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LU Jinsuo, MA Xinting, JIANG Hao, YU Mengzhu, SONG Guang, CHEN Xingdu. REMOVAL PERFORMANCE AND DEGRADATION MECHANISM OF PARTICULATE MATTER AND H2S GAS BY SOLUTION ABSORPTION-ELECTRO-FENTON PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 155-165. doi: 10.13205/j.hjgc.202412019
Citation: YANG De-yu, HAO Qing-lan, ZHAO Chen-chen, YAN Ning-na, DOU Bao-juan. CATALYTIC DEGRADATION PERFORMANCE OF TOLUENE OVER CuxMn1-xCe0.75Zr0.25Oy[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(1): 96-100. doi: 10.13205/j.hjgc.202101014

CATALYTIC DEGRADATION PERFORMANCE OF TOLUENE OVER CuxMn1-xCe0.75Zr0.25Oy

doi: 10.13205/j.hjgc.202101014
  • Received Date: 2020-03-06
    Available Online: 2021-04-23
  • A series of bimetallic and biassistant CuxMn1-xCe0.75Zr0.25Oy catalysts were prepared by sol-gel method. The catalytic degradation performance of toluene over the catalysts was tested in a fixed-bed reactor. The relationships between the catalytic activity of toluene degradation and catalyst structure were explored by XRD, H2-TPR, O2-TPD and Raman methods. It was found that the increase of copper content could enhance the interaction between Cu-Ce, and improve the oxygen vacancy concentration, lattice oxygen content and low temperature reducibility, thus promote the catalytic activity. Cu1CeZr catalyst exhibited the best activity for toluene degradation, and the temperature of complete degradation of toluene was 220℃, which was 60℃ lower than that of Mn1CeZr catalyst.
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