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Volume 39 Issue 11
Jan.  2022
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DAI Li-ping, ZHU Han-quan, KE Xiong, CHEN Ri-yao, LIU Yao-xing. REMOVAL OF HEXAVALENT CHROMIUM FROM AQUEOUS SOLUTION USING BIPOLAR MEMBRANE ELECTRODIALYSIS TECHNIQUE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 89-95. doi: 10.13205/j.hjgc.202111011
Citation: DAI Li-ping, ZHU Han-quan, KE Xiong, CHEN Ri-yao, LIU Yao-xing. REMOVAL OF HEXAVALENT CHROMIUM FROM AQUEOUS SOLUTION USING BIPOLAR MEMBRANE ELECTRODIALYSIS TECHNIQUE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 89-95. doi: 10.13205/j.hjgc.202111011

REMOVAL OF HEXAVALENT CHROMIUM FROM AQUEOUS SOLUTION USING BIPOLAR MEMBRANE ELECTRODIALYSIS TECHNIQUE

doi: 10.13205/j.hjgc.202111011
  • Received Date: 2020-08-21
    Available Online: 2022-01-26
  • In the present work, a bipolar membrane electrodialysis(BMED) was used to remove and recover hexavalent chromium[Cr(Ⅵ)] in form of H2CrO4 from the simulated wastewater. The effects of electrolyte concentration in wastewater, current density, and initial Cr(Ⅵ) concentration on removal of Cr(Ⅵ) were investigated. The experimental results showed that the electrolyte concentration of 1 g/L and current density of 2 mA/cm2 were the optimal experimental conditions when initial Cr(Ⅵ) concentration was 500 mg/L, and the removal rate was 97.6%. A higher current efficiency (CE) and a lower specific energy consumption (SEC) were obtained when two and three wastewater compartment were equipped in the BMED system and Cr(Ⅵ) removal rates in all wastewater compartments were higher than 97.0%. With the increase in the number of equipped wastewater compartment from one to two and three in the BMED system, CE increased from 31.5% to 125.8% and 284.4%, SEC decreased from 19.49×10-3 to 7.76×10-3, 4.17×10-3 kW·h/g Cr(Ⅵ), respectively. Experimental results showed that the BMED was an effective method for the removal and recovery of Cr(Ⅵ) from aqueous solution.
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  • [1]
    LONG B B, YE J E, YE Z, et al. Cr(Ⅵ) removal by Penicillium oxalicum SL2:reduction with acidic metabolites and form transformation in the mycelium[J]. Chemosphere, 2020, 253:126731.
    [2]
    ZHANG L, NIU W Y, SUN J, et al. Efficient removal of Cr(Ⅵ) from water by the uniform fiber ball loaded with polypyrrole:static adsorption, dynamic adsorption and mechanism studies[J]. Chemosphere, 2020, 248:126102.
    [3]
    ZHAO Z Y, AN H, LIN J, et al. Progress on the photocatalytic reduction removal of chromium contamination[J]. Chemical Record, 2019, 19(5):873-882.
    [4]
    ZHENG Y R, LIU S G, DAI C M, et al. Study on the influence mechanism of underground mineral element Fe(Ⅱ) on Cr(Ⅵ) transformation under subsurface and groundwater interaction zones[J]. Environmental Sciences Europe, 2020, 32(1):62.
    [5]
    PARANI S, OLUWAFEMI O S. Selective and sensitive fluorescent nanoprobe based on AgInS2-ZnS quantum dots for the rapid detection of Cr (Ⅲ) ions in the midst of interfering ions[J]. Nanotechnology, 2020, 31(39):395501.
    [6]
    TABATABAEI S, RAD B F, BAGHDADI M. Semicontinuous enhanced electroreduction of Cr(Ⅵ) in wastewater by cathode constructed of copper rods coated with palladium nanoparticles followed by adsorption[J]. Chemosphere, 2020, 251:126309.
    [7]
    XIA S P, SONG Z L, JEYAKUMAR P, et al. A critical review on bioremediation technologies for Cr(Ⅵ)-contaminated soils and wastewater[J]. Critical Reviews in Environmental Science and Technology, 2019, 49(12):1027-1078.
    [8]
    张立剑, 周睿. 活性炭材料对Cr(Ⅵ)的吸附研究[J]. 水处理技术, 2018, 44(8):49-52.
    [9]
    石林, 段睿, 杨翠英, 等. 常温还原铁氧体法处理含铬废水[J]. 环境工程学报, 2015, 9(8):3883-3888.
    [10]
    梅丽娟, 殷仕学, 朴哲, 等. 一种耐Cr(Ⅵ)微生物筛选新方法[J]. 环境科学与技术, 2019, 42(5):41-45.
    [11]
    ZHENG Y Q, CHENG B, YOU W, et al. 3D hierarchical graphene oxide-NiFe LDH composite with enhanced adsorption affinity to Congo red, methyl orange and Cr(Ⅵ) ions[J]. Journal of Hazardous Materials, 2019, 369:214-225.
    [12]
    冯西平, 冯婷希. 亚硫酸氢钠处理电镀废水中铬的实验研究[J]. 电镀与环保, 2018, 38(1):64-67.
    [13]
    MOHAMED A, YU L, FANG Y, et al. Iron mineral-humic acid complex enhanced Cr(Ⅵ) reduction by Shewanella oneidensis MR-1[J]. Chemosphere, 2020, 247:125902.
    [14]
    CAI Y Y, HAN Z P, LIN X C, et al. Study on removal of phosphorus as struvite from synthetic wastewater using a pilot-scale electrodialysis system with magnesium anode[J]. Science of the Total Environment, 2020, 726:138221.
    [15]
    陈日耀. 纳米SiO2改性海藻酸钠/壳聚糖双极膜的制备与表征[J]. 高校化学工程学报, 2012, 26(1):160-164.
    [16]
    LIU Y X, KE X, ZHU H Q, et al. Treatment of raffinate generated via copper ore hydrometallurgical processing using a bipolar membrane electrodialysis system[J]. Chemical Engineering Journal, 2020, 382:122956.
    [17]
    HERRERO-GONZALEZ M, DIAZ-GURIDI P, DOMINGUEZ-RAMOS A, et al. Highly concentrated HCl and NaOH from brines using electrodialysis with bipolar membranes[J]. Separation and Purification Technology, 2020, 242:116785.
    [18]
    İPEKÇI D, KABAY N, BUNANI S, et al. Application of heterogeneous ion exchange membranes for simultaneous separation and recovery of lithium and boron from aqueous solution with bipolar membrane electrodialysis (EDBM)[J]. Desalination, 2020, 479:114313.
    [19]
    KRAVTSOV V, KULIKOVA I, MIKHAYLIN S, et al. Alkalinization of acid whey by means of electrodialysis with bipolar membranes and analysis of induced membrane fouling[J]. Journal of Food Engineering, 2020, 277:109891.
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