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Volume 38 Issue 5
Aug.  2020
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2020  >  38(5): 165-170
HUANG Pan-pan, WANG Chen-chen, QIU Chun-sheng, SUN Li-ping, HU Shuai-long, ZHANG Yi-fan. OCCURRENCE, ENVIRONMENTAL RISK AND WATER QUALITY STANDARD OF PAEs IN WATER ENVIRONMENT[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 23-29. doi: 10.13205/j.hjgc.202005005
Citation: MIAO Zhou-wei. EFFECT AND PROCESS RESEARCH FOR TPH CONTAMINATED SOIL REMEIDANTION BY CHEMICAL OXIDANTION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 165-170. doi: 10.13205/j.hjgc.202005029
shu

EFFECT AND PROCESS RESEARCH FOR TPH CONTAMINATED SOIL REMEIDANTION BY CHEMICAL OXIDANTION

doi: 10.13205/j.hjgc.202005029

  • Shanghai Urban Construction Design & Research Institute(Group) Co., Ltd, Shanghai 200125, China

  • Received Date: 2020-04-01
    Abstract
  • In this study, the remediation effect of several chemical oxidation systems on TPH-contaminated soils were evaluated, and some impact factors were studied as well. The results showed that Fenton, Fenton-like and alkali-activated persulfate systems showed good TPH remediation performance. Since the addition of citric acid significantly improved the catalytic activity of Fenton system, the Fenton-like system showed the best TPH degradation performance. The TPH degradation in Fenton-like and alkali-activated persulfate systems followed the pseudo-first-order kinetics. Increasing the concentration of hydrogen peroxide, citric acid and persulfate could enhance the degradation of TPH. It was proved that intensifying mixing, adopting sequential addition of oxidants and reducing soil particle size could obviously improve the degradation effect of TPH with lower amount of oxidants. Moreover, the experimental results confirmed that the main active free radical in Fenton-like system was ·OH, while in the alkali-activated persulfate system, besides ·OH, the presence of SO4-· or O2-·, and other presenting free radicals also made greater advantage of the oxidants.
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