Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
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Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 38 Issue 1
Mar.  2020
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Article Contents
ZHANG Kai, YANG Shi-chao, LUO Min, WU Yan-heng, YU Su-ying. PREPARATION OF NANO-SHEET ZSM-5 ZEOLITE AND ITS ADSORPTION PROPERTIES FOR INDOOR ENVIRONMENT VOCs[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 60-64,74. doi: 10.13205/j.hjgc.202001009
Citation: ZHANG Kai, YANG Shi-chao, LUO Min, WU Yan-heng, YU Su-ying. PREPARATION OF NANO-SHEET ZSM-5 ZEOLITE AND ITS ADSORPTION PROPERTIES FOR INDOOR ENVIRONMENT VOCs[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 60-64,74. doi: 10.13205/j.hjgc.202001009

PREPARATION OF NANO-SHEET ZSM-5 ZEOLITE AND ITS ADSORPTION PROPERTIES FOR INDOOR ENVIRONMENT VOCs

doi: 10.13205/j.hjgc.202001009
  • Received Date: 2019-09-06
  • In this study, a new type of bola surfactant was synthesized and used as the template to prepare ZSM-5 molecular sieve (H-ZSM-5) with nano lamellar structure. The ethyl orthosilicate and sodium metaaluminate were used as silicon source and aluminum source, respectively. The H-ZSM-5 was prepared by hydrothermal method, and the mole ratio was 30 NaOH∶2.5 NaAlO2∶120 SiO2∶5 SDA∶4800 H2O. The prepared ZSM-5 molecular sieves were characterized by scanning electron microscopy, transmission electron microscopy, X-ray and nitrogen adsorption, thermogravimetric analysis, etc. The static adsorption experiments of formaldehyde on the traditional ZSM-5 and H-ZSM-5 were carried out. It was found that the adsorption capacity of H-ZSM-5 molecular sieve was significantly higher than that of the traditional microporous ZSM-5. The evaluation of adsorption performance by using toluene vapor molecule with larger molecular diameter showed that the nano-sheet H-ZSM-5 zeolite had the ability to adsorb VOCs molecules with larger molecular structure and the applying potential in indoor air purification.
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  • 朱天乐. 室内空气污染控制[M]. 北京:化学工业出版社. 2003: 101-161.
    SCHWIEGER W, MACHOKE A G, WEISSENBERGER T, et al. Hierarchy concepts: classi-fication and preparationstrategies for zeolite containing material with hierarchical porosity [J]. Chemical Society Reviews, 2016, 45(12): 3353-3376.
    CHOI M, NA K, KIM J, et al. Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts [J]. Nature, 2009, 461(7261): 246-249.
    SHEN X F, MAO W T, MA Y H, et al. A Hierarchical MFI zeolite with a two-dimensional square mesostructure [J]. Angewandte Chemie, (International Ed), 2018, 130(3): 732-736.
    SHEN X F, MAO W T, MA Y H, et al. Mesoporous MFI zeolite with a 2D square structure directed by surfactants with an azobenzene tail group[J]. Chemistry, 2018, 24(34): 8615-8623.
    XU D D, JING Z F, CAO F L, et al. Surfactants with aromatic-group tail and single quaternary ammonium head for directing single-crystalline mesostructured zeolite nanosheets [J]. Chemistry of Materials, 2014, 26(15): 4612-4619.
    XU D D, CHE S A, TERASAKIC O. A design concept of amphiphilic molecules for directing hierarchical porous zeolite[J]. New Journal Chemistry, 2016,40, 3982.
    朱智洪,郑丽明,孙惠惠,等. 使用八铵基头Bola型表面活性剂为模板剂合成beta中-微双孔分子筛[J]. 人工晶体学报,2015,44(2):447-453.
    黄海凤,戎文娟,顾勇义,等.ZSM-5沸石分子筛吸附-脱附VOCs的性能研究[J]. 环境科学学报,2014,34(12): 3144-3151.
    JUNG J, JO C, CHO K et al.Zeolite nanosheet of a single-pore thickness generated by a zeolite-structure-directing surfactant [J]. Journal of Materials Chemistry, 2012, 22(11): 4637-4640.
    PARK W, YU D, NA K, et al. Hierarchically structure-directing effect of multi-ammonium surfactants for the generation of MFI zeolite nanosheets[J]. Chemistry of Materials, 2011, 23(23): 5131-5137.
    NA K, JO C, KIM J, et al. Directing zeolite structures into hierarchically nanoporous architectures [J]. Science, 2011, 333(6040): 328-332.
    EVERETT D H. IUPAC: Manual of symbols and terminology for physicochemical quantities and units [J]. Pure and Applied Chemistry, 1972, 31(4): 577-638.
    ZHANG K, LUO S J, LIU Z W, et al. In situ fabrication of hierarchical MTW zeolite via nanoparticle assembly by a tailored simple organic molecule [J]. Chemistry A European Journal, 2018, 24(32): 8133-8140.
    ZHANG K, LIU Z W, YAN X, et al. In situ assembly of nanoparticles into hierarchical beta zeolite with tailored simple organic molecule[J]. Langmuir, 2017, 33(50): 14396-14404.
    黄海凤,褚翔,卢晗锋,等.两种介孔分子筛动态吸附VOCs的研究[J]. 中国环境科学,2010, 30(4): 442-447.
    TIAN F P, YANG X J, SHI Y C, et al. Adsorptive desulfurization over hierarchical beta zeolite by alkaline treatment[J]. Journal of Natural Gas Chemistry, 2012, 21(6): 647-652.
    YU W B, YUAN P, LIU D, et al. Facile preparation of hierarchically porous diatomite/MFI-type zeolite composites and their performance of benzene adsorption: the effects of NaOH etching pretreatment[J]. Journal of Hazardous Materials, 2015,285:173-181.
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