PETRILEUM CONTAMINATED SOIL CLEANING: SURFACTANT-INORGANIC ELECTROLYTE-PETROLEUM HYDROCARBON MATCHING

WANG Qi; GUO Shu-hai; LI Gang; WANG Sa; NIU Ming-fen; YIN Zhi-hui

doi:10.13205/j.hjgc.202103028

Volume 39 Issue 3

Jul. 2021

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WANG Qi, GUO Shu-hai, LI Gang, WANG Sa, NIU Ming-fen, YIN Zhi-hui. PETRILEUM CONTAMINATED SOIL CLEANING: SURFACTANT-INORGANIC ELECTROLYTE-PETROLEUM HYDROCARBON MATCHING[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 195-203,110. doi: 10.13205/j.hjgc.202103028

Citation:

WANG Qi, GUO Shu-hai, LI Gang, WANG Sa, NIU Ming-fen, YIN Zhi-hui. PETRILEUM CONTAMINATED SOIL CLEANING: SURFACTANT-INORGANIC ELECTROLYTE-PETROLEUM HYDROCARBON MATCHING[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 195-203,110. doi: 10.13205/j.hjgc.202103028

Citation:

WANG Qi, GUO Shu-hai, LI Gang, WANG Sa, NIU Ming-fen, YIN Zhi-hui. PETRILEUM CONTAMINATED SOIL CLEANING: SURFACTANT-INORGANIC ELECTROLYTE-PETROLEUM HYDROCARBON MATCHING[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 195-203,110. doi: 10.13205/j.hjgc.202103028

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PETRILEUM CONTAMINATED SOIL CLEANING: SURFACTANT-INORGANIC ELECTROLYTE-PETROLEUM HYDROCARBON MATCHING

doi: 10.13205/j.hjgc.202103028

WANG Qi^1,2,3,
GUO Shu-hai^{1,2
,
,},
LI Gang^1,2,
WANG Sa^1,2,
NIU Ming-fen⁴,
YIN Zhi-hui⁴

1. Shenyang Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China;
2. National-Local Joint Engineering Laboratory of Contaminated Soil Remediation by Bio-physicochemical Synergistic Process, Shenyang 110016, China;
3. University of Chinese Academy of Sciences, Beijing 100049, China;
4. School of Municipal and Environmental Engineering, Shenyang Jianzhu University, Shenyang 110168, China

Received Date: 2020-02-29
Available Online: 2021-07-19

Abstract

Abstract

Four surfactants, SDBS, SHO, AEO and NP-10, were selected in this study to carry out the cleaning test for the aged petroleum contaminated soil. The study was focused on the compatibility between surfactants and petroleum components. Based on the mechanism of molecular alignment regulation of surfactants, it was designed to compound the surfactants and inorganic salts and explore the cleaning effect and suitability evaluation. The results showed that the elution effect was the best when the temperature was 65℃, the soil-water ratio was 1:5, the time was 60 min, and then the cleaning capacity of the four surfactants was in the sequence of SDBS>SHO>>AEO≈NP-10. Moreover, the inorganic electrolytes, including Na₂CO₃, Na₂SiO₃ and NaOH, were selected for the compound tests. It achieved significant enhanced elution capacities of SHO, AEO, NP-10 when mixed with inorganic electrolytes except SDBS. Among them, AEO and NP-10 were the most prominent by compounding Na₂CO₃ or Na₂SiO₃. Because of the obvious difference in structure, the four surfactants showed different matching capacity for different petroleum components, and the desorption performance was strengthened after compounding with appropriate electrolyte. AEO combined with Na₂SiO₃ had the best elution effect on saturated hydrocarbons, with an elution rate of 92.97%. AEO combined with Na₂CO₃ had the best elution effect on aromatic hydrocarbons, with an elution rate of 93.58%. Moreover, the elution rate of the resin and asphaltene reached 83.47% when compounding NP-10 and Na₂SiO₃. Therefore, according to the proportion of petroleum group components, matching compound agents could be prepared to improve the elution efficiency. For example, in this study, for the aged petroleum contaminated soil mainly containing saturated hydrocarbons, the elution rate of the total petroleum by AEO+Na₂SiO₃ reached 89.14%, showing good prospect of practicality.
- petroleum-contaminated soil,
- surfactant,
- inorganic electrolyte,
- chemical cleaning,
- petroleum group components

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References(44)

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