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Volume 40 Issue 10
Oct.  2022
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Article Contents
XU Min, DU Hongyu, GUO Jiaming, ZHAO Xiaodan, LU Wei, SUN Chao, CHEN Yu, ZHOU Zhen. A PILOT-SCALE EXPERIMENT FOR ZERO LIQUID DISCHARGE AND RESOURCE RECOVERY OF FLUE GAS DESULFURIZATION WASTEWATER IN COAL-FIRED POWER PLANTS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(10): 169-175. doi: 10.13205/j.hjgc.202210023
Citation: XU Min, DU Hongyu, GUO Jiaming, ZHAO Xiaodan, LU Wei, SUN Chao, CHEN Yu, ZHOU Zhen. A PILOT-SCALE EXPERIMENT FOR ZERO LIQUID DISCHARGE AND RESOURCE RECOVERY OF FLUE GAS DESULFURIZATION WASTEWATER IN COAL-FIRED POWER PLANTS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(10): 169-175. doi: 10.13205/j.hjgc.202210023

A PILOT-SCALE EXPERIMENT FOR ZERO LIQUID DISCHARGE AND RESOURCE RECOVERY OF FLUE GAS DESULFURIZATION WASTEWATER IN COAL-FIRED POWER PLANTS

doi: 10.13205/j.hjgc.202210023
  • Received Date: 2021-08-06
  • Based on characteristics of wastewater and resource recovery, a zero liquid discharge process of flue gas desulfurization wastewater, combined with graded salt separation pretreatment, membrane concentration and electrolytic chlorine production unit, was constructed. A pilot-scale experiment was conducted for 35 d at a flow rate of 500 L/d. The results suggested that effective removal of pollutants and resource recovery could be achieved with suspended solid, Mg2+, SO2-4 and Ca2+ removal of 100%, 96.6%, 99.8% and 98.9%. The purity of CaSO4, Mg(OH)2, ettringite and CaCO3 precipitate were 86.9%, 99.8%, 88.3% and 99.9%, which were suitable to be utilized as desulfurization gypsum, dephosphorization agent, flame retardant and desulfurizer. NaClO obtained from electrolytic chlorine production could satisfy the requirement of type A, class Ⅲ in China's National Standard GB 19106-2013, which was applicable to disinfection, sterilization and water treatment.
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  • [1]
    马双忱, 陈嘉宁, 万忠诚, 等. 高盐脱硫废水水泥化固定技术的研究现状与发展[J]. 化工进展, 2019, 38(9):4275-4283.
    [2]
    王涛英, 徐军锋, 胡彦云, 等. 燃煤火电厂高盐废水的处理[J]. 环境工程, 2020, 38(1):112-116

    , 145.
    [3]
    蒋路漫, 周振, 田小测, 等. 电厂烟气脱硫废水零排放工艺中试研究[J]. 热力发电, 2019, 48(1):103-109.
    [4]
    YAN J, YUAN W H, LIU J, et al. An integrated process of chemical precipitation and sulfate reduction for treatment of flue gas desulphurization wastewater from coal-fired power plant[J]. Journal of Cleaner Production, 2019, 228:63-72.
    [5]
    刘海洋, 江澄宇, 谷小兵, 等. 燃煤电厂湿法脱硫废水零排放处理技术进展[J]. 环境工程, 2016, 34(4):33-36

    , 41.
    [6]
    GUO J M, ZHOU Z, MING Q, et al. Recovering chemical sludge from the zero liquid discharge system of flue gas desulfurization wastewater as flame retardants by a stepwise precipitation process[J]. Journal of Hazard Material, 2021, 417:126054.
    [7]
    国家环境保护总局《水和废水监测分析方法》编委会. 水和废水监测分析方法[M]. 4版.中国环境科学出版社, 2002.
    [8]
    姚敏, 杨帅, 井云环, 等. 煤化工含盐废水分盐零排放工艺模拟研究[J]. 给水排水, 2019, 55(11):79-83.
    [9]
    李嘉懿, 张海涛, 周吉峙, 等. 脱硫废水减温烟气对飞灰中重金属稳定性的影响研究[J]. 环境科学与管理, 2020, 45(12):51-55.
    [10]
    赛世杰, 李买军, 党平, 等. 高分离纳滤系统在煤化工高盐废水零排放中的应用[J]. 环境工程, 2021, 39(7):173-178.
    [11]
    XIN Y, ZHOU Z, MING Q, et al. A two-stage desalination process for zero liquid discharge of flue gas desulfurization wastewater by chloride precipitation[J]. Journal of Hazard Material, 2020, 397:122744.
    [12]
    TIAN X C, ZHOU Z, XIN Y, et al. A novel sulfate removal process by ettringite precipitation with aluminum recovery:kinetics and a pilot-scale study[J]. Journal of Hazard Material, 2019, 365:572-580.
    [13]
    ZHENG Z P, TOKUNAGA T K, WAN J M. Influence of calcium carbonate on U(Ⅵ) sorption to soils[J]. Environmental Science & Technology, 2003, 37(24):5603-5608.
    [14]
    刘璐, 赵志娟, 李雅, 等. 工业废水电渗析过程中膜污染研究进展[J].过程工程学报, 2015, 15(5):881-891.
    [15]
    施小林, 王大新, 楼书怿, 等. 电渗析技术在水泥厂废水零排放处理中的应用[J]. 环境工程, 2021, 39(7):179-184.
    [16]
    马玉斐, 王勇. 电解制氯系统酸洗废液的资源化处理工艺[J]. 给水排水, 2019, 55(9):65-69.
    [17]
    中华人民共和国建设部. 次氯酸钠发生器:GB 12176-1990[S]. 1990.
    [18]
    苗春葆, 齐振宇. 影响工业生产次氯酸钠有效氯含量的因素[J]. 中国氯碱, 2021, 4(2):24-26.
    [19]
    吴火强, 刘亚鹏, 王璟, 等. 脱硫废水膜浓缩浓水电解制氯工艺分析[J]. 热力发电, 2016, 45(9):109-115

    , 121.
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