STABILIZATION OF CADMIUM-CONTAMINATED SOIL BY SULFHYDRYL MODIFIED BIOCHAR

LI Zheng-long; ZHOU Yong-chun; LI Hai-bo; GUO Si-bo; LI Dan-yang; XU Yun-zhu

doi:10.13205/j.hjgc.202209019

Volume 40 Issue 9

Nov. 2022

Turn off MathJax

Article Contents

Article Navigation > ENVIRONMENTAL ENGINEERING > 2022 > 40(9): 143-149,157

LI Zheng-long, ZHOU Yong-chun, LI Hai-bo, GUO Si-bo, LI Dan-yang, XU Yun-zhu. STABILIZATION OF CADMIUM-CONTAMINATED SOIL BY SULFHYDRYL MODIFIED BIOCHAR[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 143-149,157. doi: 10.13205/j.hjgc.202209019

Citation:

LI Zheng-long, ZHOU Yong-chun, LI Hai-bo, GUO Si-bo, LI Dan-yang, XU Yun-zhu. STABILIZATION OF CADMIUM-CONTAMINATED SOIL BY SULFHYDRYL MODIFIED BIOCHAR[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 143-149,157. doi: 10.13205/j.hjgc.202209019

Citation:

PDF( 3421 KB)

STABILIZATION OF CADMIUM-CONTAMINATED SOIL BY SULFHYDRYL MODIFIED BIOCHAR

doi: 10.13205/j.hjgc.202209019

1. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China;
2. Shenyang Ecological Environment Monitoring Center of Liaoning Province, Shenyang 110167, China

Received Date: 2021-12-11
Available Online: 2022-11-09

Abstract

Abstract

In order to find efficient stabilization materials for cadmium contaminated soil in Northeast China, the sulfhydryl biochar was prepared with corn stalk biochar as the raw material and(3-Mercaptopropyl) trimethoxysilane(MPS) as the modifier. Furthermore, the effects of different amounts(1%, 3%, 5%) of sulfhydryl biochar, biochar and lime on soil physical and chemical properties(pH value, CEC value, SOC value), leaching content of heavy metal cadmium TCLP and chemical form of cadmium were analyzed. The results showed that the cadmium leaching content of the TCLP method was 109.82, 96.35, 86.34 mg/kg under different dosage conditions of original biochar, which was inferior to that of lime treatment under the same dosage conditions. Each amount of sulfhydryl biochar decreased soil pH value, increased CEC value, and increased SOC value. The cadmium stabilization effect of 5% thiol biochar was the most obvious, and the cadmium leaching content of the TCLP method was 67.53 mg/kg, which was 11.1% lower than that of 5% lime treatment. The results showed that the pH value of soil decreased, CEC value increased and SOC value increased with each dosage of sulfhydryl biochar. The cadmium leaching content of TCLP method was 76.99 mg/kg, 72.52 mg/kg and 67.53 mg/kg, respectively, and the effect was better than that of lime under the same dosage condition. The cadmium stabilization effect of 5% thiol biochar was the most significant, and the cadmium leaching content was 11.1% lower than that of 5% lime. The results of BCR continuous extraction showed that the amount of 5% sulfhydryl biochar reduced the soluble cadmium and reducible cadmium of weak acid by 35.8% and 17.63%, respectively, which were 8.18% and 5.7% higher than that of 5% lime treatment. The results showed that thiol biochar had a better stabilization effect than lime on cadmium-contaminated soil in northeast China.
- sulfhydryl biochar,
- lime,
- BCR continuous extraction method,
- TCLP method,
- soil repair

FullText(HTML)

References(30)

References

[1]	庄国泰.我国土壤污染现状与防控策略[J].土壤与生态环境安全,2014,30(4):477-483.
[2]	陈志良,莫大伦,仇荣亮.镉污染对生物有机体的危害及防治对策[J].环境保护科学,2001,27(4):37-39.
[3]	吕宏虹,宫艳艳,唐景春,等.生物炭及其复合材料的制备与应用研究进展[J].农业环境科学学报,2015,34(8):1429-1440.
[4]	陈温福,张伟明,孟军.农用生物炭研究进展与前景[J].中国农业科学,2013,46(16):3323-3333.
[5]	S P SOHI E K,E LOPEZ-CAPEL,et al.A review of biochar and its use and function in soil[J].Advances in Agronomy,2010,105(1):47-82.
[6]	DAVID H,LAURENT E,PHILIPPE S.Beneficial effects of biochar application to contaminated soils on the bioavailability of Cd,Pb and Zn and the biomass production of rapeseed (Brassica napus L.)[J].Biomass and Bioenergy,2013,57:196-204.
[7]	ABBAS T,RIZWAN M,ALI S,et al.Effect of biochar on alleviation of cadmium toxicity in wheat (Triticμm aestivμm L.) grown on Cd-contaminated saline soil[J].Environmental Science and Pollution Research,2017,25(26):25668-25680.
[8]	PUGA A P,ABREU C A,MELO L C A,et al.Cadmium,lead,and zinc mobility and plant uptake in a mine soil amended with sugarcane straw biochar[J].Environmental Science and Pollution Research,2015,22(22):17606-17614.
[9]	袁帅,赵立欣,孟海波,等.生物炭主要类型理化性质及其研究展望[J].植物营养与肥料学报,2016,22(5):1402-1417.
[10]	GAN W T,GAO L K,ZHAN X X,et al.Preparation of thiol-functionalized magnetic sawdust composites as an adsorbent to remove heavy metal ions[J].RSC Advances,2016,6(44):37600-37609.
[11]	王亚玲,李述贤,杨合.有机改性蒙脱石负载巯基修复汞污染土壤[J].环境工程学报,2018,12(12):3433-3439.
[12]	LIANG X F,QIN X,HUANG Q Q,et al.Mercapto functionalized sepiolite:a novel and efficient immobilization agent for cadmium polluted soil[J].RSC Advances,2017,7(63):39955-39961.
[13]	ZHANG D,DING A F.Effects of passivating agents on the availability of Cd and Pb and microbial community function in a contaminated acidic soil[J].Bulletin Environmental Contamination and Toxicology,2019,103(1):98-105.
[14]	邹峻桦.不同温度及气氛条件下生物炭的制备与还田效果研究[D].武汉:华中农业大学,2017.
[15]	LUO Y,DURENKAMP M,DE NOBILI M,et al.Short term soil priming effects and the mineralisation of biochar following its incorporation to soils of different pH[J].Soil Biology & Biochemistry,2011,43(11):2304-2314.
[16]	鲍士旦.土壤农化分析[M].3版.北京:中国农业出版社,2000.
[17]	EPA.Method 1311 toxicity characteristic leaching procedure[M].Washington,DC:US EPA,1992.
[18]	M.L.ALONSO Castillo,E.VEREDA Alonso,M.T.SILES Cordero,et al.Fractionation of heavy metals in sediment by using microwave assisted sequential extraction procedure and determination by inductively coupled plasma mass spectrometry[J].Microchemical Journal,2011,98(2):234-239.
[19]	CHAI L Y,LI Q Z,ZHU Y H,et al.Synthesis of thiolfunctionalized spent grain as a novel adsorbent for divalent metalions[J].Bioresource Technology,2010,101(15):6269-6272.
[20]	ZHANG C,SUI J H,LI J,et al.Efficient removal of heavy metal ions by thiol-functionalized superparamagnetic carbon nanotubes[J].Chemical Engineering Journal,2012,210:45-52.
[21]	邵爱云,程德义,代静玉,等.巯基改性稻壳炭对水中Cd²⁺的吸附特性[J].生态与农村环境学报,2019,35(8):1071-1079.
[22]	姚璁,何天容,冉澍,等.巯基改性泥炭对水体中Hg²⁺的吸附解吸研究[J].工业水处理,2020,40(10):67-71.
[23]	Jihyeong RYU,Myeong Yeon LEE,Min Gyu SONG,et al.Highly selective removal of Hg(Ⅱ) ions from aqueous solution using thiol-modified porous polyaminal-networked polymer[J].Separation and Purification Technology,2020,250:1-10.
[24]	IPPOLITO J A,DUCEY T F,CANTRELL K B,et al.Designer,acidic biochar influences calcareous soil characteristics[J].Chemosphere,2016,142(1):184-191.
[25]	ZHANG R H,LI Z G,LIU X D,et al.Immobilization and bioavailability of heavy metals in greenhouse soils amended with rice straw-derived biochar[J].Ecological Engineering,2017,98:183-188.
[26]	CHRISTOPHER J.ATKINSON J D F,NEIL A.HIPPS.Potential mechanisms for achieving agricultural benefits from biochar application to temperate soils:a review[J].Plant and Soil,2010,337(1/2):1-18.
[27]	DU Y Y,WANG X,JI X H,et al.Effectiveness and potential risk of CaO application in Cd-contaminated paddy soil[J].Chemosphere,2018,204:130-139.
[28]	van POUCKE R,AINSWORTH J,MAESEELE M,et al.Chemical stabilization of Cd-contaminated soil using biochar[J].Applied Geochemistry,2018,88:122-130.
[29]	LIAN M M,WANG L F,FENG Q Q,et al.Thiol-functionalized nano-silica for in-situ remediation of Pb,Cd,Cu contaminated soils and improving soil environment[J].Environmental Pollution,2021,280:116879.
[30]	杨惟薇,张超兰,曹美珠,等.4种生物炭对镉污染潮土钝化修复效果研究[J].水土保持学报,2015,29(1):239-243.