SOLIDIFICATION/STABILIZATION OF As IN SOIL USING BIOCHAR LOADED WITH FERRIC MANGANESE BINARY OXIDES(FMBO)

LI Geng; LI Haibo; LI Yinghua; CHEN Xi

doi:10.13205/j.hjgc.202203018

Volume 40 Issue 3

Mar. 2022

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2022 > 40(3): 118-125

Ding Jing, Lei Yang. RESEARCH ON SEMI-AEROBIC BIOREACTOR LANDFILL SYSTEM:LEACHATE CHARACTERISTICS[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(3): 6-10. doi: 10.13205/j.hjgc.201503002

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LI Geng, LI Haibo, LI Yinghua, CHEN Xi. SOLIDIFICATION/STABILIZATION OF As IN SOIL USING BIOCHAR LOADED WITH FERRIC MANGANESE BINARY OXIDES(FMBO)[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(3): 118-125. doi: 10.13205/j.hjgc.202203018

Ding Jing, Lei Yang. RESEARCH ON SEMI-AEROBIC BIOREACTOR LANDFILL SYSTEM:LEACHATE CHARACTERISTICS[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(3): 6-10. doi: 10.13205/j.hjgc.201503002

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SOLIDIFICATION/STABILIZATION OF As IN SOIL USING BIOCHAR LOADED WITH FERRIC MANGANESE BINARY OXIDES(FMBO)

doi: 10.13205/j.hjgc.202203018

School of Resources&Civil Engineering, Northeastern University, Shenyang 110819, China

Received Date: 2021-10-09
Available Online: 2022-07-07

Abstract

Abstract

The chemical forms of arsenic (As) in soil environment were sophisticated, and there was a defect in the treatment of different forms of As with conventional solidification and stabilization materials. We integrated the surface adsorption of biochar (BC), pore filling, electrostatic attraction, complexation and co-precipitation oxidation-reduction of ferric manganese binary oxides (FMBO), then a new functional material BC_FM was prepared and stabilized with Portland cement. The effect of key parameters on treatment effect was discussed by response surface method. The results showed that when the ratio of BC_FM to Portland cement was 9.88% and 8.80%, and the curing time was 20.53 days, the minimum leaching concentration of As was 0.055 mg/L, the exchangeable state proportion was reduced from 4% to 0.5%, the residual state proportion was increased from 77% to 87%, and the unconfined compressive strength exceeded 50 kPa. It was speculated that the curing and stabilization mechanism of BC_FM was the combination of Fe-O(H)-As coprecipitation, Mn-O(H)-As oxidation and BC function. The results of this study provide a new technical scheme for long-term curing and stabilization of As.
- heavy metal pollution soil,
- solidification/stabilization,
- biochar,
- ferric manganese binary oxides,
- response surface analysis

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References

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