Source Journal of CSCD
Source Journal for Chinese Scientific and Technical Papers
Core Journal of RCCSE
Included in JST China
Volume 38 Issue 5
Aug.  2020
Turn off MathJax
Article Contents
SHI Hui-min, WANG Qun-hui, NI Jin, GAO Ming, WU Chuan-fu. DEGRADATION OF AMOXICILLIN SIMULATED WASTEWATER USING A THREE-DIMENSIONAL ELECTRODES REACTOR[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 30-35. doi: 10.13205/j.hjgc.202005006
Citation: SHI Hui-min, WANG Qun-hui, NI Jin, GAO Ming, WU Chuan-fu. DEGRADATION OF AMOXICILLIN SIMULATED WASTEWATER USING A THREE-DIMENSIONAL ELECTRODES REACTOR[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 30-35. doi: 10.13205/j.hjgc.202005006

DEGRADATION OF AMOXICILLIN SIMULATED WASTEWATER USING A THREE-DIMENSIONAL ELECTRODES REACTOR

doi: 10.13205/j.hjgc.202005006
  • Received Date: 2019-05-09
  • Electrochemical oxidation is an efficient and environmental-friendly technology with significant advantages in the treatment of antibiotics including amoxicillin. The traditional two-dimensional electrode reactor packed activated carbon as particle electrode will reduce the mass transfer resistance in the system and improve current efficiency. This study explored the optimal conditions for the treatment of amoxicillin simulated wastewater by a three-dimensional electrode reactor, and compared with a two-dimensional electrode reactor and the adsorption process. The optimal conditions were as follows: the quartz sand accounted for 10% of the total volume of the packed particles, the current density was 5 mA/cm2, the electrolyte was 17 mmol/L Na2SO4, and the initial pH of the solution was 5.56. Under the optimal condition, the TOC removal rate was 49.1%, and the amoxicillin removal rate was 99.0%. The synergy between electrolysis and adsorption in the three-dimensional electrodes reactor made the TOC removal rate higher than that of adsorption and traditional two-dimensional electrode reactor (49.1%>22.0%+8.7%), showing a good application prospect.
  • loading
  • 傅海霞, 刘怡, 董志英, 等. 抗生素与重金属复合污染的生态毒理效应研究进展[J]. 环境工程, 2016,34(4):60-63

    ,104.
    MAKOWSKA N, KOCZURA R, MOKRACKA J. Class 1 integrase, sulfonamide and tetracycline resistance genes in wastewater treatment plant and surface water[J]. Chemosphere, 2016,144:1665-1673.
    CARVALHO I T, SANTOS L. Antibiotics in the aquatic environments: a review of the European scenario[J]. Environment International, 2016,94:736-757.
    金明兰, 刘凯, 徐莹莹, 等. 污水处理厂中磺胺类抗生素、抗性菌、抗性基因的特性[J]. 环境工程, 2015,33(11):1-4.
    JOHANSSON C H, JANMAR L, BACKHAUS T. Toxicity of ciprofloxacin and sulfamethoxazole to marine periphytic algae and bacteria[J]. Aquat Toxicol, 2014,156:248-258.
    MUTIYAR P K, MITTAL A K. Occurrences and fate of an antibiotic amoxicillin in extended aeration-based sewage treatment plant in Delhi, India: a case study of emerging pollutant[J]. Desalination & Water Treatment, 2013,51(31/32/33):6158-6164.
    PRAVEENA S M, SHAIFUDDIN S N M, SUKIMAN S, et al. Pharmaceuticals residues in selected tropical surface water bodies from Selangor (Malaysia): occurrence and potential risk assessments[J]. Science of the Total Environment, 2018,642:230-240.
    PUTRA E K, PRANOWO R, SUNARSO J, et al. Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: mechanisms, isotherms and kinetics[J]. Water Research, 2009,43(9):2419-2430.
    HOMAYOONFAL M, MEHRNIA M R. Amoxicillin separation from pharmaceutical solution by pH sensitive nanofiltration membranes[J]. Separation and Purification Technology, 2014,130:74-83.
    AY F, KARGI F. Advanced oxidation of amoxicillin by Fenton’s reagent treatment[J]. Journal of Hazardous Materials, 2010,179(1/2/3):622-627.
    MIRZAEI A, CHEN Z, HAGHIGHAT F, et al. Magnetic fluorinated mesoporous g-C3N4 for photocatalytic degradation of amoxicillin: transformation mechanism and toxicity assessment[J]. Applied Catalysis B:Environmental, 2019,242:337-348.
    ZHANG C, JIANG Y H, LI Y L, et al. Three-dimensional electrochemical process for wastewater treatment: a general review[J]. Chemical Engineering Journal, 2013,228:455-467.
    ZHU X P, NI J R, XING X, et al. Synergies between electrochemical oxidation and activated carbon adsorption in three-dimensional boron-doped diamond anode system[J]. Electrochimica Acta, 2011,56(3):1270-1274.
    LI X Y, WU Y, ZHU W, et al. Enhanced electrochemical oxidation of synthetic dyeing wastewater using SnO2-Sb-doped TiO2-coated granular activated carbon electrodes with high hydroxyl radical yields[J]. Electrochimica Acta, 2016,220:276-284.
    GARCIA E A, AGULLO-BARCELO M, BOND P, et al. Hybrid electrochemical-granular activated carbon system for the treatment of greywater[J]. Chemical Engineering Journal, 2018,352:405-411.
    石岩, 王启山, 岳琳, 等. 三维电极/电Fenton法去除垃圾渗滤液中的COD[J]. 中国给水排水, 2008,24(19):87-90.
    赵媛媛, 王德军, 赵朝成. 电催化氧化处理难降解废水用电极材料的研究进展[J]. 材料导报, 2019,33(7):1125-1132.
    郑天龙. 微气泡/臭氧—三维电极反应器深度处理腈纶废水的研究[D]. 北京:北京科技大学, 2016.
    XIA Y J, DAI Q Z. Electrochemical degradation of antibiotic levofloxacin by PbO2 electrode: kinetics, energy demands and reaction pathways[J]. Chemosphere, 2018,205:215-222.
    CHEN G H. Electrochemical technologies in wastewater treatment[J]. Separation and Purification Technology, 2004,38(1):11-41.
    ADRIANO W S, VEREDAS V, SANTANA C C, et al. Adsorption of amoxicillin on chitosan beads: kinetics, equilibrium and validation of finite bath models[J]. Biochemical Engineering Journal, 2005,27(2):132-137.
    于丽花, 薛娟琴, 罗瑶, 等. 电解液条件对苯酚降解及羟自由基生成的影响[J]. 环境工程学报, 2016,10(8):4043-4048.
    YANG C, YOU X, CHENG J H, et al. A novel visible-light-driven In-based MOF/graphene oxide composite photocatalyst with enhanced photocatalytic activity toward the degradation of amoxicillin[J]. Applied Catalysis B: Environmental, 2017,200:673-680.
    LAN Y D, COETSIER C, CAUSSERAND C, et al. On the role of salts for the treatment of wastewaters containing pharmaceuticals by electrochemical oxidation using a boron doped diamond anode[J]. Electrochimica Acta, 2017,231:309-318.
    KAUR R, KUSHWAHA J P, SINGH N. Electro-oxidation of amoxicillin trihydrate in continuous reactor by Ti/RuO2 anode[J]. Science of the Total Environment, 2019,677:84-97.
    MÉNDEZ E, GONZÁLEZ-FUENTES M A, REBOLLAR-PEREZ G, et al. Emerging pollutant treatments in wastewater: cases of antibiotics and hormones[J]. Journal of Environmental Science and Health, Part A, 2017,52(3):235-253.
    孙超. 活性炭三维电极—活性炭纤维生物膜法处理阿莫西林模拟废水[D]. 泰安:山东农业大学, 2016.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (209) PDF downloads(4) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return