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Volume 38 Issue 6
Aug.  2020
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2020  >  38(6): 58-66
WANG Xing-run, LI Lei, YANG Xiang-hua, TIAN Yong-qiang. PROGRESS IN REMEDIATION OF CHROMIUM-CONTAMINATED SITES[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 1-8,23. doi: 10.13205/j.hjgc.202006001
Citation: XI Dong-dong, LI Xiao-min, XIONG Zi-xuan, JIANG Zhi, ZHANG Xiao-ming, YANG Wei-chun. SYNERGISTIC REMOVAL OF Cu, Co, Ni AND Cr FROM CONTAMINATED SOIL BY BIOCHAR-SUPPORTED NANOSCALE ZERO-VALENT IRON[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 58-66. doi: 10.13205/j.hjgc.202006010
shu

SYNERGISTIC REMOVAL OF Cu, Co, Ni AND Cr FROM CONTAMINATED SOIL BY BIOCHAR-SUPPORTED NANOSCALE ZERO-VALENT IRON

doi: 10.13205/j.hjgc.202006010

  • School of Metallurgy and Environment, Central South University, Changsha 410006, China

  • Received Date: 2020-03-24
    Abstract
  • In this study, a low-cost and highly efficient composite material (ZVI-SM) with nanoscale zero-valent iron loaded by biochar was synthesized and applied to the remediation of copper, cobalt, nickel and chromium contaminated soil. The effects of biochar precursors and biochar composites prepared at different carbonation temperatures on the remediation of heavy metal contamination, and their removal mechanisms were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and metal adsorption experiment. FeCr2O4 formed by adsorption and reduction greatly reduced the toxicity of chromium and improved the removal efficiency of copper, cobalt and nickel. The introduction of Fe0 not only increased the adsorption capacity of heavy metals to biochar, but also solved the problem of toxicity of Cr(Ⅵ). XPS further clarified that biochar could be used as the electron transfer medium; the strong interaction between the gain and loss electrons of the surface functional groups; Fe0 could enhance the removal effect of the composite material on multi-heavy metal ions; besides ZVI-SM500, the removal rates of rest of the four materials, ZVI-SM100, 300, 400, 700 for copper, cobalt, nickel, chromium were much higher than the commercial nanoscale Fe0 and single application of biological carbon materials; this kind of composite material (ZVI-SM) showed a strong affinity and reactivity to chromium and copper, and completely removed copper and chromium in 5 minutes. Cobalt and nickel could also achieve more than 80% removal rate in 180 minutes. There was a significant ion competition effect in the reaction process in the order of Cr≥Cu>Co>Ni, consistent with the trend of the standard reduction potential of metal ions. Soil remediation experiments showed that ZNI-SM300 for remediation of contaminated soil, after 15 days, the content of Cr(Ⅵ) decreased from 480 mg/kg to 0.52 mg/kg, and the total amount of water-soluble Cr decreased from 500 mg/kg to 1.2 mg/kg. The immobilization efficiency of both was more than 99%, while the total removal effect of water-soluble copper, cobalt, nickel and Cr(Ⅵ) was achieved. Therefore, the nanoscale zero-valent iron with SM300 as the carrier could be used as the ideal material for the remediation of soil contaminated by composite heavy metals.
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    Created with Highcharts 5.0.7Chart context menuAccess Area Distribution其他: 8.0 %其他: 8.0 %其他: 0.1 %其他: 0.1 %Central District: 0.1 %Central District: 0.1 %China: 1.2 %China: 1.2 %Japan: 0.1 %Japan: 0.1 %Saitama: 0.1 %Saitama: 0.1 %Tuen Mun San Hui: 0.3 %Tuen Mun San Hui: 0.3 %United States: 0.3 %United States: 0.3 %[]: 0.6 %[]: 0.6 %上海: 5.5 %上海: 5.5 %东莞: 1.1 %东莞: 1.1 %中山: 0.1 %中山: 0.1 %临汾: 0.1 %临汾: 0.1 %临沂: 0.3 %临沂: 0.3 %丽水: 0.1 %丽水: 0.1 %丽江: 0.1 %丽江: 0.1 %乌兰察布: 0.1 %乌兰察布: 0.1 %乐山: 0.1 %乐山: 0.1 %佛山: 0.4 %佛山: 0.4 %保定: 0.6 %保定: 0.6 %信阳: 0.1 %信阳: 0.1 %兰州: 0.1 %兰州: 0.1 %凉山彝族自治州: 0.1 %凉山彝族自治州: 0.1 %北京: 11.5 %北京: 11.5 %十堰: 0.1 %十堰: 0.1 %南京: 3.5 %南京: 3.5 %南充: 0.3 %南充: 0.3 %南宁: 0.2 %南宁: 0.2 %南昌: 1.1 %南昌: 1.1 %南通: 0.2 %南通: 0.2 %南通市崇川区: 0.1 %南通市崇川区: 0.1 %厦门: 0.5 %厦门: 0.5 %台北: 0.3 %台北: 0.3 %台州: 0.6 %台州: 0.6 %合肥: 1.2 %合肥: 1.2 %吉林: 0.4 %吉林: 0.4 %呼和浩特: 0.1 %呼和浩特: 0.1 %咸阳: 0.1 %咸阳: 0.1 %哈尔滨: 0.1 %哈尔滨: 0.1 %唐山: 0.2 %唐山: 0.2 %嘉兴: 0.1 %嘉兴: 0.1 %大同: 0.1 %大同: 0.1 %天津: 2.9 %天津: 2.9 %太原: 0.8 %太原: 0.8 %威海: 0.1 %威海: 0.1 %娄底: 0.1 %娄底: 0.1 %宁波: 0.4 %宁波: 0.4 %安庆: 0.1 %安庆: 0.1 %安康: 0.1 %安康: 0.1 %安顺: 0.1 %安顺: 0.1 %宜昌: 0.1 %宜昌: 0.1 %宜春: 0.6 %宜春: 0.6 %宝鸡: 0.1 %宝鸡: 0.1 %宣城: 0.6 %宣城: 0.6 %宫城: 0.1 %宫城: 0.1 %巴中: 0.1 %巴中: 0.1 %常州: 0.6 %常州: 0.6 %常德: 0.3 %常德: 0.3 %平顶山: 0.1 %平顶山: 0.1 %广州: 1.2 %广州: 1.2 %廊坊: 0.1 %廊坊: 0.1 %延安: 0.1 %延安: 0.1 %张家口: 1.3 %张家口: 1.3 %德州: 0.1 %德州: 0.1 %德阳: 0.1 %德阳: 0.1 %惠州: 0.2 %惠州: 0.2 %成都: 1.3 %成都: 1.3 %成都市双流区: 0.1 %成都市双流区: 0.1 %扬州: 0.3 %扬州: 0.3 %抚州: 0.1 %抚州: 0.1 %拉萨: 0.1 %拉萨: 0.1 %拉贾斯坦邦: 0.1 %拉贾斯坦邦: 0.1 %攀枝花: 0.1 %攀枝花: 0.1 %新乡: 0.3 %新乡: 0.3 %无锡: 0.5 %无锡: 0.5 %昆明: 0.8 %昆明: 0.8 %晋城: 0.1 %晋城: 0.1 %朝阳: 0.2 %朝阳: 0.2 %杭州: 3.9 %杭州: 3.9 %枣庄: 0.1 %枣庄: 0.1 %株洲: 1.0 %株洲: 1.0 %桂林: 0.4 %桂林: 0.4 %榆林: 0.1 %榆林: 0.1 %武汉: 2.6 %武汉: 2.6 %汕头: 0.1 %汕头: 0.1 %沈阳: 0.5 %沈阳: 0.5 %河源: 0.1 %河源: 0.1 %泸州: 0.1 %泸州: 0.1 %洛阳: 0.1 %洛阳: 0.1 %济南: 1.3 %济南: 1.3 %济源: 0.1 %济源: 0.1 %海口: 0.1 %海口: 0.1 %淄博: 0.4 %淄博: 0.4 %淮北: 0.1 %淮北: 0.1 %深圳: 0.7 %深圳: 0.7 %温州: 0.5 %温州: 0.5 %湖州: 0.4 %湖州: 0.4 %湘潭: 0.1 %湘潭: 0.1 %漯河: 0.7 %漯河: 0.7 %潍坊: 0.1 %潍坊: 0.1 %潮州: 0.1 %潮州: 0.1 %濮阳: 0.1 %濮阳: 0.1 %烟台: 0.3 %烟台: 0.3 %眉山: 0.1 %眉山: 0.1 %石家庄: 1.0 %石家庄: 1.0 %福州: 0.8 %福州: 0.8 %绍兴: 0.3 %绍兴: 0.3 %绵阳: 0.4 %绵阳: 0.4 %芒廷维尤: 5.9 %芒廷维尤: 5.9 %芝加哥: 1.1 %芝加哥: 1.1 %苏州: 0.6 %苏州: 0.6 %葫芦岛: 0.1 %葫芦岛: 0.1 %衡水: 0.1 %衡水: 0.1 %衡阳: 0.2 %衡阳: 0.2 %衢州: 0.2 %衢州: 0.2 %襄阳: 0.1 %襄阳: 0.1 %西宁: 4.7 %西宁: 4.7 %西安: 1.5 %西安: 1.5 %贵阳: 0.2 %贵阳: 0.2 %赣州: 0.2 %赣州: 0.2 %达州: 0.3 %达州: 0.3 %运城: 0.9 %运城: 0.9 %遵义: 0.2 %遵义: 0.2 %邯郸: 0.1 %邯郸: 0.1 %邵阳: 0.1 %邵阳: 0.1 %郑州: 1.7 %郑州: 1.7 %鄂州: 0.1 %鄂州: 0.1 %重庆: 2.0 %重庆: 2.0 %金华: 0.1 %金华: 0.1 %银川: 0.1 %银川: 0.1 %锦州: 0.4 %锦州: 0.4 %镇江: 0.1 %镇江: 0.1 %长春: 0.4 %长春: 0.4 %长沙: 3.2 %长沙: 3.2 %长治: 0.3 %长治: 0.3 %阜新: 0.1 %阜新: 0.1 %阳泉: 0.1 %阳泉: 0.1 %陇南: 0.1 %陇南: 0.1 %青岛: 2.5 %青岛: 2.5 %韶关: 0.1 %韶关: 0.1 %香港特别行政区: 0.3 %香港特别行政区: 0.3 %鹰潭: 0.1 %鹰潭: 0.1 %黄冈: 0.1 %黄冈: 0.1 %黄石: 0.6 %黄石: 0.6 %齐齐哈尔: 0.1 %齐齐哈尔: 0.1 %其他其他Central DistrictChinaJapanSaitamaTuen Mun San HuiUnited States[]上海东莞中山临汾临沂丽水丽江乌兰察布乐山佛山保定信阳兰州凉山彝族自治州北京十堰南京南充南宁南昌南通南通市崇川区厦门台北台州合肥吉林呼和浩特咸阳哈尔滨唐山嘉兴大同天津太原威海娄底宁波安庆安康安顺宜昌宜春宝鸡宣城宫城巴中常州常德平顶山广州廊坊延安张家口德州德阳惠州成都成都市双流区扬州抚州拉萨拉贾斯坦邦攀枝花新乡无锡昆明晋城朝阳杭州枣庄株洲桂林榆林武汉汕头沈阳河源泸州洛阳济南济源海口淄博淮北深圳温州湖州湘潭漯河潍坊潮州濮阳烟台眉山石家庄福州绍兴绵阳芒廷维尤芝加哥苏州葫芦岛衡水衡阳衢州襄阳西宁西安贵阳赣州达州运城遵义邯郸邵阳郑州鄂州重庆金华银川锦州镇江长春长沙长治阜新阳泉陇南青岛韶关香港特别行政区鹰潭黄冈黄石齐齐哈尔

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      沈阳化工大学材料科学与工程学院 沈阳 110142

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