PREPARATION OF A FENTON-LIKE Cu-Co-Fe METALLIC OXIDE CATALYST AND ITS DEGRADATION PERFORMANCE ON TYPICAL REFRACTORY ORGANICS

JIANG Shu-wen; WEI Shi-cheng; WANG Ting; LU Yao-bin; LIU Guang-li; LUO Hai-ping; ZHANG Ren-duo

doi:10.13205/j.hjgc.202111009

Volume 39 Issue 11

Jan. 2022

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JIANG Shu-wen, WEI Shi-cheng, WANG Ting, LU Yao-bin, LIU Guang-li, LUO Hai-ping, ZHANG Ren-duo. PREPARATION OF A FENTON-LIKE Cu-Co-Fe METALLIC OXIDE CATALYST AND ITS DEGRADATION PERFORMANCE ON TYPICAL REFRACTORY ORGANICS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 77-82,118. doi: 10.13205/j.hjgc.202111009

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PREPARATION OF A FENTON-LIKE Cu-Co-Fe METALLIC OXIDE CATALYST AND ITS DEGRADATION PERFORMANCE ON TYPICAL REFRACTORY ORGANICS

doi: 10.13205/j.hjgc.202111009

1. CSG Power Generation Company, Guangzhou 510630, China;
2. School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510006, China;
3. Environmental Protection Research Institute of Guangxi Zhuang Autonomous Region, Nanning 530022, China

Received Date: 2021-06-14
Available Online: 2022-01-26

Abstract

Abstract

The aim of this study was to enhance the typical refractory organics degradation in the wastewater treatment by using A Fenton-like catalyst, which was synthesized and tested for the antipyrine and dyes degradation. The results demonstrated that the metallic oxide catalyst, Cu_1-xCo_xFe₂O₄ prepared by the hydrothermal method had a good crystal structure with the specific surface area of 147.3~187.5 m²/g, and the saturation magnetization value of 17.2~62.3 EMU/g. With the Co content increasing, the catalytic activity of the catalysts increased significantly. The optimized catalyst of Cu_0.25Co_0.75Fe₂O₄ had the applicable pH range of 7~9. With the initial antipyrine concentration of 50 mg/L, the catalyst dosage of 0.7 g/L and H₂O₂ dosage of 150 mmol/L, the antipyrine removal reached 93.1% at the initial pH=7 and 94.7% at the initial pH=9, respectively. Different types of refractory organic compounds, such as rhodamine B and acid orange Ⅱ, could also be effectively degraded with the catalyst. After 5 cycles of magnetic recovery and reuse of the catalyst, the antipyrine removal could be kept 80% above, indicating that the catalyst had good stability and reusability. The Fenton-like catalyst synthesized in this study provided scientific basis for efficient removal of refractory organic compounds from wastewater.
- antipyrine,
- Fenton-like catalyst,
- metallic oxide,
- removal

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References(27)

References

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