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Volume 38 Issue 6
Aug.  2020
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GUO Tian-tian, ZHANG Han, AN Wen-gang, DUAN Yu-tong, FAN Wei, HUO Ming-xin. COMPOSITIONAL STRUCTRE CHANGES AND CHARACTERISTICS OF DISSOLVED ORGANIC MATTERS DURING ARTIFICIAL GROUNDWATER RECHARGE WITH RECLAIMED WATER[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 126-131,107. doi: 10.13205/j.hjgc.202006020
Citation: GUO Tian-tian, ZHANG Han, AN Wen-gang, DUAN Yu-tong, FAN Wei, HUO Ming-xin. COMPOSITIONAL STRUCTRE CHANGES AND CHARACTERISTICS OF DISSOLVED ORGANIC MATTERS DURING ARTIFICIAL GROUNDWATER RECHARGE WITH RECLAIMED WATER[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 126-131,107. doi: 10.13205/j.hjgc.202006020

COMPOSITIONAL STRUCTRE CHANGES AND CHARACTERISTICS OF DISSOLVED ORGANIC MATTERS DURING ARTIFICIAL GROUNDWATER RECHARGE WITH RECLAIMED WATER

doi: 10.13205/j.hjgc.202006020
  • Received Date: 2019-05-20
  • This study carried out a laboratory column experiment to simulate the infiltration process, analyzed the variation of total dissolved organic matter (DOM) content and structural composition, and extracted the main organic components with the recommended method by IHSS for analysis and characterization. The results showed that after infiltration, the COD concentration in reclaimed water decreased from 57.90 mg/L (0 h) to 21.50 mg/L (159 h), and the removal efficiency reached 63%. Accordingly, the DOC concentration decreased from 12.40 mg/L to 7.16 mg/L, and the removal rate was 42%. Fluorescene regional integration results showed that aromatic protein-like substances and SMP-like substances were main components of DOM in reclaimed water; DOM in soil was mainly composed of humic acid (HA). Affected by the DOM leaching release in soil, the DOM of leachate from the experiment was mainly composed of HA (the proportion was more than 60%). The results of SEM and EDS analysis showed that the surface of HA was spongy, mainly composed of C (64.40%) and O (34.25%) elements. FTIR spectrum revealed that HA contained various functional groups such as hydroxyl and carboxyl groups. UV-Vis spectrum was monotonous and showed no characteristic. The ratios between characteristic peaks showed that the HA belonged to the macromolecular category.
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  • 肖宇. 高碑店污水处理厂二级出水深度处理后用于地下回灌的再生污水健康风险评价[D]. 北京:中国地质大学(北京), 2005.
    魏亮亮, 赵庆良, 薛爽,等. 二级出水经地下水回灌后的梯级利用及安全评价[J]. 中国给水排水, 2012, 28(19):78-83.
    MICHAEL-KORDATOU I, MICHAEL C, DUAN X, et al. Dissolved effluent organic matter: characteristics and potential implications in wastewater treatment and reuse applications [J]. Water Research, 2015, 77:213-248.
    唐东民. 溶解性有机质的动态变化及其对有机物吸附解吸的影响[D]. 四川:四川农业大学, 2008.
    白英臣. 天然溶解有机质和环境污染物的相互作用:以铜、汞离子和卡马西平为例[D]. 北京:中国科学院地球化学研究所,2007.
    李峰. 再生水补给地下水过程中水文地球化学作用的模拟研究[D]. 北京:中国地质大学(北京), 2015.
    张晗. 再生水地下储存过程中的水质变化及水文地球化学演化规律研究[D]. 长春:东北师范大学, 2018.
    MORTEZA B, RASMUS B, COLIN S, et al. Handling of Rayleigh and Raman scatter for PARAFAC modeling of fluorescence data using interpolation [J]. Journal of Chemometrics, 2010, 20(3/4):99-105.
    CHEN W, WESTERHOFF P, LEENHEER J A, et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter [J]. Environmental Science & Technology, 2015, 37(24):5701-5710.
    SHOZO K, AKIRA W, KAZUHITOITOH, et al. Comparison of two methods of preparation of humic and fulvic acids, IHSS method and NAGOYA method [J]. Soil Science & Plant Nutrition, 2006, 38(1):23-30.
    ZHANG S, YUAN L, LI W, et al. Characterization of pH-fractionated humic acids derived from Chinese weathered coal [J]. Chemosphere, 2017, 166:334-342.
    ESSANDOH H M K, TIZAOUI C, MOHAMED M H A. Removal of dissolved organic carbon and nitrogen during simulated soil aquifer treatment [J]. Water Research, 2013, 47(11):3559-3572.
    WESTERHOFF P, PINNEY M. Dissolved organic carbon transformations during laboratory-scale groundwater recharge using lagoon-treated wastewater [J]. Waste Management, 2000, 20(1):75-83.
    JARUSUTTHIRAK C, AMY G. Understanding soluble microbial products (SMP) as a component of effluent organic matter (EfOM) [J]. Water Research, 2007, 41(12):2787-2793.
    崔晓春. 再生水中余铝对生物堵塞和生物膜形成的影响与作用机制[D]. 长春:东北师范大学, 2017.
    WU L L, ZHAO X, ZHANG M. Removal of dissolved organic matter in municipal effluent with ozonation, slow sand filtration and nanofiltration as high quality pre-treatment option for artificial groundwater recharge [J]. Chemosphere, 2011, 83(5):693-699.
    FOX P, ABOSHANP W, ALSAMADI B. Analysis of soils to demonstrate sustained organic carbon removal during soil aquifer treatment[J]. Journal of Environmental Quality, 2005, 34(1):156-163.
    NōGRE M, VINDROLA D, SPERA S, et al. Effect of the chemical composition of soil humic acids on their viscosity, surface pressure,and morphology [J]. Soil Science, 2002, 167(10):636-651.
    林樱. 土壤、沉积物以及蓝藻中有机质标准物质的提取与表征[D]. 北京:中国环境科学研究院, 2011.
    LI L, ZHAO Z Y, HUANG W L, et al. Characterization of humic acids fractionated by ultrafiltration [J]. Organic Geochemistry, 2004, 35(9):1025-1037.
    BAI Y, WU F, LIU C, et al. Interaction between carbamzepine and humic substances: a fluorescence spectroscopy study [J]. Environmental Toxicology and Chemistry, 2008, 27(1):95-102.
    HENRY V M. Association of hydrophobic organic contaminants with soluble organic matter: evaluation of the database of K doc values [J]. Advances in Environmental Research, 2002, 6(4):577-593.
    DOSKOČIL L, BURDÍKOVÁ-SZEWIECZKOVÁ J, ENEV V, et al. Spectral characterization and comparison of humic acids isolated from some European lignites [J]. Fuel, 2018, 213:123-132.
    毛静春. 中国干旱半干旱草原地区土壤中腐殖质的提取与表征研究[D]. 哈尔滨:哈尔滨工业大学, 2015.
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