Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 39 Issue 1
Apr.  2021
Turn off MathJax
Article Contents
Abstract
References
Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2021  >  39(1): 96-100
YANG De-yu, HAO Qing-lan, ZHAO Chen-chen, YAN Ning-na, DOU Bao-juan. CATALYTIC DEGRADATION PERFORMANCE OF TOLUENE OVER CuxMn1-xCe0.75Zr0.25Oy[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(1): 96-100. doi: 10.13205/j.hjgc.202101014
Citation: YANG De-yu, HAO Qing-lan, ZHAO Chen-chen, YAN Ning-na, DOU Bao-juan. CATALYTIC DEGRADATION PERFORMANCE OF TOLUENE OVER CuxMn1-xCe0.75Zr0.25Oy[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(1): 96-100. doi: 10.13205/j.hjgc.202101014
shu

CATALYTIC DEGRADATION PERFORMANCE OF TOLUENE OVER CuxMn1-xCe0.75Zr0.25Oy

doi: 10.13205/j.hjgc.202101014

  • College of Chemical Engineering and Materials Science, Tianjin University of Science & Technology, Tianjin 300457, China

  • Received Date: 2020-03-06
    Available Online: 2021-04-23
    Abstract
  • A series of bimetallic and biassistant CuxMn1-xCe0.75Zr0.25Oy catalysts were prepared by sol-gel method. The catalytic degradation performance of toluene over the catalysts was tested in a fixed-bed reactor. The relationships between the catalytic activity of toluene degradation and catalyst structure were explored by XRD, H2-TPR, O2-TPD and Raman methods. It was found that the increase of copper content could enhance the interaction between Cu-Ce, and improve the oxygen vacancy concentration, lattice oxygen content and low temperature reducibility, thus promote the catalytic activity. Cu1CeZr catalyst exhibited the best activity for toluene degradation, and the temperature of complete degradation of toluene was 220℃, which was 60℃ lower than that of Mn1CeZr catalyst.
    • FullText(HTML)
    • References(21)
  • AZALIM S, FRANCO M, BRAHMI R, et al. Removal of oxygenated volatile organic compounds by catalytic oxidation over Zr-Ce-Mn catalysts[J]. Journal of Hazardous Materials, 2011, 88(1/2/3):422-427.
    LI S M, HAO Q L, ZHAO R Z, et al. Highly efficient catalytic removal of ethyl acetate over Ce/Zr promoted copper/ZSM-5 catalysts[J]. Chemical Engineering Journal, 2016, 285(1):536-543.
    DENG Q F, REN T Z, AGULA B, et al. Mesoporous CexZr1-xO2 solid solutions supported CuO nanocatalysts for toluene total oxidation[J]. Journal of Industrial and Engineering Chemistry, 2014, 20(5):3303-3312.
    HOU Z Y, FENG J, LIN T, et al. The performance of manganese-based catalysts with Ce0.65Zr0.35O2 as support for catalytic oxidation of toluene[J]. Applied Surface Science, 2017, 434:82-90.
    KANG R N, WEI X L, LI H X, et al. Sol-gel enhanced mesoporous Cu-Ce-Zr catalyst for toluene oxidation[J]. Combustion Science and Technology, 2018, 190(5):878-892.
    TANG X L, ZHANG B C, LI Y, et al. Carbon monoxide oxidation over CuO/CeO2 catalysts[J]. Catalysis Today, 2004, 93/94/95:191-198.
    GUO X L, LI J, ZHOU R X. Catalytic performance of manganese doped CuO-CeO2 catalysts for selective oxidation of CO in hydrogen-rich gas[J]. Fuel, 2016, 163:56-64.
    廖伟平,杨柳,王飞,等. 不同制备方法的Mn-Ce催化剂低温SCR性能研究[J].化学学报, 2011, 69(22):2723-2728.
    汤清虎,吴成明,黄晓娜,等. 非晶态Mn-Ce-O催化芳香醇选择氧化[J].催化学报, 2009, 30(3):207-212.
    LU H F, KONG X X, HUAN H F, et al. Cu-Mn-Ce ternary mixed-oxide catalysts for catalytic combustion of toluene[J]. Journal of Environmental Sciences, 2015, 32:102-107.
    OKUMURA K, KOBAYASHI T, TANAKA H, et al. Toluene combustion over palladium supported on various metal oxide supports[J]. Applied Catalysis B:Environmental, 2003, 44:325-331.
    PIUMETTI M, FINO D, RUSSO N. Mesoporous manganese oxides prepared by solution combustion synthesis as catalysts for the total oxidation of VOCs[J]. Applied Catalysis B:Environmental, 2015, 163:277-287.
    SCIRE S, MINICO S, CRISAFULLI C. Catalytic combustion of volatile organic compounds on gold/cerium oxide catalysts[J]. Applied Catalysis B:Environmental, 2003, 40(1):43-49.
    RIVAS B, LÓPEZ-FONSECA R, GUTIÉRREZ-ORTIZ M Á, et al. Combustion of chlorinated VOCs using κ-CeZrO4 catalysts[J]. Catal Today, 2011,176(1):470-473.
    ZABILSKIY M, ERJAVEC B, DJINOVIĆ, P, et al. Ordered mesoporous CuO-CeO2 mixed oxides as an effective catalyst for N2O decomposition[J]. Chemical Engineering Journal, 2014, 254:153-162.
    LUO Y J, QIAN Q R, CHEN Q H. On the promoting effect of the addition of CexZr1-xO2 to palladium based alumina catalysts for methanol deep oxidation[J]. Materials Research Bulletin, 2015, 62:65-70.
    SANTOS V P, PEREIRA M F R, ÓRFO J J M, et al. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds[J]. Applied Catalysis B:Environmental, 2010, 99(1/2):353-363.
    NIU J R, QIAN H L, LIU J, et al. Process and mechanism of toluene oxidation using Cu1-yMn2CeyOx/sepiolite prepared by the co-precipitation method[J]. Journal of Hazardous Materials, 2018, 357:332-340.
    ZHOU G L, LAN H, GAO T T, et al. Influence of Ce/Cu ratio on the performance of ordered mesoporous CeCu composite oxide catalysts[J]. Chemical Engineering Journal, 2014, 246:53-63.
    LANDI G, BARBATO P S, DI BENEDETTO A, et al. Optimization of the preparation method of CuO/CeO2 structured catalytic monolith for CO preferential oxidation in H2-rich streams[J]. Applied Catalysis B:Environmental, 2016, 181:727-737.
    HE C, XU B T, SHI J W, et al. Catalytic destruction of chlorobenzene over mesoporous ACeOx (A=Co, Cu, Fe, Mn, or Zr) composites prepared by inorganic metal precursor spontaneous precipitation[J]. Fuel Processing Technology, 2015, 130:179-187.
    • Relative Articles

  • Relative Articles

    [1]YAO Haiqian, GUO Xinchao, FU Fengman, YANG Hao, GUO Xiang, ZHANG Fanghong. Mn-Fe-Ce/GAC CATALYZED OZONE OXIDATION TECHNOLOGY FOR ANILINE WASTEWATER[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(5): 28-34. doi: 10.13205/j.hjgc.202405004
    [2]LI Ru, LI Xiaokang, FENG Yan, WANG Xueyan, XING Qianyun. DEGRADATION OF XYLENE BY DBD PLASMA IN COLLABORATION WITH Mn-TiO2/γ-Al2O3 CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 157-166. doi: 10.13205/j.hjgc.202404019
    [3]WANG Chengcheng, LI Qian, ZHAO Shuguang, SONG Leshan, LIU Hua, ZHANG Ying, LIU Si. PREPARATION AND ELECTRO-CATALYTIC PERFORMANCE OF LEAD-ANTIMONY ELECTRODE WITH A TIN-ANTIMONY INTERMEDIATE LAYER[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(3): 92-98. doi: 10.13205/j.hjgc.202403011
    [4]LI Haicheng, CHENG Cheng, CHEN Zhenglin, YANG Lixia, LUO Shenglian. SULFIDE ION DOPING PROMOTES EFFICIENT PHOTOCATALYTIC DEGRADATION OF TOLUENE BY WO3 NANOWIRES[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(9): 201-210. doi: 10.13205/j.hjgc.202409019
    [5]WU Xinming, AN Hao, ZHAO Junyu, OU Zixuan, HAO Liangshan, LI Chao. PREPARATION OF Fe/Mn-PAC CATALYSTS AND DEGRADATION OF REACTIVE BRILLIANT BLUE KN-R BY CATALYTIC OZONATION[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 32-39. doi: 10.13205/j.hjgc.202304005
    [6]YANG Jiani, ZHAO Baowei, YANG Maoying, SUO Jinmiao, ZHU Zhengyu, DENG Aiqin. PREPARATION OF Fe/C CATALYST BASED ON FERRIC CITRATE AND ITS ACTIVATION PERFORMANCE ON PEROXYDISULFATE TO DEGRADE SULFADIAZINE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(7): 116-123,251. doi: 10.13205/j.hjgc.202307016
    [7]ZHAO Ying, LIU Qingliang, WANG Shuo, SUN Zhiqiang, MA Jun. MECHANISM OF PEROVSKITE LaBO3 CATALYZED PEROXYACETIC ACID DEGRADATION OF BISPHENOL A IN WATER[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(12): 1-10. doi: 10.13205/j.hjgc.202312001
    [8]LIU Dong, QI Junwen, XU Zunzhu, ZHANG Jiwen, JIN Xiaoxian, LI Jiansheng. ADSORPTION PERFORMANCE OF TOLUENE ON HYDROPHOBIC MODIFIED MOLECULAR SIEVES UNDER HIGH HUMIDITY[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(2): 66-72,81. doi: 10.13205/j.hjgc.202302010
    [9]FENG Chao, XIONG Gaoyan, WANG Yunxia, PAN Yuan, LIU Yunqi. SYNTHESIS OF CuO-Cu1.5Mn1.5O4 COMPOSITE OXIDE BY USING A BIMETALLIC ORGANIC FRAMEWORK FOR CATALYTIC PROPANE TOTAL OXIDATION[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(8): 69-77. doi: 10.13205/j.hjgc.202208009
    [10]ZHANG Shicheng, LI Simin, ZHU Jia. DEGRADATION OF METHYL ORANGE BY CuO/g-C3N4 ACTIVATED PEROXODISULFATE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(10): 40-48. doi: 10.13205/j.hjgc.202210006
    [11]SHANG Xiao-han, ZHU Xiao-biao. HETEROGENEOUS FENTON DEGRADATION OF BENZOTRIAZOLE IN WATER BY Fe/Cu/ZEOLITE CATALYST AT NEUTRAL pH VALUE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(2): 10-15. doi: 10.13205/j.hjgc.202102002
    [12]ZHANG Kai, YANG Shi-chao, LUO Min, WU Yan-heng, YU Su-ying. PREPARATION OF NANO-SHEET ZSM-5 ZEOLITE AND ITS ADSORPTION PROPERTIES FOR INDOOR ENVIRONMENT VOCs[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 60-64,74. doi: 10.13205/j.hjgc.202001009
    • Supplements(0)
    • Cited By
  • Created with Highcharts 5.0.7Amount of accessChart context menuAbstract Views, HTML Views, PDF Downloads StatisticsAbstract ViewsHTML ViewsPDF Downloads2024-052024-062024-072024-082024-092024-102024-112024-122025-012025-022025-032025-04010203040
    Created with Highcharts 5.0.7Chart context menuAccess Class DistributionFULLTEXT: 28.0 %FULLTEXT: 28.0 %META: 71.0 %META: 71.0 %PDF: 1.0 %PDF: 1.0 %FULLTEXTMETAPDF
    Created with Highcharts 5.0.7Chart context menuAccess Area Distribution其他: 10.8 %其他: 10.8 %China: 0.3 %China: 0.3 %[]: 0.3 %[]: 0.3 %临汾: 0.1 %临汾: 0.1 %北京: 1.6 %北京: 1.6 %南宁: 0.1 %南宁: 0.1 %南昌: 0.1 %南昌: 0.1 %南通: 0.4 %南通: 0.4 %卡拉奇: 0.3 %卡拉奇: 0.3 %台州: 0.1 %台州: 0.1 %咸阳: 0.1 %咸阳: 0.1 %哈尔滨: 0.1 %哈尔滨: 0.1 %嘉兴: 0.1 %嘉兴: 0.1 %太原: 0.9 %太原: 0.9 %宣城: 0.1 %宣城: 0.1 %常德: 0.1 %常德: 0.1 %广州: 0.7 %广州: 0.7 %张家口: 0.4 %张家口: 0.4 %成都: 0.3 %成都: 0.3 %扬州: 0.3 %扬州: 0.3 %昆明: 0.4 %昆明: 0.4 %晋城: 0.3 %晋城: 0.3 %朝阳: 0.1 %朝阳: 0.1 %杭州: 0.4 %杭州: 0.4 %武汉: 0.1 %武汉: 0.1 %济源: 0.3 %济源: 0.3 %湖州: 0.6 %湖州: 0.6 %漯河: 0.1 %漯河: 0.1 %芒廷维尤: 72.0 %芒廷维尤: 72.0 %芝加哥: 0.6 %芝加哥: 0.6 %苏州: 0.1 %苏州: 0.1 %衢州: 0.1 %衢州: 0.1 %西宁: 3.4 %西宁: 3.4 %贵阳: 0.1 %贵阳: 0.1 %运城: 1.3 %运城: 1.3 %遵义: 0.1 %遵义: 0.1 %邯郸: 0.1 %邯郸: 0.1 %郑州: 0.4 %郑州: 0.4 %重庆: 0.1 %重庆: 0.1 %长沙: 0.3 %长沙: 0.3 %长治: 0.1 %长治: 0.1 %青岛: 0.4 %青岛: 0.4 %其他China[]临汾北京南宁南昌南通卡拉奇台州咸阳哈尔滨嘉兴太原宣城常德广州张家口成都扬州昆明晋城朝阳杭州武汉济源湖州漯河芒廷维尤芝加哥苏州衢州西宁贵阳运城遵义邯郸郑州重庆长沙长治青岛

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (473) PDF downloads(6) Cited by()
    Proportional views
    Related

    Journal Online

    Authors' Center

    Links

    Copyright © 《工业建筑》杂志社有限公司 京ICP备11033253号-1

    Supported by: Beijing Renhe Information Technology Co. Ltd     百度统计

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return