EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION

LI Wei; WANG Ke-xin; GONG Zhen-lin; ZHANG Ji-guang; LIU Bao-xia; MA Meng-jie; LAN Ye-qing

doi:10.13205/j.hjgc.202011010

Volume 38 Issue 11

Apr. 2021

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2020 > 38(11): 60-65,52

LI Wei, WANG Ke-xin, GONG Zhen-lin, ZHANG Ji-guang, LIU Bao-xia, MA Meng-jie, LAN Ye-qing. EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(11): 60-65,52. doi: 10.13205/j.hjgc.202011010

Citation:

LI Wei, WANG Ke-xin, GONG Zhen-lin, ZHANG Ji-guang, LIU Bao-xia, MA Meng-jie, LAN Ye-qing. EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(11): 60-65,52. doi: 10.13205/j.hjgc.202011010

Citation:

LI Wei, WANG Ke-xin, GONG Zhen-lin, ZHANG Ji-guang, LIU Bao-xia, MA Meng-jie, LAN Ye-qing. EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(11): 60-65,52. doi: 10.13205/j.hjgc.202011010

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EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION

doi: 10.13205/j.hjgc.202011010

1. College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095, China;
2. China Tobacco Jiangsu Industrial Co., Ltd, Nanjing 210011, China;
3. School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China;
4. Tobacco Research Institute, Chinese Academy of Agricultural Sciences, Qingdao 266101, China;
5. College of Sciences, Nanjing Agricultural University, Nanjing 210095, China

Received Date: 2019-10-09
Available Online: 2021-04-23
Publish Date: 2021-04-23

Abstract

Abstract

In this paper, micro-scale zinc-copper (mZn/Cu) bimetallic particles were prepared via replacement reaction and applied in the removal of Rhodamine B. The effects of initial pH, mZn/Cu dosage and initial concentration on the degradation of Rhodamine B were investigated. The optimal conditions for the degradation of of Rhodamine B was determined through single-factor experiment. As compared with single metals, the formation of microbatteries on mZn/Cu greatly improved its ability to provide electrons and its chemical activity, resulting in more efficient degradation of Rhodamine B. When N₂ was bubbled into the reaction system to remove the dissolved oxygen and the scavengers such as tert-butyl alcohol (TBA) and benzoquinone (BQ) were introduced, the degradation of Rhodamine B was also greatly inhibited. This proved that under acidic and aerobic conditions, the dissolved oxygen could accepted electrons from the surface of mZn/Cu to produce ·OH and O₂^-· radicals responsible for the rapid removal of Rhodamine B. Thus, this study not only provided a low-cost and high-efficiency technology for the degradation of organic contaminants in aqueous solution, but also put insight into the mechanism of the reaction.
- Rhodamine B,
- micro-scale zinc-copper bimetallic particles,
- radicals,
- degradation mechanism

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References

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