Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
CAO Li, LIAN Zi, HUANG Xue-min. CATALYTIC PERFORMANCE OF TYPICAL VOCs OVER MnCeOx/ZEOLITE CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 48-53. doi: 10.13205/j.hjgc.202001007
Citation: CAO Li, LIAN Zi, HUANG Xue-min. CATALYTIC PERFORMANCE OF TYPICAL VOCs OVER MnCeOx/ZEOLITE CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 48-53. doi: 10.13205/j.hjgc.202001007

CATALYTIC PERFORMANCE OF TYPICAL VOCs OVER MnCeOx/ZEOLITE CATALYST

doi: 10.13205/j.hjgc.202001007
  • Received Date: 2019-09-16
  • Manganese-cerium composite oxides catalyst was prepared with zeolite as the carrier. The binary catalytic performance of the catalyst for industrial typical VOCs was investigated, and the catalyst was characterized by BET, XRD and SEM. Results showed that the addition of the cerium promoted the dispersion of the manganese and improved the activity of the composite oxide catalyst.The catalytic performance of MnCeOx/zeolite was the best with n(Mn)∶n(Ce) of 1∶1, loading ratio of 20% and calcination temperature of 500 ℃, with initial and complete combustion temperatures of toluene at 155 ℃ and 255 ℃, respectively. In the single component experiment, the catalysts for three organics all showed higher activity, and the temperature of conversion of 90% was below 275 ℃; the catalytic performance decreased in the order of ethyl acetate, toluene and acetone, which was mainly affected by the level of the activation energy as well as their polarity of molecule. In the binary catalytic experiment, T50 and T90 of three organics increased respectively by 8~13 ℃ and 14~38 ℃ than that in the single component experiment, due to the competitive adsorption.
  • KAMAL M S,RAZZAK S A,HOSSAIN M M.Catalytic oxidation of volatile organic compounds (VOCs): a review[J]. Atmospheric Environment,2016,140: 117-134.
    金凌云,何迈,鲁继青,等.Y2O3涂层负载Pd整体式催化剂的制备和催化性能[J].催化学报,2007,28(7):635-640.
    LI W B, WANG J X,GONG H. Catalytic combustion of VOCs on non-noble metal catalysts[J].Catalysis Today, 2010,148(1/2): 81-87.
    SAQER S M, KONDARIDES D I, VERYKIOS X E. Catalytic oxidation of toluene over binary mixtures of copper, manganese and cerium oxides supported on γ-Al2O3[J]. Applied Catalysis B: Environmental, 2011,103(3/4): 275-286.
    ZHANG Z X, JIANG Z, SHANGGUAN W F. Low-temperature catalysis for VOCs removal in technology and application: a state-of-the-art review[J]. Catalysis Today, 2016,264:270-278.
    LUO M M, CHENG Y, PENG X Z, et al.Copper modified manganese oxide with tunnel structure as efficient catalyst for low-temperature catalyticcombustion of toluene[J]. Chemical Engineering Journal, 2019,369:758-765.
    CASTAÑO M H,MOLINA R,MORENO S. Cooperative effect of the Co-Mn mixed oxides for the catalytic oxidation of VOCs:influence of the synthesis method[J]. Applied Catalysis A:General,2015, 492:48-59.
    DOGGALI P,TERAOKA Y,MUNGSE P. Combustion of volatile organic compounds over Cu-Mn based mixed oxide type catalysts supported on mesoporous Al2O3,TiO2 and ZrO2[J]. Journal of Molecular Catalysis A: Chemical, 2012,358(6):23-30.
    张广福, 季生福, 万会军, 等. 铜锰基SBA-15催化剂的制备及对甲苯燃烧消除的催化性能[J]. 北京化工大学学报, 2008, 35(1):5-10.
    李树娜,宋佩,张金丽,等.CeO2-MnOx催化剂形貌对低浓度甲烷催化燃烧反应性能的影响[J].燃料化学学报, 2018, 46(5):615-624.
    ZHANG L, PENG Y X, ZHANG J, et al. Adsorptive and catalytic properties in the removal of volatile organic compounds over zeolite-based materials[J].Chinese Journal of Catalysis, 2016, 37:800-809.
    彭鹏,张占全,王有和,等.多级孔分子筛的制备与催化应用[J].化学进展,2013,25(12):2028-2037.
    PENG J, BAN H Y, ZHANG X T, et al. Binary adsorption equilibrium of propylene and ethylene on silicalite-1: prediction and experiment[J]. Chemical Physics Letters, 2005, 401(1/2/3):94-98.
    YU J W, NERETNIEKS I. Single-component and multicomponent adsorption equilibria on activated carbon of methylcyclohexane, toluene, and isobutyl methyl ketone[J]. Industrial and Engineering Chemistry Research, 1990, 29(2): 220-231.
    曹利,黄学敏,宋文斌,等. 用修正的E-L模型描述二元VOCs气体在活性炭上的吸附平衡[J].环境工程学报,2011, 5(10):2326-2330.
    JOSÉ I.GUTIÉRREZ-ORTIZ, BEATRIZDE RIVAS, RUBÉN LÓPEZ-FONSECA,et al. Catalytic purification of waste gases containing VOC mixtures with Ce/Zr solid solutions[J]. Applied Catalysis B: Environmental, 2006, 65(3/4): 191-200.
    HE C, LIN Y, ZHANG X Y,et al. Deep catalytic oxidation of benzene, toluene, ethyl acetate over Pd/SBA-15 catalyst: reaction behaviors and kinetics[J]. Asia-Pacific Journal of Chemical Engineering, 2012, 7(5): 705-715.
    曹利, 黄学敏, 冯燕. 掺杂CeO2的CuMnOx复合氧化物催化剂的制备及对甲苯催化燃烧性能研究[J]. 西安建筑科技大学学报(自然科学版), 2010, 42(5): 729-733.
    郝吉明,马广大. 大气污染控制工程[M]. 2版. 北京:高等教育出版社,2002.
  • Relative Articles

    [1]WANG Xiaowei, MIN Chaohui, SONG Jun, ZHANG Jinghua, ZHAO Hongbing, CAO Chen, ZHANG Chi, LIU Tianfu, LIU Jingyin, HUANG Xiaoli, CHEN Liang, LIU Xin. EMISSION CHARACTERISTICS AND WHOLE PROCESS CONTROL IMPLEMENTATION PATH FOR VOCs IN RAILWAY TRANSPORTATION INDUSTRY[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(10): 102-111. doi: 10.13205/j.hjgc.202410013
    [2]FEI Bo, ZHANG Gangfeng, BU Mengya, LI Xiangdong. ADSORPTION AND DESORPTION PERFORMANCE OF HONEYCOMB ACTIVATED CARBON AND ZEOLITE MOLECULAR SIEVE FOR VOCs EXHAUST GAS FROM COATING[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(3): 90-96. doi: 10.13205/j.hjgc.202303012
    [3]ZHAO Puzhen, LIU Chu, HUANG Qianlin, LÜ Lu. FABRICATION OF NICKEL FOAM BASED MnO2 MONOLITHIC CATALYSTS AND ITS APPLICATION IN CATALYTIC ELIMINATION OF TOLUENE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 71-78,115. doi: 10.13205/j.hjgc.202304010
    [4]FENG Chao, XIONG Gaoyan, WANG Yunxia, PAN Yuan, LIU Yunqi. SYNTHESIS OF CuO-Cu1.5Mn1.5O4 COMPOSITE OXIDE BY USING A BIMETALLIC ORGANIC FRAMEWORK FOR CATALYTIC PROPANE TOTAL OXIDATION[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(8): 69-77. doi: 10.13205/j.hjgc.202208009
    [5]SHUAI Qifan, LU Jiangang, LI Jiansheng. ANALYSIS ON STRUCTURAL SIMULATION, OPTIMIZATION AND APPLICATION EFFECT OF A REGENERATIVE THERMAL OXIDIZER[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(2): 146-153. doi: 10.13205/j.hjgc.202202023
    [6]LIU Chengjian, FU Mingli, HUANG Daojian, QIN Hao, YU Yufan. APPLICATION OF A RAPID IDENTIFICATION SYSTEM OF ATMOSPHERIC ENVIRONMENTAL POLLUTION SOURCES IN AN ECONOMIC AND TECHNOLOGICAL DEVELOPMENT ZONE IN THE GUANGDONG-HONG KONG-MACAO GREATER BAY AREA[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(7): 172-178. doi: DOI:10.13205/j.hjgc.202207025
    [7]LIU Jia-hong, LIU Sheng-nan, LIU Mao-hui, YUE Ya-yun, YANG Duo-kun, SUN Meng, LI Jing. INVENTORY AND CHARACTERISTICS OF SMALL-SCALE VOCs IN A DISTRICT OF TIANJIN[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(8): 188-194,200. doi: 10.13205/j.hjgc.202008031
    [8]XU Zun-zhu, LU Zhao-yang, ZHANG Ji-wen, SUN Yong-jia, GAO Shuang, YI Bin, WANG Teng-jiao, WANG Fei. APPLICATION STATUS OF INDUSTRIAL VOCs TREATMENT TECHNOLOGIES IN TYPICAL CITIES OF THE YANGTEZ RIVER DELTA REGION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 54-59. doi: 10.13205/j.hjgc.202001008
    [9]XU Chen-chen, ZHANG Qi, XU Qi, YUAN Hai-yan. RESEARCH PROGRESS OF ORGANIC-INORGANIC PHOTOCATALYSTS FOR DEGRADING VOCs[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 28-36. doi: 10.13205/j.hjgc.202001004
    [10]LI Juan-juan, ZHANG Meng, CAI Song-cai, YU En-qi, CHEN Jing, JIA Hong-peng. LIGHT-DRIVEN THERMOCATALYSIS/PHOTO-THERMOCATALYSIS OF VOCs: RECENT ADVANCES AND FUTURE PERSPECTIVES[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 13-20. doi: 10.13205/j.hjgc.202001002
    [15]Zhang Junxiang, Huang Xuemin, Cao Li, Ma Guangda, . ADSORPTION OF VOCs ON MODIFIED ACTIVATED CARBON BY SUPPORTED Cu[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(1): 90-94. doi: 10.13205/j.hjgc.201501021
    [17]Zhang Xiaoxu, Zhang Hongyu, Li Guoxue, . EFFECT OF ADDITIVE QUANTITY OF STALKS ON H2 S AND NH3 EMISSION DURING KITCHEN WASTE COMPOSTING[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(1): 95-99. doi: 10.13205/j.hjgc.201501022
  • Cited by

    Periodical cited type(7)

    1. 陈东,陈军辉,姜涛,梅林德. 催化燃烧工艺在制药行业VOCs废气治理中的应用. 浙江化工. 2024(02): 48-54 .
    2. 邢欣,李娜,程杰. 不同Cu负载量Cu-ZSM-5催化剂上正丁胺的选择催化氧化性能. 环境工程. 2022(03): 51-58 . 本站查看
    3. 胡志斐,王振峰,汪思瀛,武文斐,侯丽敏,张凯,白心蕊. 矿物材料在催化脱硝方面的应用进展. 矿产保护与利用. 2021(01): 161-165 .
    4. 樊灏,沈振兴,逯佳琪,常甜,黄宇. 常温除甲醛催化剂Mn_1Ce_x/HZSM-5的活性位点与性能分析. 环境工程. 2021(06): 99-105 . 本站查看
    5. 隗晶慧,冯勇超,于庆君,易红宏,唐晓龙,张媛媛,孟宪政,袁雨婷. 餐饮油烟中典型VOCs催化氧化研究进展. 化工进展. 2021(10): 5730-5746 .
    6. 高齐,马建,胡吉国,盛守祥,陈琛,冯俊亭. TFT-LCD制造行业VOCs排放特征及减排效果. 液晶与显示. 2020(10): 1087-1094 .
    7. 唐振艳,刘锋,左川,侯文明. 挥发性有机物催化燃烧用贵金属催化剂的研究进展. 贵金属. 2020(03): 85-93 .

    Other cited types(4)

  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (264) PDF downloads(148) Cited by(11)
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return