Source Journal of CSCD
Source Journal for Chinese Scientific and Technical Papers
Core Journal of RCCSE
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Volume 40 Issue 11
Nov.  2022
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PEI Jianlu, WANG Kunjun, CHEN Xin, LI Xiaochen, LI Yuan, TIAN Lintao, LI Yongguo. NEGATIVE SYNERGISTIC EFFECT OF AMINO IONIC LIQUID SUPPORTED ACTIVATED CARBON ON CO2 ADSORPTION PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(11): 78-83. doi: 10.13205/j.hjgc.202211011
Citation: PEI Jianlu, WANG Kunjun, CHEN Xin, LI Xiaochen, LI Yuan, TIAN Lintao, LI Yongguo. NEGATIVE SYNERGISTIC EFFECT OF AMINO IONIC LIQUID SUPPORTED ACTIVATED CARBON ON CO2 ADSORPTION PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(11): 78-83. doi: 10.13205/j.hjgc.202211011

NEGATIVE SYNERGISTIC EFFECT OF AMINO IONIC LIQUID SUPPORTED ACTIVATED CARBON ON CO2 ADSORPTION PERFORMANCE

doi: 10.13205/j.hjgc.202211011
  • Received Date: 2021-12-14
    Available Online: 2023-03-24
  • [TETA] [L] ionic liquid was synthesized by the acid-base neutralization reaction of triethylenetetramine and L-lactic acid, and different mass fractions of ionic liquid were loaded into coconut shell activated carbon. The effects of ionic liquid impregnation on the microstructure and CO2 adsorption performance of coconut shell activated carbon were investigated by FTIR, XRD and automatic specific surface and pore size distribution analyzer. The results showed that the interaction between ionic liquid and activated carbon led to the fine crystallization of graphitized microcrystals, which adversely affected the structural stability of activated carbon, while the "plugging" filling of the pore structure of coconut shell activated carbon by ionic liquid led to the significant decrease of CO2 physical adsorption performance, and limited the increase of CO2 chemisorption performance of the composite, which was the root cause of the significant decrease in the total CO2 absorption performance of the composite. And ionic liquid in activated carbon showed a "step" filling behavior from small pore size to large pore size.
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  • [1]
    VICENT-LUNA J M, GUTIERREZ-SEVILLANO J J, ANTA J A, et al. Effect of room-temperature ionic liquids on CO2 separation by a Cu-BTC metal-organic framework[J]. Journal of Physical Chemistry C, 2013, 117(40):20762-20768.
    [2]
    CHEN Y F, HU Z Q, GUPTA K M, et al. Ionic liquid/metal-organic framework composite for CO2 capture:a computational investigation[J]. Journal of Physical Chemistry C, 2011, 115(44):21736-21742.
    [3]
    LI Z J, XIAO Y L, XUE W J, et al. Ionic liquid/metal-organic framework composites for H2S removal from natural gas:a computational exploration[J]. The Journal of Physical Chemistry C, 2015, 119(7):3674-3683.
    [4]
    银建中, 蔡佩, 周雪玲,等. 浸渍法制备负载化离子液体吸附剂及其表征[J]. 环境工程, 2017, 35(7):77-81.
    [5]
    SILVA F W M, MAGALHAES G M, JARDIM E O, et al. CO2 adsorption on ionic liquid-modified Cu-BTC:experimental and simulation study[J]. Adsorption Science Technology, 2015, 33(2):223-242.
    [6]
    SEZGINEL K B, KESKIN S, UZUN A. Tuning the gas separation performance of Cu-BTC by ionic liquid incorporation[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2016, 32(4):1139-1147.
    [7]
    MA J, YING Y P, GUO X Y, et al. Fabrication of mixed-matrix membrane containing metal organic framework composite with task specific ionic liquid for efficient CO2 separation[J]. Journal of Materials Chemistry, A. Materials for Energy and Sustainability, 2016, 4(19):7281-7288.
    [8]
    BAN Y J, LI Z J, LI Y S, et al. Confinement of ionic liquids in nanocages:tailoring the molecular sieving properties of ZIF-8 for membrane-based CO2 capture[J]. Angewandte Chemie, 2015, 54(51):15483-15487.
    [9]
    KINIK F P, ALTINTAS C, BALCI V, et al.[BMIM][PF6] incorporation doubles CO2 selectivity of ZIF-8:elucidation of interactions and their consequences on performance[J]. ACS Applied Materials & Interfaces, 2016, 8(45):30992-31005.
    [10]
    KOYUTURK B, ALTINTAS C, KINIK F P, et al. Improving gas separation performance of ZIF-8 by[BMIM][BF4] incorporation:interactions and their consequences on performance[J]. Journal of Physical Chemistry C, 2017, 121(19):10370-10381.
    [11]
    XIA X X, HU G Q, LI W, et al. Understanding reduced CO2 uptake of ionic liquid/metal-organic framework (IL/MOF) composites[J]. ACS Applied Nano Materials, 2019, 2(9):6022-6029.
    [12]
    HU P C, ZHANG R, LIU Z C, et al. Absorption performance and mechanism of CO2 in aqueous solutions of amine-based ionic liquids[J]. Energy & Fuels, 2015, 29(9):6019-6024.
    [13]
    ZHANG G J, ZHAO P Y, HAO L X, et al. Amine-modified SBA-15(P):a promising adsorbent for CO2 capture[J]. Journal of CO2 Utilization, 2018, 24:22-33.
    [14]
    TZIALLA O, KAKASIMOS G, ATHANASEKOU C, et al. Porous carbons from ionic liquid precursors confined within nanoporous silicas[J]. Microporous & Mesoporous Materials, 2016, 223:163-175.
    [15]
    SERAFIN J. Utilization of spent dregs for the production of activated carbon for CO2 adsorption[J]. Polish Journal of Chemical Technology, 2017, 19(2):44-50.
    [16]
    SUMRIT M, PHANSIRI M, WANWIMON P, et al. Characterization and properties of activated carbon prepared from tamarind seeds by KOH activation for Fe(Ⅲ) adsorption from aqueous solution[J]. The Scientific World Journal, 2015, 2015(1):415961.
    [17]
    聂千. 活性炭孔结构对CO2和CH4吸附分离性能的影响[D]. 太原:太原理工大学, 2021.
    [18]
    WEI J W, MEI D J, LIN Z F, et al. Effects of TETA or TEPA loading on CO2 adsorption properties using pore-expanded KIT-6 as support[J]. Nano Brief Reports and Reviews, 2018,13(4):1850042.
    [19]
    ACHARYA J, SAHU J N, SAHOO B K, et al. Removal of chromium(Ⅵ) from wastewater by activated carbon developed from Tamarind wood activated with zinc chloride[J]. Chemical Engineering Journal, 2009, 150(1):25-39.
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