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Volume 38 Issue 6
Aug.  2020
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2020  >  38(6): 115-120
CHEN Dan-dan, WANG Bing, WANG Bo. TREATMENT OF HIGH CONCENTRATION SULFIDE WASTEWATER BY SODIUM SULFITE OXIDATION METHOD[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 115-120. doi: 10.13205/j.hjgc.202006018
Citation: CHEN Dan-dan, WANG Bing, WANG Bo. TREATMENT OF HIGH CONCENTRATION SULFIDE WASTEWATER BY SODIUM SULFITE OXIDATION METHOD[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 115-120. doi: 10.13205/j.hjgc.202006018
shu

TREATMENT OF HIGH CONCENTRATION SULFIDE WASTEWATER BY SODIUM SULFITE OXIDATION METHOD

doi: 10.13205/j.hjgc.202006018

  • 1. School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China;

  • 2. Shanghai Municipal Engineering Design Institute(Group) Co., Ltd, Shanghai 200092, China

  • Received Date: 2019-05-17
    Abstract
  • Treatment of high concentration sulfide wastewater by oxidation with Na2SO3 was investigated under the condition of atmospheric pressure and room temperature. The effects of initial pH, Na2SO3 dosage on the sulfide removal efficiency and production of oxidation products were studied. The crystal structure of solid phase was analyzed. At the same time, a method combining theoretical calculation of electrode potential of sulfite oxidative desulfurization and separation of target product S0 by reaction-centrifugation coupling was used to study the sulfide oxidation process. The results indicated that under the optimal condition of initial pH 5 and Na2SO3 dosage of 5 g/L, after reaction 15 min, the sulfide removal rate could reached 71.79% and the formation of sulfur could reached 603.5 mg/L. Using the method of separated target product S0 by reaction-centrifugation coupling under the condition of 2500 r/min rotating speed, could increase the formation of S0 to 819.5 mg/L. The result of X-Ray Diffraction indicated that the solid phase products of flocculation system and ordinary system were constitutionally stable annular rhombic sulfur (α-sulfur) at room temperature.
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