MODIFICATION OF GEHLENITE CERAMSITE AND ITS TREATMENT EFFICIENCY ON MANGANESE-CONTAINING WASTEWATER

QIN Juan; YANG Shangwen; BAO Yuqing; WU Yujie; CAI Lin; WEN Qian

doi:10.13205/j.hjgc.202208006

Volume 40 Issue 8

Nov. 2022

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2022 > 40(8): 47-54

MOU Zijie, LI Junqi, LI Xiaojing. RESEARCH PROGRESS ON APPLICATION OF GEOSYNTHETICS IN GREEN STORMWATER INFRASTRUCTURE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(8): 206-212. doi: 10.13205/j.hjgc.202208029

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QIN Juan, YANG Shangwen, BAO Yuqing, WU Yujie, CAI Lin, WEN Qian. MODIFICATION OF GEHLENITE CERAMSITE AND ITS TREATMENT EFFICIENCY ON MANGANESE-CONTAINING WASTEWATER[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(8): 47-54. doi: 10.13205/j.hjgc.202208006

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MODIFICATION OF GEHLENITE CERAMSITE AND ITS TREATMENT EFFICIENCY ON MANGANESE-CONTAINING WASTEWATER

doi: 10.13205/j.hjgc.202208006

Nantong Key Laboratory of Intelligent and New Energy Materials, School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

Received Date: 2021-10-07
Publish Date: 2022-11-08

Abstract

Abstract

Gehlenite ceramsites were prepared through calcination, with industrial solid wastes lime mud and fly ash as the raw materials. Then, the ceramsites were modified by hydrothermal reaction of NaOH solution and finally applied to the adsorption of manganese-containing wastewater. The ceramsites before and after the modification were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), to explore the modification mechanism. Under different modification conditions, such as the concentration of NaOH solution and the temperature of the hydrothermal reaction, the adsorption efficiency of Mn²⁺ by the ceramsites was detected. Thus, the optimum modification conditions and the adsorption mechanism of Mn²⁺ were determined. The results showed that after modification, the main mineral phase of the ceramsites was still gehlenite, but a new phase, Ca(OH)₂ was generated because of the activation of the partial calcium element. Accordingly, the alkalinity of the ceramsites was increased, significantly improving the removal rate of Mn²⁺ and shortening the adsorption equilibrium time. The concentrations of NaOH solution of 4, 3 mol/L and the temperature of 160 ℃ were the optimum modification conditions of the two ceramsites, respectively. For the adsorption of Mn²⁺ by the modified ceramsites, the adsorption equilibrium was achieved at 10~15 min, and the removal rate was close to 100%. During the adsorption process, Mn²⁺ in solution was reacted with OH^- released from the ceramsites to form white Mn(OH)₂ and then quickly oxidized to brown MnO(OH)₂, which was evenly adsorbed on the surface of the ceramsites. This technology not only realized the utilization of solid wastes, but also achieved the purpose of Treating Waste with Waste.
- gehlenite,
- hydrothermal modification,
- concentration of NaOH,
- temperature,
- Mn²⁺ removal

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References

[1]	AN Q,ZHANG C Y,ZHAO B,et al.Insight into synergies between Acinetobacter sp.AL-6 and pomelo peel biochar in a hybrid process for highly efficient manganese removal[J].The Science of the Total Environment,2021,793:148609.
[2]	朱文雪,陈莹莹,张彬,等.水中Mn(Ⅲ)介导的头孢哌酮钠转化机制[J].环境化学,2020,39(8):2206-2216.
[3]	BEUKES N J,SWINDELL E,WABO H.Manganese deposits of Africa[J].Episodes,2016,39(2):285.
[4]	TAN S G,GAO C H,YUAN H,et al.An antiperovskite compound with multifunctional properties:Mn₃PdN[J].Journal of Solid State Chemistry,2021,302:122389.
[5]	ALI Z,SHAFIQ M,ASADABADI S J,et al.Magneto-electronic studies of anti-perovskites NiNMn₃ and ZnNMn₃[J].Computational Materials ence,2014,81(2):141-145.
[6]	AHSAN M Z,ISLAM M A,KHAN F A.Effects of sintering temperature on ac conductivity,permittivity,and permeability of manganese doped cobalt ferrite nanoparticles[J].Results in Physics,2020,19:103402.
[7]	DENG Y L,SHU J C,LEI T Y,et al.A green method for Mn²⁺ and NH₄⁺-N removal in electrolytic manganese residue leachate by electric field and phosphorus ore flotation tailings[J].Separation and Purification Technology,2021,270(4):118820.
[8]	DROKE E A,LOERCH S C.Effects of parenteral selenium and vitamin E on performance,health and humoral immune response of steers new to the feedlot environment[J].Journal of Animal Science,1989,67(5):1350-1359.
[9]	SHU J C,WU H P,CHEN M J,et al.Fractional removal of manganese and ammonia nitrogen from electrolytic metal manganese residue leachate using carbonate and struvite precipitation[J].Water Research,2018,153(4):229-238.
[10]	白凤明,黄廷林,程亚.无氧条件下复合锰氧化膜去除地下水中高浓度锰[J].环境工程学报,2019,13(4):878-884.
[11]	马文婕,陈天虎,陈冬,等.δ-MnO₂/沸石纳米复合材料同时去除地下水中的铁锰氨氮[J].环境科学,2019,40(10):4553-4561.
[12]	唐章程,黄廷林,胡瑞柱,等.结晶造粒流化床同步去除水中铁、锰及硬度的中试实验[J].环境工程学报,2018,12(11):3090-3098.
[13]	GONG C H,WANG B,LIU B,et al.Facile in situ synthesis of nickel/cellulose nanocomposites:mechanisms,properties and perspectives[J].Cellulose,2014,21(6):4359-4368.
[14]	BAO X,WU Q L,TIAN J Y,et al.Fouling mechanism of forward osmosis membrane in domestic wastewater concentration:role of substrate structures[J].Chemical Engineering Journal,2019,370:262-273.
[15]	李静,鲍东杰,王向宁,等.磁性纳米复合吸附剂PFM对铜的吸附性能与吸附机理研究[J].环境工程,2020,38(5):84-88.
[16]	刘光明,卫文豪,杨开亮,等.水体中Mn(Ⅱ)的去除——氧化结合吸附法[J].上海海事大学学报,2020,41(2):123-126.
[17]	唐朝春,陈惠民,刘名,等.ZnAl和MgAl水滑石吸附废水中磷的研究进展[J].化工进展,2015,34(1):245-251.
[18]	魏婷,牛丽君,张光明,等.三元复合吸附剂Ce-Zr-Zn对水中低浓度磷的吸附性能及其机理[J].环境工程学报,2020,14(11):2938-2945.
[19]	曾辉平,于亚萍,吕赛赛,等.基于铁锰泥的除砷颗粒吸附剂制备及其比较[J].环境科学,2019,40(11):5002-5008.
[20]	ZENG Q,WANG Y X,XIE S H,et al.Drinking-water disinfection by-products and semen quality:a cross-sectional study in china[J].Environ Health Perspect,2014,122(7):741-746.
[21]	李鹏飞,毛林清,陈胡星.陶粒对铬的固化及其机制研究[J].环境工程,2018,36(11):118-122.
[22]	向洋,张翔凌,雷雨,等.不同合成条件对ZnAl-LDHs覆膜改性生物陶粒除磷效果的影响[J].环境科学,2018,39(5):2184-2194.
[23]	赵媛媛,刘丹妮,戴友芝,等.给水厂残泥免烧陶粒对Pb与Cd的吸附特征[J].环境科学研究,2019,32(7):1250-1258.
[24]	黄志华,杨佘维,汪永红,等.基于新型陶粒催化剂的H₂O₂/O₃多相催化氧化体系降解刚果红的研究[J].环境工程,2016,34(7):82-87.
[25]	HU X F,JARNERUD T,KARASEV A,et al.Utilization of fly ash and waste lime from pulp and paper mills in the argon oxygen decarburization process[J].Journal of Cleaner Production,2020,261:121182.
[26]	彭晓月,宋菊林.造纸厂碱回收白泥原位改性固化处理技术[J].施工技术,2018,47(增刊4):1127-1130.
[27]	刘定平,黄俊钦,夏松.造纸白泥旋流雾化脱硫除尘一体化技术试验研究[J].工业炉,2019,41(3):11-16.
[28]	LIU J,SHI N,WANG T,et al.Significant enhancement of VOCs conversion by facile mechanochemistry coupled MnO₂ modified fly ash:mechanism and application[J].Fuel,2021,304(33):121443.
[29]	SADARANG J,NAYAK R K.Utilization of fly ash as an alternative to silica sand for green sand mould casting process[J].Journal of Manufacturing Processes,2021,68(3):1553-1561.
[30]	宋萌珠,KAEWMEE P,JO G,等.聚合物改性粉煤灰制备多孔复合材料及其性能研究[J].环境工程,2020,38(8):27-33 ,95.
[31]	QIN J,CUI C,CUI X Y,et al.Preparation and characterization of ceramsite from lime mud and coal fly ash[J].Construction and Building Materials,2015,5(oct.1):10-17.
[32]	YATONGCHAI C,THAVORNYUTIKARN B.Conversion of lime mud waste to hydroxyapatite biomaterials[J].Materials Chemistry and Physics,2021,5:124544.
[33]	ZHANG L,ZHANG L,DONG X,et al.The effect and mechanism of Si/Al ratio on microstructure of zeolite modified ceramsite derived from industrial wastes[J].Microporous and Mesoporous Materials,2021,311:110667.
[34]	MI H C,YI L S,WU Q,et al.Preparation of high-strength ceramsite from red mud,fly ash,and bentonite[J].Ceramics International,2021,47(13):18218-18229.
[35]	LI X G,WANG P Q,QIN J Y,et al.Mechanical properties of sintered ceramsite from iron ore tailings affected by two-region structure[J].Construction and Building Materials,2020,240:117919.
[36]	QIN J,YANG C M,CUI C,et al.Ca²⁺ and OH^- release of ceramsites containing anorthite and gehlenite prepared from waste lime mud[J].Journal of Environmental Sciences,2016,47(9):91-99.

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