FUNDAMENTAL RESEARCH ON CO<sub>2</sub> CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL

LI Han-fei; WU Wei; BAI Lu-lu

doi:10.13205/j.hjgc.202209001

Volume 40 Issue 9

Nov. 2022

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LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO2 CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001

Citation:

LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO₂ CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001

LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO2 CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001

Citation:

LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO₂ CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001

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FUNDAMENTAL RESEARCH ON CO₂ CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL

doi: 10.13205/j.hjgc.202209001

Department of Resources and Environment, School of Metallurgy, Northeastern University, Shenyang 110819, China

Received Date: 2022-02-16
Available Online: 2022-11-09

Abstract

Abstract

To promote the implementation of China's Dual Carbon Goals policy and expand the recycling technology of CO₂, the experimental exploration of CO₂ synthesis of diesel was carried out in this paper. Using iron-based catalyst and CO₂ as the raw material, the feasibility study of CO₂ hydrogenation synthesis of diesel was discussed. Based on verifying the feasibility of CO₂ synthesis to derive diesel, we further investigated the effect of catalyst carrier's acidity and alkalinity, catalyst component Fe content and additive addition on catalytic activity. The research showed that the main components and component distribution characteristics of the synthesis products of CO₂ hydrogenation were highly consistent with those of commercial diesel. The iron-based catalyst supported by γ-Al₂O₃ could effectively promote the reverse water gas reaction of CO₂ and the Fenton reaction. As a catalyst promoter, the addition of potassium had a good auxiliary effect on improving the catalytic activity. The reaction temperature and pressure were the controllable factors of the reaction, and the pressure was the decisive factor. The study found that only when the pressure was higher than 1.6 MPa, the reaction smoothly occured in the temperature range above 250 ℃. In addition, the acidity and alkalinity of the carrier, the content of the catalytic component Fe and the auxiliary K had a crucial influence on the composition characteristics of the synthesized products and similarity with diesel.
- CO₂ hydrogenation,
- iron-based catalyst,
- carbon neutrality,
- hydrocarbon,
- derivative diesel

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References(37)

References

[1]	徐敏杰,朱明辉,陈天元,等.CO₂ 高值化利用:CO₂ 加氢制甲醇催化剂研究进展[J].化工进展,2020,40(2):565-576.
[2]	MARTIN O,MARTÍN A J,MONDELLI C,et al.Indium oxide as a superior catalyst for methanol synthesis by CO₂ hydrogenation[J].Angewandte Chemie,2016,128(21):6369-6373.
[3]	JIANG K,ASHWORTH P,ZHANG S Y,et al.China’s carbon capture,utilization and storage (CCUS) policy:a critical review[J].Renewable and Sustainable Energy Reviews,2020,119:109601.
[4]	何良年.二氧化碳化学:碳捕集,活化与资源化[J].科学通报,2021,66(7):713-715.
[5]	GAO S,LIN Y,JIAO X C,et al.Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel[J].Nature,2016,529(7584):68-71.
[6]	苏豪,查永进,王眉山,等.CCS 与 CCUS 碳减排优劣势分析[J].环境工程,2015,33(增刊1):1044-1047,1053.
[7]	薛博,刘勇,王沉,等.碳捕获,封存与利用技术及煤层封存 CO₂ 研究进展[J].化学世界,2020,61(4):294-297.
[8]	LIN J H,MA C P,WANG Q,et al.Enhanced low-temperature performance of CO₂ methanation over mesoporous Ni/Al₂O₃-ZrO₂ catalysts[J].Applied Catalysis B:Environmental,2019,243:262-272.
[9]	RONDA-LLORET M,ROTHENBERG G,SHIJU N R.A critical look at direct catalytic hydrogenation of carbon dioxide to olefins[J].ChemSusChem,2019,12(17):3896-3914.
[10]	WANG Y,GAO W Z,KAZUMI S,et al.Direct and oriented conversion of CO₂ into value-added aromatics[J].Chemistry-A European Journal,2019,25(20):5149-5153.
[11]	LI H Z,REN S J,ZHANG S X,et al.The high-yield direct synthesis of dimethyl ether from CO₂ and H₂ in a dry reaction environment[J].Journal of Materials Chemistry A,2021,9(5):2678-2682.
[12]	焦佳鹏,田海锋,何环环,等.CO/CO₂ 加氢制芳烃的研究进展[J].化工进展,2021,40(1):205-220.
[13]	高鹏,崔勖,钟良枢,等.CO/CO₂ 加氢高选择性合成化学品和液体燃料[J].化工进展,2019,38(1):183-195.
[14]	成康,张庆红,康金灿,等.二氧化碳直接制备高值化学品中的接力催化方法[J].中国科学:化学,2020,50(7):743-755.
[15]	张超,张玉龙,朱明辉,等.CO₂ 高值化利用新途径:铁基催化剂 CO₂ 加氢制烯烃研究进展[J].化工进展,2021,40(2):577-593.
[16]	GUTTERØD E S,LAZZARINI A,FJERMESTAD T,et al.Hydrogenation of CO₂ to methanol by Pt nanoparticles encapsulated in UiO-67:deciphering the role of the metal-organic framework[J].Journal of the American Chemical Society,2020,142(2):999-1009.
[17]	ZHANG X B,ZHANG A F,JIANG X,et al.Utilization of CO₂ for aromatics production over ZnO/ZrO₂-ZSM-5 tandem catalyst[J].Journal of CO₂ Utilization,2019,29:140-145.
[18]	LI W,WANG K C,ZHAN G W,et al.Hydrogenation of CO₂ to dimethyl ether over tandem catalysts based on biotemplated hierarchical ZSM-5 and Pd/ZnO[J].ACS Sustainable Chemistry & Engineering,2020,8(37):14058-14070.
[19]	RAFATI M,WANG L,SHAHBAZI A.Effect of silica and alumina promoters on co-precipitated Fe-Cu-K based catalysts for the enhancement of CO₂ utilization during Fischer-Tropsch synthesis[J].Journal of CO₂ Utilization,2015,12:34-42.
[20]	SAEIDI S,NAJARI S,FAZLOLLAHI F,et al.Mechanisms and kinetics of CO₂ hydrogenation to value-added products:a detailed review on current status and future trends[J].Renewable and Sustainable Energy Reviews,2017,80:1292-1311.
[21]	MULEJA A A,GORIMBO J,MASUKU C M.Effect of co-feeding inorganic and organic molecules in the Fe and Co catalyzed Fischer-Tropsch synthesis:a review[J].Journal of CO₂ Utilization,2015,12:34-42.
[22]	YANG X,ZHANG H,LIU T Y,et al.Preparation of iron carbides formed by iron oxalate carburization for Fischer-Tropsch synthesis[J].Catalysts,2019,9(4):347-360.
[23]	GNANAMANI M K,JACOBS G,HAMDEH H H,et al.Fischer-Tropsch synthesis:mössbauer investigation of iron containing catalysts for hydrogenation of carbon dioxide[J].Catalysis Today,2013,207:50-56.
[24]	GNANAMANI M K,SHAFER W D,SPARKS D E,et al.Fischer-Tropsch synthesis:effect of CO₂ containing syngas over Pt promoted Co/γ-Al₂O₃ and K-promoted Fe catalysts[J].Catalysis Communications,2011,12(11):936-939.
[25]	董子超,吴玉,张博风,等.新型 FeCo 双金属催化剂催化 CO₂ 加氢制低碳烯烃[J].化工学报,2021,72(5):2647-2656.
[26]	GUO L S,SUN J,GE Q J,et al.Recent advances in direct catalytic hydrogenation of carbon dioxide to valuable C₂⁺ hydrocarbons[J].Journal of Materials Chemistry A,2018,6(46):23244-23262.
[27]	AMOYAL M,VIDRUK-NEHEMYA R,LANDAU M V,et al.Effect of potassium on the active phases of Fe catalysts for carbon dioxide conversion to liquid fuels through hydrogenation[J].Journal of Catalysis,2017,348:29-39.
[28]	CIMINO S,BOCCIA F,LISI L.Effect of alkali promoters (Li,Na,K) on the performance of Ru/Al₂O₃ catalysts for CO₂ capture and hydrogenation to methane[J].Journal of CO₂ Utilization,2020,37:195-203.
[29]	WANG Q,CHEN Y,LI Z H.Research progress of catalysis for low-carbon olefins synthesis through hydrogenation of CO₂[J].Journal of Nanoscience and Nanotechnology,2019,19(6):3162-3172.
[30]	马光远,徐艳飞,王捷,等.合成气直接法制取低碳烯烃铁基催化体系研究进展[J].化工进展,2018,37(3):992-1000.
[31]	ZHANG J L,FANG K G,ZHANG K,et al.Carbon dispersed iron-manganese catalyst for light olefin synthesis from CO hydrogenation[J].Korean Journal of Chemical Engineering,2009,26(3):890-894.
[32]	ZENG G T,QIU J,LI Z,et al.CO₂ reduction to methanol on TiO₂-passivated GaP photocatalysts[J].ACS Catalysis,2014,4(10):3512-3516.
[33]	RAZZAQ R,LI C,USMAN M,et al.A highly active and stable Co₄N/γ-Al₂O₃ catalyst for CO and CO₂ methanation to produce synthetic natural gas (SNG)[J].Chemical Engineering Journal,2015,262:1090-1098.
[34]	WANG Z Q,XU Z N,PENG S Y,et al.High-performance and long-lived Cu/SiO₂ nanocatalyst for CO₂ hydrogenation[J].ACS Catalysis,2015,5(7):4255-4259.
[35]	JOHNSON G R,BELL A T.Role of ZrO₂ in promoting the activity and selectivity of Co-Based Fischer-Tropsch synthesis catalysts[J].ACS Catalysis,2016,6(1):100-114.
[36]	LI Z L,WANG J J,QU Y Z,et al.Highly selective conversion of carbon dioxide to lower olefins[J].ACS Catalysis,2017,7(12):8544-8548.
[37]	WANG S W,WU T J,LIN J,et al.Iron-potassium on single-walled carbon nanotubes as efficient catalyst for CO₂ hydrogenation to heavy olefins[J].ACS Catalysis,2020,10(11):6389-6401.