catalytic activity and coke resistance of Ni catalyst in dry reforming of methane［J］. Catalysts，2022，12（2）:216.
[58]	WANG Y N，ZHANG R J，YAN B H. Ni/Ce_0.9Eu_0.1O_1.95 with enhanced coke resistance for dry reforming of methane［J］. Journal of Catalysis，2022，407:77-89.
[59]	WANG H Q，NING Y N，QIU L，et al. Effect of the interaction between metal and support on the carbon deposition performance of Ni/NiAl2O4 Catalyst for Dry Reforming of Methane［J］. Chemical Reaction Engineering and Technology，2022，38（2）:115-125. 王慧琴，宁亚妮，邱丽，等. 金属与载体相互作用对Ni/NiAl₂O₄催化剂甲烷干重整积炭性能的影响［J］. 化学反应工程与工艺，2022，38（2）:115-125.
[60]	WU X L，LYU L H，MA Q X，et al. Research progress of nickel-based catalysts for carbon dioxide reforming of methane［J］. Clean Coal Technology，2021，27（3）:129-137. 吴兴亮，吕凌辉，马清祥，等. 甲烷二氧化碳重整镍基催化剂的研究进展［J］. 洁净煤技术，2021，27（3）:129-137.
[61]	AZANCOT L，BOBADILLA L F，CENTENO M A，et al. Effect of potassium loading on basic properties of Ni/MgAl₂O₄ catalyst for CO₂ reforming of methane［J］. Journal of CO₂ Utilization，2021，52:101681.
[62]	OU Z L，RAN J Y，QIU H Y，et al. Uncovering the effect of surface basicity on the carbon deposition of Ni/CeO₂ catalyst modified by oxides in DRM［J］. Fuel，2023，335:126994.
[63]	TEH L P，SETIABUDI H D，TIMMIATI S N，et al. Recent progress in ceria-based catalysts for the dry reforming of methane:A review［J］. Chemical Engineering Science，2021，239:116606.
[64]	ZHOU R F，MOHAMEDALI M，REN Y X，et al. Facile synthesis of multi-layered nanostructured Ni/CeO₂ catalyst plus in-situ pre-treatment for efficient dry reforming of methane［J］. Applied Catalysis B:Environmental，2022，316:121696.
[65]	XIA H H，DANG C X，ZHOU D，et al. Lamellar cross-linking Ni/CeO₂ as an efficient and durable catalyst for dry reforming of methane［J］. Chemical Engineering Journal，2024，489:151365.
[66]	DAS S，ASHOK J，BIAN Z，et al. Silica-ceria sandwiched Ni core-shell catalyst for low temperature dry reforming of biogas:Coke resistance and mechanistic insights［J］. Applied Catalysis B:Environmental，2018，230:220-236.
[67]	LIU Z Y，LUSTEMBERG P，GUTIéRREZ R A，et al. In situ investigation of methane dry reforming on metal/ceria（111）surfaces:Metal-support interactions and C-H bond activation at low temperature［J］. Angewandte Chemie International Edition，2017，56（42）:13041-13046.
[68]	ZHANG F，LIU Z Y，ZHANG S H，et al. In situ elucidation of the active state of Co-CeO₂ catalysts in the dry reforming of methane:The important role of the reducible oxide support and interactions with cobalt［J］. ACS Catalysis，2018，8（4）:3550-3560.
[69]	CHEN S Y，ZAFFRAN J，YANG B. Dry reforming of methane over the cobalt catalyst:Theoretical insights into the reaction kinetics and mechanism for catalyst deactivation［J］. Applied Catalysis B:Environmental，2020，270:118859.
[70]	ZHANG X D，ZHANG G J，LIU J，et al. Effects of defective structure originating from N incorporation-evaporation of Co-based biomass carbon catalysts on methane dry reforming［J］. Fuel，2024，357:129752.
[71]	TRAN N T，LE Q V，CUONG N V，et al. La-doped cobalt supported on mesoporous alumina catalysts for improved methane dry reforming and coke mitigation［J］. Journal of the Energy Institute，2020，93（4）:1571-1580.
[72]	PAKHARE D，SPIVEY J. A review of dry（CO₂）reforming of methane over noble metal catalysts［J］. Chemical Society Reviews，2014，43（22）:7813-7837.
[73]	LIU Z Y，ZHANG F，RUI N，et al. Highly active ceria-supported Ru catalyst for the dry reforming of methane:In situ identification of Ru^δ+-Ce³⁺ interactions for enhanced conversion［J］. ACS Catalysis，2019，9（4）:3349-3359.
[74]	MAO Y R，ZHANG L Z，ZHENG X J，et al. Coke-resistance over Rh-Ni bimetallic catalyst for low temperature dry reforming of methane［J］. International Journal of Hydrogen Energy，2023，48（37）:13890-13901.
[75]	DANG C X，LUO J L，YANG W W，et al. Low-temperature catalytic dry reforming of methane over Pd promoted Ni-CaO-Ca₁₂Al₁₄O₃₃ multifunctional catalyst［J］. Industrial & Engineering Chemistry Research，2021，60（50）:18361-18372.
[76]	ZHENG Y S，ZOU Z P，LÜ L，et al. Research progress of anti-deactivation nickel based catalysts for dry reforming of methane［J］. Low-carbon Chemistry And Chemical Engineering，2021，46（6）:1-8，16. 郑幼松，邹宗鹏，吕莉，等. 甲烷干重整抗失活镍基催化剂研究进展［J］. 低碳化学与化工，2021，46（6）:1-8，16.
[77]	TURAP Y，WANG I，FU T T，et al. Co-Ni alloy supported on CeO₂ as a bimetallic catalyst for dry reforming of methane［J］. International Journal of Hydrogen Energy，2020，45（11）:6538-6548.
[78]	MARGOSSIAN T，LARMIER K，KIM S M，et al. Supported bimetallic NiFe nanoparticles through colloid synthesis for improved dry reforming performance［J］. ACS Catalysis，2017，7（10）:6942-6948.
[79]	SONG K，LU M M，XU S P，et al. Effect of alloy composition on catalytic performance and coke-resistance property of Ni-Cu/Mg（Al）O catalysts for dry reforming of methane［J］. Applied Catalysis B:Environmental，2018，239:324-333.
[80]	WU Z X，YANG B，MIAO S，et al. Lattice strained Ni-Co alloy as a high-performance catalyst for catalytic dry reforming of methane［J］. ACS Catalysis，2019，9（4）:2693-2700.
[81]	YANG E S，NAM E，JO Y，et al. Coke resistant NiCo/CeO₂ catalysts for dry reforming of methane derived from core@shell Ni@Co nanoparticles［J］. Applied Catalysis B:Environment and Energy，2023，339:123152.
[82]	ARMENGOL-PROFITóS M，BRAGA A，PASCUA-SOLé L，et al. Enhancing the performance of a novel CoRu/CeO₂ bimetallic catalyst for the dry reforming of methane via a mechanochemical process［J］. Applied Catalysis B:Environment and Energy，2024，345:123624.
[83]	JIA Y T，WU S W，QIU P，et al. Atomically dispersed metal catalysts for methane dry reforming［J］. Journal of Materials Chemistry A，2025，13（8）:5530-5545.
[84]	HONG H，XU Z，MEI B，et al. A self-regenerating Pt/Ge-MFI zeolite for propane dehydrogenation with high endurance［J］. Science，2025，388（6746）:497-502.
[85]	DUAN X L，LI Y，ZHAO J H，et al. Machine learning accelerated discovery of entropy-stabilized oxide catalysts for catalytic oxidation［J］. Journal of the American Chemical Society，2024，147（1）:651-661.
[86]	CAO C X，ZHANG N A，CHENG Y. Numerical analysis on steam methane reforming in a plate microchannel reactor:Effect of washcoat properties［J］. International Journal of Hydrogen Energy，2016，41（42）:18921-18941.
[87]	HAMZAH A B，FUKUDA T，OOKAWARA S，et al. Process intensification of dry reforming of methane by structured catalytic wall-plate microreactor［J］. Chemical Engineering Journal，2021，412:128636.
[88]	XU Y Y，XUE Z G，LIU B，et al. Research progress on membrane reactor for CO₂ hydrogenation to fuels［J］. Membrane Science and Technology，2024，44（3）:143-152. 许月阳，薛志刚，柳波，等. 膜反应器用于二氧化碳加氢转变燃料的研究进展［J］. 膜科学与技术，2024，44（3）:143-152.
[89]	GAO Y C，JIANG J G，MENG Y，et al. A novel nickel catalyst supported on activated coal fly ash for syngas production via biogas dry reforming［J］. Renewable Energy，2020，149:786-793.
[90]	LÜ H F，DONG X，LI R T，et al. Super-dry reforming of methane using a tandem electro-thermocatalytic system［J］. Nature Chemistry，2025:1-8.