Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 39 Issue 8
Jan.  2022
Turn off MathJax
Article Contents
Abstract
References
Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2021  >  39(8): 93-98
LIU Mu, WANG Shao-hua, WANG Tong-chun, DUAN Meng-yuan, SU Ying-qiang, HAN Hui-ming, LIN Xiao-feng, LI Ze-hua. A LARGE-SCALE ENGINEERING APPLICATION OF MICROFILTRATION-NANOFILTRATION COMBINED TECHNOLOGY IN DRINKING WATER ADVANCED TREATMENT[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 151-155. doi: 10.13205/j.hjgc.202107020
Citation: ZHAO Zhong-qi, ZHAO Yan, LANG Lang, HU Xiao-min, SHAN Shi-liang. PREPARATION OF Fe3O4@CNF@Zn-BTC MATERIAL AND ITS PERFORMANCE IN REMOVING PHOSPHORUS FROM WATER[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(8): 93-98. doi: 10.13205/j.hjgc.202108012
shu

PREPARATION OF Fe3O4@CNF@Zn-BTC MATERIAL AND ITS PERFORMANCE IN REMOVING PHOSPHORUS FROM WATER

doi: 10.13205/j.hjgc.202108012

  • 1. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China;

  • 2. Zhicheng Huayuan(Liaoning) Construction Engineering Management Consulting Co., Ltd, Shenyang 110819, China

  • Received Date: 2021-01-06
    Available Online: 2022-01-18
    Abstract
  • In view of the current situation of phosphorus pollution such as excessive phosphorus content in effluent of the secondary sedimentation tank of a sewage plant, a new material Fe3O4@CNF@Zn-BTC was synthesized for specific adsorption of phosphorus. It was made of magnetic nano Fe3O4 particles, carboxylated cellulose nanocrystals and metal organic framework Zn-BTC under general laboratory conditions. The loading of CNF material and MOFs material improved the crystallinity of the composite material, and then improved the rigidity and stability of the composite material, and produced the related bonds between TOCNF surface -COO- and Fe and MOFs, which improved the porosity of the composite material and the rigidity of the material at the same time, and overcome the shortcomings of rigidity and stability of MOFs material to a great extent. Fe3O4@CNF@Zn-BTC was characterized by SEM, FTIR, XRD, XPS and BET, and its removal effect on trace phosphorus in water was discussed under normal temperature and pressure. The results showed that the phosphorus content could be reduced to 0.3~0.5 mg/L by adding a small amount of Fe3O4@CNF@Zn-BTC at normal temperature and pressure for 60 minutes, which met the first class A standard specified in GB 18918—2002, and then the average removal rate was as high as 95%. Compared with other conventional phosphorus removal materials such as activated carbon, Fe3O4@CNF@Zn-BTC material had higher phosphorus removal efficiency, simpler recovery, stronger reproducibility, lower cost and easier synthesis process. Therefore, Fe3O4@CNF@Zn-BTC showed great prospects in improving the water quality of phosphorus polluted environment.
    • FullText(HTML)
    • References(11)
  • [1]
    YIN H B,YAN X W,GU X H.Evaluation of thermally-modified calciumrich attapulgite as a low-cost substrate for rapid phosphorus removal in constructed wetlands[J].Water Research,2017,115(May 15):329-338.
    [2]
    CHEN X,ZHOU W Q,PICKETT S T A,et al.Diatoms are better indicators of urban stream conditions:a case study in Beijing,China[J].Ecological Indicators,2016,60:265-274.
    [3]
    林建伟,王虹,詹艳慧,等.氢氧化镧-天然沸石复合材料对水中低浓度磷酸盐的吸附作用[J].环境科学,2016,37(1):208-219.
    [4]
    SHEN K,ZHANG L,CHEN X D,et al.Ordered macro-microporous metal-organic framework single crystals[J].Science,2018,359:206-210.
    [5]
    DHAKSHINAMOORTHY A,LI Z H,GARCIA H.Catalysis and photo-catalysis by metal organic frameworks[J].Chemical Society Reviews,2018,47:8134-8172.
    [6]
    GUO Y,PENG X S.Mass transport through metal organic framework membranes[J].Science China Materials,2019,62:25-42.
    [7]
    JIANG K,ZHANG L,XIA T,et al.A water-stable fcu-MOF material with exposed amino groups for the multi-functional separation of small molecules[J].Science China Mater,2019,62:1315-1322.
    [8]
    SADAT M E,PATEL R,SOOKOOR J,et al.Effect of spatial confinement on magnetic hyperthermia via dipolar interactions in Fe3O4 nanoparticles for biomedical applications[J].Materials Science & Engineering C,2014,42(sep.):52-63.
    [9]
    EICHHORN S J.Cellulose nanowhiskers:promising materials for advanced applications[J].Soft Matter,2011,7(2):303-315.
    [10]
    KHOSHKAVA V,KMAML M R.Effect of cellulose nanocrystals (CNC) particle morphology on dispersion and rheological and mechanical properties of polypropylene/CNC nanocomposites[J].ACS Applied Materials & Interfaces,2014,6(11):8146-8157.
    [11]
    YANAG R T,YU H Y,SONG M L,et al.Flower-like zinc oxide nanorod clusters grown on spherical cellulose nanocrystals via simple chemical precipitation method[J].Cellulose,2016,23(3):1871-1884.
    • Relative Articles

  • Relative Articles

    [1]LIU Wenkai, WANG Kunpeng, WANG Xiaomao, HUANG Xia. HIGHLY SELECTIVE NANOFILTRATION SEPARATION TECHNOLOGY FACILITATES RESOURCE EXTRACTION AND RECOVERY FROM HIGH SALINITY ENVIRONMENTS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(9): 29-41. doi: 10.13205/j.hjgc.202409003
    [2]KONG Wanting, LI Xuesong, WANG Zhiwei. RECENT ADVANCES IN ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY TECHNOLOGY FOR CHARACTERIZATION OF FOULING AND MASS TRANSFER PROCESSES ON NANOFILTRATION AND REVERSE OSMOSIS MEMBRANES[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(9): 51-62. doi: 10.13205/j.hjgc.202409005
    [3]YANG Yiqing, ZHANG Yuxiang, ZHANG Yufei, LI Yaohuang, WU Mingyu, ZHANG Nan, CHEN Xiaoqiang. GAS PRODUCTION AND LEACHATE PROPERTIES OF MUNICIPAL SOLID WASTE WITH CONTINUOUS INJECTION OF CONCENTRATED NF LEACHATE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(3): 148-154. doi: 10.13205/j.hjgc.202303020
    [4]ZENG Guangshu, ZHOU Zhenchao, LIN Yanhan, GE Ziye, LIN Zejun, SHUAI Xinyi, ZHOU Jinyu, CHEN Hong. DISTRIBUTION OF ANTIBIOTIC RESISTANCE GENES AND EXPOSURE RISK IN DRINKING WATER: A REVIEW[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(9): 114-123. doi: 10.13205/j.hjgc.202309014
    [5]FENG Guizhen, HUANG Lin, FAN Shixiu. EFFECT OF ORGANIC MATTER CHARACTERISTICS IN RAW WATER ON NANOFILTRATION MEMBRANE FOULING[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(2): 1-6,42. doi: 10.13205/j.hjgc.202302001
    [6]ZHOU Kang, WANG Zhen-kai, ZHANG Gui-cheng, CHEN Xin-an, CHENG Yan, LUO Gang, SUN Sheng-peng. BIODEGRADATION AND TERTIARY TREATMENT EFFICIENCIES OF TYPICAL PHARMACEUTICAL MICROPOLLUTANTS BY MBBR AND UVC-BASED ADVANCED OXIDATION PROCESSES[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 37-43. doi: 10.13205/j.hjgc.202205006
    [7]CHANG Jia-yu, YU Shui-li, LIU Hua-fa, GAO Le, LIU Gui-cai. EVOLUTION IN MEMBRANE PERFORMANCE OF GROUNDWATER SOURCED WATERWORKS DURING LONG-TERM OPERATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 73-79. doi: 10.13205/j.hjgc.202107008
    [8]YANG Zhe, DAI Ruo-bin, WEN Yue, WANG Li, WANG Zhi-wei, TANG Chu-yang. RECENT PROGRESS OF NANOFILTRATION MEMBRANE IN WATER TREATMENT AND WATER REUSE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 1-12. doi: 10.13205/j.hjgc.202107001
    [9]XU Lan, ZHOU Zhen-chao, ZHU Lin, LIU Yang, SHUAI Xin-yi, LIN Ze-jun, CHEN Hong. REMOVAL EFFICIENCY OF ANTIBIOTIC RESISTOME IN ACTIVATED CARBON DRINKING WATER PURIFIERS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(6): 27-33. doi: 10.13205/j.hjgc.202106005
    [10]SAI Shi-jie, LI Mai-jun, DANG Ping, LIU Hui, ZHANG Na, HUANG Xia. APPLICATION OF HIGH SEPARATION NANOFILTRATION PROCESS IN ZERO DISCHARGE OF HIGH SALT WASTEWATER FROM COAL CHEMICAL INDUSTRY[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 173-178. doi: 10.13205/j.hjgc.202107024
    [11]YANG Shu-jun, ZHANG Chen, HE Jun, XIONG Jian-ying, LI Xue-ting, HUANG Xiao-wen. ENGINEERING APPLICATION OF NANOFILTRATION & THREE-LEVELS REDUCTION OF NANOFILTRATION CONCENTRATE TECHNOLOGY FOR ADVANCED TREATMENT OF LANDFILL LEACHATE[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(6): 81-87,114. doi: 10.13205/j.hjgc.202006013
    [12]YANG Pei-lin, WANG Ji, WANG Zhi-kang, ZHANG Guang-long, QIN Fan-xin. PHTHALATE ESTERS POLLUTION CHARACTERISTICS AND HEALTH RISK OF DRINKING WATER SOURCES IN GUIYANG[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 172-177,27. doi: 10.13205/j.hjgc.202001028
    [13]FU Rao, ZHANG Wen-long, FENG Jiang-tao, YAN Wei. SYNTHESIZATION OF ANATASE TiO2 SYNTHESIZED AT LOW TEMPERATURE, AND ITS ADSORPTION PERFORMANCE ON FLUORIDE ION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(2): 70-76. doi: 10.13205/j.hjgc.202002009
    • Supplements(0)
    • Cited By

  • Cited by

    Periodical cited type(0)

    Other cited types(3)

  • Created with Highcharts 5.0.7Amount of accessChart context menuAbstract Views, HTML Views, PDF Downloads StatisticsAbstract ViewsHTML ViewsPDF Downloads2024-052024-062024-072024-082024-092024-102024-112024-122025-012025-022025-032025-04020406080100
    Created with Highcharts 5.0.7Chart context menuAccess Class DistributionFULLTEXT: 8.2 %FULLTEXT: 8.2 %META: 89.8 %META: 89.8 %PDF: 2.0 %PDF: 2.0 %FULLTEXTMETAPDF
    Created with Highcharts 5.0.7Chart context menuAccess Area Distribution其他: 11.3 %其他: 11.3 %China: 0.8 %China: 0.8 %[]: 0.2 %[]: 0.2 %上海: 5.4 %上海: 5.4 %东莞: 1.7 %东莞: 1.7 %临汾: 0.2 %临汾: 0.2 %临沂: 0.2 %临沂: 0.2 %乌鲁木齐: 0.2 %乌鲁木齐: 0.2 %伊犁: 0.2 %伊犁: 0.2 %佛山: 0.6 %佛山: 0.6 %保定: 0.8 %保定: 0.8 %信阳: 0.6 %信阳: 0.6 %北京: 7.6 %北京: 7.6 %十堰: 1.4 %十堰: 1.4 %南京: 2.6 %南京: 2.6 %厦门: 0.3 %厦门: 0.3 %台州: 1.4 %台州: 1.4 %合肥: 0.3 %合肥: 0.3 %哈尔滨: 0.6 %哈尔滨: 0.6 %唐山: 0.2 %唐山: 0.2 %嘉兴: 1.6 %嘉兴: 1.6 %大连: 0.6 %大连: 0.6 %天津: 5.0 %天津: 5.0 %太原: 0.5 %太原: 0.5 %宁波: 0.9 %宁波: 0.9 %宜春: 0.5 %宜春: 0.5 %宣城: 0.8 %宣城: 0.8 %宿州: 0.3 %宿州: 0.3 %常州: 0.8 %常州: 0.8 %常德: 0.2 %常德: 0.2 %广州: 0.6 %广州: 0.6 %张家口: 0.3 %张家口: 0.3 %徐州: 0.8 %徐州: 0.8 %成都: 0.8 %成都: 0.8 %扬州: 2.3 %扬州: 2.3 %无锡: 0.2 %无锡: 0.2 %昆明: 0.3 %昆明: 0.3 %晋城: 0.3 %晋城: 0.3 %朝阳: 0.2 %朝阳: 0.2 %杭州: 1.7 %杭州: 1.7 %武汉: 1.4 %武汉: 1.4 %江门: 0.9 %江门: 0.9 %沈阳: 0.2 %沈阳: 0.2 %济南: 0.5 %济南: 0.5 %济源: 0.2 %济源: 0.2 %海口: 0.5 %海口: 0.5 %清远: 0.2 %清远: 0.2 %温州: 1.4 %温州: 1.4 %湖州: 0.5 %湖州: 0.5 %漯河: 11.2 %漯河: 11.2 %烟台: 0.2 %烟台: 0.2 %盐城: 0.3 %盐城: 0.3 %石家庄: 0.6 %石家庄: 0.6 %秦皇岛: 0.2 %秦皇岛: 0.2 %绍兴: 0.2 %绍兴: 0.2 %舟山: 0.2 %舟山: 0.2 %芒廷维尤: 6.2 %芒廷维尤: 6.2 %芝加哥: 0.6 %芝加哥: 0.6 %苏州: 0.2 %苏州: 0.2 %萍乡: 0.2 %萍乡: 0.2 %衡阳: 0.3 %衡阳: 0.3 %衢州: 1.1 %衢州: 1.1 %西宁: 9.5 %西宁: 9.5 %西安: 0.8 %西安: 0.8 %贵阳: 0.2 %贵阳: 0.2 %运城: 1.6 %运城: 1.6 %遵义: 0.2 %遵义: 0.2 %邯郸: 0.5 %邯郸: 0.5 %郑州: 1.1 %郑州: 1.1 %重庆: 0.6 %重庆: 0.6 %长沙: 3.0 %长沙: 3.0 %长治: 0.2 %长治: 0.2 %阳泉: 0.3 %阳泉: 0.3 %青岛: 0.5 %青岛: 0.5 %其他China[]上海东莞临汾临沂乌鲁木齐伊犁佛山保定信阳北京十堰南京厦门台州合肥哈尔滨唐山嘉兴大连天津太原宁波宜春宣城宿州常州常德广州张家口徐州成都扬州无锡昆明晋城朝阳杭州武汉江门沈阳济南济源海口清远温州湖州漯河烟台盐城石家庄秦皇岛绍兴舟山芒廷维尤芝加哥苏州萍乡衡阳衢州西宁西安贵阳运城遵义邯郸郑州重庆长沙长治阳泉青岛

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (168) PDF downloads(3) Cited by(3)
    Proportional views
    Related

    Journal Online

    Authors' Center

    Links

    Copyright © 《工业建筑》杂志社有限公司 京ICP备11033253号-1

    Supported by: Beijing Renhe Information Technology Co. Ltd     百度统计

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return