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Volume 38 Issue 5
Aug.  2020
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2020  >  38(5): 84-88
LI Jing, BAO Dong-jie, WANG Xiang-ning, LIU Zhan-meng. ADSORPTION PROPERTIES AND MECHANISM OF A MAGNETIC NANOCOMPOSITE ADSORBENT (PFM) FOR COPPER[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 84-88. doi: 10.13205/j.hjgc.202005015
Citation: LI Jing, BAO Dong-jie, WANG Xiang-ning, LIU Zhan-meng. ADSORPTION PROPERTIES AND MECHANISM OF A MAGNETIC NANOCOMPOSITE ADSORBENT (PFM) FOR COPPER[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 84-88. doi: 10.13205/j.hjgc.202005015
shu

ADSORPTION PROPERTIES AND MECHANISM OF A MAGNETIC NANOCOMPOSITE ADSORBENT (PFM) FOR COPPER

doi: 10.13205/j.hjgc.202005015

  • 1. Xingtai Polytechnic College, Xingtai 054035, China;

  • 2. School of Civil Engineering and Architecture, East China Jiao Tong University, Nanchang 330013, China

  • Received Date: 2019-04-25
    Abstract
  • A novel magnetic composite adsorbent of PAM@Fe3O4/MnO2 (PFM) was prepared and introduced to remove copper ions from water. The effects of adsorbent dosage, initial concentration of the heavy metal solution, and the adsorption time for the Cu2+ removal were investigated. The experimental results showed that the magnetic composite adsorbent of PFM could effectively remove copper ions from water. Under the conditions of Cu2+ concentration of 50 mg/L, pH of 6.0, and adsorbent dosage of 1.6 g/L, the adsorption equilibrium was gained within 400 min. The adsorption capacity could reach 30.29 mg/g and the removal rate of Cu2+ was as high as 97% then. Adsorption-regeneration cycles confirmed that the adsorbent could be reused successfully for Cu2+ adsorption and had promising potential for practical application. The VSM analysis showed that PFM had the advantages of superparamagnetism and ferromagnetism. The XRD pattern indicated that PAM adhered to the surface of nano-Fe3O4/MnO2, which enhanced the surface area of contact with metal ions in solution and would be beneficial to the adsorption of metal ions. The amide bonds that appeared in the FTIR spectra analysis indicated that magnetic composite adsorbent was successfully prepared by Fe3O4/MnO2 and PAM.
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