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Volume 39 Issue 3
Jul.  2021
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Article Contents
LIU Xiu, LIU Li-heng, LIU Rui, HUANG Lin, LIN Hua, WEI Zhong-hua, WANG Dun-qiu. EXPERIMENTAL STUDY ON Cr REMOVAL FROM SIMULATED WASTEWATER BY CAGE CORE BLACK CARBON BEADS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 75-81. doi: 10.13205/j.hjgc.202103011
Citation: LIU Xiu, LIU Li-heng, LIU Rui, HUANG Lin, LIN Hua, WEI Zhong-hua, WANG Dun-qiu. EXPERIMENTAL STUDY ON Cr REMOVAL FROM SIMULATED WASTEWATER BY CAGE CORE BLACK CARBON BEADS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 75-81. doi: 10.13205/j.hjgc.202103011

EXPERIMENTAL STUDY ON Cr REMOVAL FROM SIMULATED WASTEWATER BY CAGE CORE BLACK CARBON BEADS

doi: 10.13205/j.hjgc.202103011
  • Received Date: 2020-01-03
    Available Online: 2021-07-19
  • The cage core black carbon beads were used to remove Cr in aqueous solution. The effects of initial pH and Cr concentration, adsorption time and temperature and adsorbent dosage on Cr removal were discussed, while the isotherm, kinetics and thermodynamics of Cr removal process were also studied. The results showed that lower initial pH, higher adsorption temperature and adsorbent dosage, and longer adsorption time were conducive to Cr removal. The Cr removal process was better described by D-R model and pseudo-second order kinetic model. The saturated adsorption capacity of bamboo based biochar for Cr was 30.62 mg/g. The controlling-step of this process was combination of liquid film diffusion and intraparticle diffusion, while the liquid film diffusion was the dominant course. The Cr removal by cage core black carbon beads made from bamboo was a spontaneous and endothermic chemisorption process.
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  • [1]
    RANGABHASHIYAM S, BALASUBRAMANIAN P. The potential of lignocellulosic biomass precursors for biochar production:performance, mechanism and wastewater application:a review[J]. Industrial Crops and Products, 2019, 128:405-423.
    [2]
    WAN Z H, CHO D W, TSANG D C W, et al. Concurrent adsorption and micro-electrolysis of Cr(Ⅵ) by nanoscale zerovalent iron/biochar/Ca-alginate composite[J]. Environmental Pollution, 2019, 247:410-420.
    [3]
    DIAO Z H, DU J J, JIANG D, et al. Insights into the simultaneous removal of Cr6+ and Pb2+ by a novel sewage sludge-derived biochar immobilized nanoscale zero valent iron:coexistence effect and mechanism[J]. Science of the Total Environment, 2018, 642:505-515.
    [4]
    YU J D, JIANG C Y, QUAN Q Q, et al. Enhanced removal of Cr(Ⅵ) from aqueous solution by supported ZnO nanoparticles on biochar derived from waste water hyacinth[J]. Chemosphere, 2018, 195:632-640.
    [5]
    DIAO Z H, XU X R, CHEN H, et al. Simultaneous removal of Cr(Ⅵ) and phenol by persulfate activated with bentonite-supported nanoscale zero-valent iron[J]. Journal of Hazardous Materials, 2016, 316:186-193.
    [6]
    WU J, ZHENG H, ZHANG F, et al. Iron-carbon composite from carbonization of iron-crosslinked sodium alginate for Cr(Ⅵ) removal[J]. Chemical Engineering Journal, 2019, 362:21-29.
    [7]
    LI P G, FU T, GAO X Y, et al. Adsorption and reduction transformation behaviors of Cr(Ⅵ) on mesoporous polydopamine/titanium dioxide composite nanospheres[J]. Journal of Chemical & Engineering Data, 2019, 64:2686-2696.
    [8]
    CHAKRABARTY T, AFRIN R, MIA M Y, et al. Phytoremediation of Chromium and some chemical parameters from Tannery effluent by using water Hyacinth (Eichhornia craassipes)[J]. Research in Agriculture Livestock & Fisheries, 2017, 4(3):151-156.
    [9]
    MAULION R V,HIWATIG K B,RENDON C J L, et al. Utilization of water hyacinth (Eichhorniacrassipes) for phytoremediation of hexavalent chromium in simulated wastewater[J]. Asia Pacific Journal of Multidisciplinary Research, 2015, 3(4):117-123.
    [10]
    CHERDCHOO W, NITHETTHAM S, CHAROENPANICH J. Removal of Cr(Ⅵ) from synthetic wastewater by adsorption onto coffee ground and mixed waste tea[J]. Chemosphere, 2019, 221:758-767.
    [11]
    ARSLANOGLU H, KAYA S, TVMEN F. Cr(Ⅵ) adsorption on low-cost activated carbon developed from grape marc-vinasse mixture[J]. Particulate Science and Technology, 2019,11:1-14.
    [12]
    WANG X D, LI C X, LI Z W, et al. Effect of pyrolysis temperature on characteristics, chemical speciation and risk evaluation of heavy metals in biochar derived from textile dyeing sludge[J].Ecotoxicology and Environmental Safety, 2019, 168:45-52.
    [13]
    WANG R, YOSHIMASA A, MOTOI M. Surface properties and water vapor adsorption-desorption characteristics of bamboo-based activated carbon[J]. Journal of Analytical and Applied Pyrolysis,2013, 104:667-674.
    [14]
    MOTOHIDE H, YOSHIMASA A, THIRAVETYAN P, et al. Preparation of bamboo chars and bamboo activated carbons to remove color and COD from Ink wastewater[J]. Water Environment Research, 2016, 88(1):87-96.
    [15]
    BEI C, YOSHIMASA A, MOTOI M. Preparation of bamboo-based oxidized biochar for simultaneous removal of Cd(Ⅱ) and Cr(Ⅵ) from aqueous solutions[J]. Desalination and Water Treatment, 2019, 168:269-281.
    [16]
    BING Z, YUNHAI W, PENG F. Bamboo charcoal modified with Cu2+ and 3-aminopropyl trimethoxy silane for the adsorption of acid fuchsin dye:optimization by response surface methodology and the adsorption mechanism[J]. Journal of Applied Polymer Science, 2019, 136(27):47728.
    [17]
    DUAN S B, WEI M, PAN Y Z, et al. Synthesis of magnetic biochar from iron sludge for the enhancement of Cr (Ⅵ) removal from solution[J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 80:835-841.
    [18]
    YU J W, CHI C, ZHU B, et al. High adsorptivity and recycling performance activated carbon fibers for Cu(Ⅱ) adsorption[J]. Science of the Total Environment, 2020, 700:134412.
    [19]
    TANG Q, WANG K T, MUHAMMAD Y, et al. Synthesis of highly efficient porous inorganic polymer microspheres for the adsorptive removal of Pb2+ from wastewater[J]. Journal of Cleaner Production, 2018, 193:351-362.
    [20]
    SHARFILAHI S, GEETANJALI R, CHAUDHRYSAIF A. Acid washed black cumin seed powder preparation for adsorption of methylene blue dye from aqueous solution:Thermodynamic, kinetic and isotherm studies[J]. Journal of Molecular Liquids, 2018, 264:275-284.
    [21]
    LIANG C H, ZHANG X D, FENG P, et al. ZIF-67 derived hollow cobalt sulfide as superior adsorbent for effective adsorption removal of ciprofloxacin antibiotics[J]. Chemical Engineering Journal, 2018, 344:95-104.
    [22]
    LIU L H, TANG C W, PENG Y L, et al. Modification of bentonite by Al/Mg-polymeric hydroxy for Cu2+, Cd2+, and Pb2+ removal from aqueous solutions[J]. Desalination and Water Treatment, 2019, 147:243-254.
    [23]
    WANG Y L, ZHANG N, CHEN D N, et al. Facile synthesis of acid-modified UiO-66 to enhance the removal of Cr(Ⅵ) from aqueous solutions[J]. Science of the Total Environment, 2019, 682:118-127.
    [24]
    CUI Y B, ATKINSO J D. Glycerol-derived magnetic mesoporous Fe/C composites for Cr(Ⅵ) removal, prepared via acid-assisted one-pot pyrolysis[J]. Chemosphere, 2019, 228:694-701.
    [25]
    JISEON J, DAESUNG L. Magnetite nanoparticles supported on organically modified montmorillonite for adsorptive removal of iodide from aqueous solution:optimization using response surface methodology[J]. Science of the Total Environment, 2018, 615:549-557.
    [26]
    YI Y H, LV J L, LIU Y, et al. Synthesis and application of modified Litchi peel for removal of hexavalent chromium from aqueous solutions[J]. Journal of Molecular Liquids, 2017, 225:28-33.
    [27]
    WANG X P, LU J, CAO B Y, et al. Facile synthesis of recycling Fe3O4/graphene adsorbents with potassium humate for Cr(Ⅵ) removal[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2019, 560:384-392.
    [28]
    SHOKRY A, TAHANAYMAN L, IBRAHIM H, et al. The development of a ternary nanocomposite for the removal of Cr(Ⅵ) ions from aqueous solutions[J]. RSC Advances, 2019, 9:39187-39200.
    [29]
    CHERDCHOO W, NITHETTHAM S, CHAROENPANICH J. Removal of Cr(Ⅵ) from synthetic wastewater by adsorption onto coffee ground and mixed waste tea[J]. Chemosphere, 2019, 221:758-767.
    [30]
    NEMR A. Potential of pomegranate husk carbon for Cr(Ⅵ) removal from wastewater:kinetic and isotherm studies[J]. Journal of Hazardous Materials, 2009, 161(1):132-141.
    [31]
    GAO Q Y, LIN D G, FAN Y J, et al. Visible light induced photocatalytic reduction of Cr(Ⅵ) by self-assembled and amorphous Fe-2MI[J]. Chemical Engineering Journal,2019,374:10-19.
    [32]
    TAN C, RONG H, WANG H T, et al. Adsorption of heavy metals by biochar derived from municipal sewage sludge[J]. Journal of Tsinghua University, 2014, 54(8):1062-1067.
    [33]
    ALI A, SAEED K. Decontamination of Cr(Ⅵ) and Mn(Ⅱ) from aqueous media by untreated and chemically treated banana peel:a comparative study[J]. Desalination & Water Treatment,2015, 3(13):3586-3591.
    [34]
    TAO X M, WU Y H, CHA L G. Shaddock peels-based activated carbon as cost-saving adsorbents for efficient removal of Cr (Ⅵ) and methyl orange[J]. Environmental Science and Pollution Research, 2019, 26:19828-19842.
    [35]
    DAKIKY M, KHAMIS M, MANASSRA A, et al. Eective adsorption of chromium (Ⅵ) in industrial wastewater using low-cost abundantly available adsorbents[J]. Advances in Environmental Research,2002, 6(4):533-540.
    [36]
    BABEL S, KURNIAWAN T. Cr(Ⅵ) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan[J]. Chemosphere,2004, 54, 951-967.
    [37]
    ALOTHMAN Z, ALI R, NAUSHAD M. Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell:adsorption kinetics, equilibrium and thermodynamic studies[J]. The Chemical Engineering Journal,2012, 184:238-247.
    [38]
    UCUN H, BAYHAN K, KAYA Y. Kinetic and thermodynamic studies of thebiosorption of Cr (Ⅵ) by Pinussylvestris Linn[J]. Journal of Hazardous Materials, 2008, 153:52-59.
    [39]
    YU S, YUAN G M, GAO H J, et al. Removal of Cr(Ⅵ) from aqueous solutions using polymer nanotubes[J]. Journal of Materials Science, 2020, 55:163-176.
    [40]
    OGATA F, UETA E I, KAWASAKI N. Characteristics of a novel adsorbent Fe-Mgtype hydrotalcite and its adsorption capability of As(Ⅲ) and Cr(Ⅵ) from aqueous solution[J].Journal of Industrial Engineering Chemistry, 2018, 59:56-63.
    [41]
    HVSEYIN D, KADIR S, BINGÖLBALI S. Equilibrium and kinetics characteristics of copper(Ⅱ) sorption onto gyttja[J]. Bulletin of Environmental Contamination and Toxicology, 2010, 84:147-151.
    [42]
    DURANOǦLU D, TROCHIMCZUK A W, BEKER U. Kinetics and thermodynamics of hexavalent chromium adsorption onto activated carbon derived from acrylonitrile-divinylbenzene copolymer[J]. Chemical Engineering Journal, 2012, 187:193-202.
    [43]
    QIANWEI L, HANJIN L, JUNJIE G, et al. Facile one-pot preparation of nitrogen-doped ultra-light graphene oxide aerogel and its prominent adsorption performance of Cr(Ⅵ)[J]. Chemical Engineering Journal, 2018, 338:62-71.
    [44]
    SUN L, YUAN Z G, GONG W B, et al. The mechanism study of trace Cr(Ⅵ) removal from water using Fe0 nanorods modified with chitosan in porous anodic alumina[J]. Applied Surface Science, 2015, 328:606-613.
    [45]
    ZHANG X J, ZHANG L, LI A M. Eucalyptus sawdust derived biochar generated by combining the hydrothermal carbonization and low concentration KOH modification for hexavalent chromium removal[J]. Journal of Environmental Management, 2018, 206:989-998.
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