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Volume 38 Issue 11
Apr.  2021
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2020  >  38(11): 60-65,52
He Yuzhong Zhao Haibao Li Jianguo Yao Yuping, . CALCULATION OF DUST/SO3 RATIO FOR LOW-LOW TEMPERATURE ELECTROSTATICPRECIPITATOR AND ANALYSIS OF COALS IN CHINA[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(2): 76-79. doi: 10.13205/j.hjgc.201502016
Citation: LI Wei, WANG Ke-xin, GONG Zhen-lin, ZHANG Ji-guang, LIU Bao-xia, MA Meng-jie, LAN Ye-qing. EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(11): 60-65,52. doi: 10.13205/j.hjgc.202011010
shu

EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION

doi: 10.13205/j.hjgc.202011010

  • 1. College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095, China;

  • 2. China Tobacco Jiangsu Industrial Co., Ltd, Nanjing 210011, China;

  • 3. School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China;

  • 4. Tobacco Research Institute, Chinese Academy of Agricultural Sciences, Qingdao 266101, China;

  • 5. College of Sciences, Nanjing Agricultural University, Nanjing 210095, China

  • Received Date: 2019-10-09
    Available Online: 2021-04-23
  • Publish Date: 2021-04-23
    Abstract
  • In this paper, micro-scale zinc-copper (mZn/Cu) bimetallic particles were prepared via replacement reaction and applied in the removal of Rhodamine B. The effects of initial pH, mZn/Cu dosage and initial concentration on the degradation of Rhodamine B were investigated. The optimal conditions for the degradation of of Rhodamine B was determined through single-factor experiment. As compared with single metals, the formation of microbatteries on mZn/Cu greatly improved its ability to provide electrons and its chemical activity, resulting in more efficient degradation of Rhodamine B. When N2 was bubbled into the reaction system to remove the dissolved oxygen and the scavengers such as tert-butyl alcohol (TBA) and benzoquinone (BQ) were introduced, the degradation of Rhodamine B was also greatly inhibited. This proved that under acidic and aerobic conditions, the dissolved oxygen could accepted electrons from the surface of mZn/Cu to produce ·OH and O2-· radicals responsible for the rapid removal of Rhodamine B. Thus, this study not only provided a low-cost and high-efficiency technology for the degradation of organic contaminants in aqueous solution, but also put insight into the mechanism of the reaction.
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      沈阳化工大学材料科学与工程学院 沈阳 110142

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