Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 39 Issue 7
Jan.  2022
Turn off MathJax
Article Contents
SAI Shi-jie, LI Mai-jun, DANG Ping, LIU Hui, ZHANG Na, HUANG Xia. APPLICATION OF HIGH SEPARATION NANOFILTRATION PROCESS IN ZERO DISCHARGE OF HIGH SALT WASTEWATER FROM COAL CHEMICAL INDUSTRY[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 173-178. doi: 10.13205/j.hjgc.202107024
Citation: SAI Shi-jie, LI Mai-jun, DANG Ping, LIU Hui, ZHANG Na, HUANG Xia. APPLICATION OF HIGH SEPARATION NANOFILTRATION PROCESS IN ZERO DISCHARGE OF HIGH SALT WASTEWATER FROM COAL CHEMICAL INDUSTRY[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 173-178. doi: 10.13205/j.hjgc.202107024

APPLICATION OF HIGH SEPARATION NANOFILTRATION PROCESS IN ZERO DISCHARGE OF HIGH SALT WASTEWATER FROM COAL CHEMICAL INDUSTRY

doi: 10.13205/j.hjgc.202107024
  • Received Date: 2021-02-27
    Available Online: 2022-01-18
  • A high separation nanofiltration system consisting of 3 sub-nanofiltration systems was proposed and its effect in zero discharge project of high salt wastewater from coal chemical industry was analyzed.Resultsshowed that the average rejection rates of SO42- and Cl- were 99.7% and-13.7% respectively, and the average water recovery rate was 81.9%, which indicated a good separation effect of monovalent and divalent salts. The fluctuation of water recovery rates and operating pressures of nanofiltration system and its subsystems in continuous operation were small, and the system operation stability was high. The average rejection rates of COD, Ca2+ and Mg2+ were 47.6%, 76.9% and 86.0% respectively, while the cleaning frequencies were 2.1, 0 and 1.0 times per month respectively, which indicated that the system had a high anti-fouling performance. The plant demonstrated that the high separation nanofiltration system had a promising prospect in the field of zero discharge of high salt wastewater.
  • loading
  • [1]
    何睦盈,张亚峰.冷冻脱硝-纳滤-热泵蒸发技术处理高盐废水[J].给水排水,2013,39(11):60-63.
    [2]
    赛世杰.纳滤膜在高盐废水零排放领域的分盐性能研究[J].工业水处理,2017,37(9):75-78.
    [3]
    王晓琳,丁宁.反渗透和纳滤技术与应用[M].北京:化学工业出版社,2005.
    [4]
    韩永萍,林强,李亚秋.纳滤膜传质过程的研究[J].化学世界,2011,52(12):760-764

    ,733,730,742.
    [5]
    王钊.高分子膜错流纳滤过程的理论分析与有限元模拟[D].济南:山东大学,2014.
    [6]
    VEZZANI D,BANDINI S.Donnan equilibrium and dielectric exclusion for characterization of nanofiltration membranes[J].Desalination,2002,149:477-483.
    [7]
    王智.纳滤截留无机离子特性及机理研究[D].北京:清华大学,2018.
    [8]
    RAUTENBACH R,GROSCHL A.Separation potential of nanofiltration membranes[J].Desalination,1990,77:73-84.
    [9]
    GARCIA A J,DICKSON J M.Mathematical modeling of nanofiltration membranes with mixed electrolyte solutions[J].Journal of Membrane Science,2004,235:1-13.
    [10]
    DEY T K,RAMACHANDHRAN V,MISRA B M.Selectivity of anionic species in binary mixed electrolyte systems for nanofiltration membranes[J].Desalination,2000,127:165-175.
    [11]
    熊日华,何灿,马瑞,等.高盐废水分盐结晶工艺及其技术经济分析[J].煤炭科学技术,2018,46(9):37-43.
    [12]
    李东,桑华俭,李杨,等.高盐废水零排放结晶盐资源化工艺分析与比较[J].工业用水与废水,2019,50(6):1-5.
    [13]
    姚敏,于双恩,金政伟,等.煤化工含盐废水纳滤分盐效果研究[J].煤炭加工与综合利用,2020(6):46-50.
    [14]
    蒋路漫,周振,田小测,等.电厂烟气脱硫废水零排放工艺中试研究[J].热力发电,2019,48(1):103-109.
    [15]
    徐志清,赵焰,陆梦楠,等.基于膜法的火电厂废水零排放技术研究及应用[J].中国电机工程学报,2019,39(增刊):148-154.
    [16]
    邵国华,刘艳军,雍骏.纳滤膜处理脱硫废水近零排放资源化实验研究[J].膜科学与技术,2019,39(6):124-128.
    [17]
    江成广.煤化工与矿井水浓盐水资源化利用技术开发[J].煤化工,2019,47(3):13-16.
    [18]
    窦晓春.煤化工高盐水近零排放及分质盐技术研究[D].北京:北京化工大学,2018.
    [19]
    赛世杰,党平,张震,等.高水回收率和高硫酸根截留率的组合纳滤分盐系统:201721223252.6[P].2017-09-22.
    [20]
    李琨.纳滤分离煤化工浓盐水的效能及膜污染机理研究[D].哈尔滨:哈尔滨工业大学,2020.
    [21]
    MIR F Q,SHUKLA A.Negative rejection of NaCl in ultrafiltration of aqueous solution of NaCl and KCl using sodalite octahydrate zeolite-clay charged ultrafiltration membrane[J].Industrial & Engineering Chemistry Research,2010,49.
    [22]
    HAJIBABANIA S,VERLIEFDE A,MC DONALD J A,et al.Fate of trace organic compounds during treatment by nanofiltration[J].Journal of Membrane Science,2011,373:130-139.
    [23]
    KOTRAPPANAVAR N S,HUSSAIN A A,ABASHAR M E E,et al.Prediction of physical properties of nanofiltration membranes for neutral and charged solutes[J].Desalination,2011,280:174-182.
    [24]
    王帅,郭慧枝,袁江龙,等.煤化工高盐废水的纳滤膜分盐效果分析[J].工业用水与废水,2019,50(3):35-40.
    [25]
    张生兰.纳滤+高压反渗透+蒸发结晶组合工艺在煤化工废水零排放中的应用[J].节能环保,2020,10(7):6-8.
    [26]
    夏俊方.纳滤膜在高盐废水零排放应用中的分盐特征研究[J].工业用水与废水,2020,51(1):28-31.
    [27]
    张小亚,苑宏英,石雪莉,等.氯化钠/硫酸钠体系的纳滤分盐试验分析[J].膜科学与技术,2020,40(5):111-117.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (233) PDF downloads(20) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return