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Volume 40 Issue 5
Jul.  2022
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JING Xiu-yan, WANG Wen-ji, DONG Qiang-fei, QIAO Le-le, DENG Yue-hua. ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 67-74. doi: 10.13205/j.hjgc.202205010
Citation: JING Xiu-yan, WANG Wen-ji, DONG Qiang-fei, QIAO Le-le, DENG Yue-hua. ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 67-74. doi: 10.13205/j.hjgc.202205010

ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS

doi: 10.13205/j.hjgc.202205010
  • Received Date: 2021-09-02
    Available Online: 2022-07-02
  • In this paper, the montmorillonite was saturated with five metal cations by the impregnation method to obtain iron-based montmorillonite(Fe-MT), copper-based montmorillonite(Cu-MT), potassium-based montmorillonite(K-MT), sodium-based montmorillonite(Na-MT), and calcium-based montmorillonite(Ca-MT). The adsorption behavior, main influencing factors, and adsorption mechanism of propranolol on these montmorillonites saturated with five interlayer metal cations were studied. The results showed that the five metal cations saturated montmorillonite had high adsorption capacity for propranolol, in the sequence of Fe-MT>Cu-MT>K-MT>Na-MT>Ca-MT. The increase of adsorption capacity at pH of 3~9 was due to the weakening of the competitiveness of adsorption sites of H+ and propranolol on montmorillonite saturated with metal cations. The decrease of adsorption capacity at pH of 9~11 resulted from propranolol mainly existed in molecular state and the decrease of electrostatic attraction. The presence of K+, Na+, and Ca2+ could inhibit the absorption of propranolol. The addition of humic acid could promote the adsorption of propranolol, but its effect decreased with the increase of humic acid concentration, and even adsorption inhibition occured. Langmuir isothermal adsorption model and the pseudo-second-order kinetic equation could better describe the adsorption process of propranolol. This study was expected to provide a theoretical basis for a comprehensive understanding of the migration and transformation of propranolol in soil environment.
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