PREPARATION OF STAINLESS STEEL-BASED Sb-SnO<sub>2</sub>/PbO<sub>2</sub> ELECTRODE AND EFFECT OF ELECTRODEPOSITION FACTORS ON ITS PERFORMANCE

ZHAO Bin; YANG Yang; QIU Fengtao; SU Yan; QU Zhenhe; HUANG Qian; JIANG Qi; XU Hao

doi:10.13205/j.hjgc.202304004

Volume 41 Issue 4

Apr. 2023

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2023 > 41(4): 26-31,39

ZHAO Bin, YANG Yang, QIU Fengtao, SU Yan, QU Zhenhe, HUANG Qian, JIANG Qi, XU Hao. PREPARATION OF STAINLESS STEEL-BASED Sb-SnO2/PbO2 ELECTRODE AND EFFECT OF ELECTRODEPOSITION FACTORS ON ITS PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 26-31,39. doi: 10.13205/j.hjgc.202304004

Citation:

ZHAO Bin, YANG Yang, QIU Fengtao, SU Yan, QU Zhenhe, HUANG Qian, JIANG Qi, XU Hao. PREPARATION OF STAINLESS STEEL-BASED Sb-SnO₂/PbO₂ ELECTRODE AND EFFECT OF ELECTRODEPOSITION FACTORS ON ITS PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 26-31,39. doi: 10.13205/j.hjgc.202304004

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PREPARATION OF STAINLESS STEEL-BASED Sb-SnO₂/PbO₂ ELECTRODE AND EFFECT OF ELECTRODEPOSITION FACTORS ON ITS PERFORMANCE

doi: 10.13205/j.hjgc.202304004

1. Huaneng Yingcheng Thermal Power Co., Ltd, Yingcheng 432406, China;
2. Xi'an TPRI Water-Management & Environmental Protection Co., Ltd, State Key Laboratory of High-Efficiency Flexible Coal Power Generation and Carbon Capture Utilization and Storage, Xi'an 710054, China;
3. Department of Environmental Science Engineering, Xi'an Jiaotong University, Xi'an 710049, China

Received Date: 2022-05-27
Available Online: 2023-05-26
Publish Date: 2023-04-01

Abstract

Abstract

In this paper, the stainless steel-based lead dioxide (PbO₂) electrode with antimony-doped tin dioxide (Sb-SnO₂) interlayer was prepared using 316L stainless steel as the substrate, and used for the decolorization of Acid Red G (ARG). The morphology, crystal structure, stability and catalytic performance of the electrode were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), enhanced lifetime test, and linear scan test (LSV). Based on this, orthogonal experiments were used to optimize four typical factors (lead ion concentration, temperature, current density and electrodeposition time) that had a strong influence on stability of the electrode. The results showed that the β-PbO₂ layer was successfully prepared on the stainless steel substrate with a typical conical structure of β-PbO₂ in its morphology. The results of the enhanced lifetime test indicated that the failure mechanism of the stainless steel-based PbO₂ electrode was mainly pitting corrosion, which was different from the uniform corrosion of the titanium-based oxide electrode. The LSV test, hydroxyl radical (·OH) yield test and electrocatalytic degradation test were used to demonstrate the better catalytic performance of the stainless steel-based PbO₂ electrode, after optimizing the conditions in orthogonal experiments. The successful preparation of stainless steel-based PbO₂ electrode is expected to provide a new choice for electrocatalytic oxidation anode materials.
- PbO₂ electrode,
- stainless steel base,
- electrodeposition,
- orthogonal experiment,
- catalytic activity

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References(29)

References

[1]	胡承志, 刘会娟, 曲久辉. 电化学水处理技术研究进展[J]. 环境工程学报, 2018, 12(3): 677-696.
[2]	叶国杰, 王一显, 罗培, 等. 水处理高级氧化法活性物种生成机制及其技术特征分析[J]. 环境工程, 2020, 38(2): 1-15.
[3]	徐浩, 乔丹, 许志成, 等. 电催化氧化技术在有机废水处理中的应用[J]. 工业水处理, 2021, 41(3): 1-9.
[4]	刘明康, 周键, 王三反, 等. Ce修饰Ti/PbO₂阳极电催化氧化降解苯酚的研究[J]. 环境科学与管理, 2017, 42(7): 75-79.
[5]	袁孟孟, 傅鸿宣, 乔丹, 等. Fe₃O₄/TiO_x磁性颗粒构建的2.5维电极及其电催化性能[J]. 工业水处理, 2021, 41(1): 71-76.
[6]	BI Q, ZHANG Z K, SUN Y F, et al. Preparation and performance of highly active and long-life mesopore Ti/SnO₂-Sb electrodes for electrochemical degradation of phenol[J]. Journal of Alloys and Compounds, 2021, 889: 161657.
[7]	李晓良, 徐浩, 延卫. 高效Ti/PbO₂电极制备及对酸性红G的降解研究[J]. 中国环境科学, 2017, 37(7): 2591-2598.
[8]	唐长斌, 王飞, 牛浩, 等. 引入电弧喷涂氮化锆中间层的钛基PbO₂的电催化阳极性能[J]. 材料研究学报, 2020, 34(7): 527-534.
[9]	GUO H, XU Z C, WANG D, et al. Evaluation of diclofenac degradation effect in "active" and "non-active" anodes: a new consideration about mineralization inclination[J]. Chemosphere, 2022, 286: 131580.
[10]	岳文清, 倪月, 孙则朋, 等. 改性钛基PbO₂电极对有机污染物的降解性能:以甲基橙和4-硝基苯酚为例[J]. 中国环境科学, 2022, 42(2): 706-716.
[11]	DONG H, HU X Y, ZHANG Y H, et al. Co/La modified Ti/PbO₂ anodes for chloramphenicol degradation: catalytic performance and reaction mechanism[J]. Chemosphere, 2021, 285: 131568.
[12]	李佳欣, 陈野, 韩洪军, 等. 钛基PbO₂电极制备及其电催化处理煤化工废水[J]. 中国给水排水, 2019, 35(3): 111-116.
[13]	董艳杰, 林海波, 陈碧芬. 苯酚电化学氧化过程中Ti/PbO₂阳极钝化现象的研究[J]. 云南化工, 2021, 48(3): 55-58.
[14]	李献民, 刘立, 董洁, 等. 钛及钛合金材料经济性及低成本方法论述[J]. 中国材料进展, 2015, 34(5): 401-406.
[15]	KITTE S A, ZAFAR M N, ZHOLUDOV Y T, et al. Determination of concentrated hydrogen peroxide free from oxygen interference at stainless steel electrode[J]. Analytical chemistry, 2018, 90(14): 8680-8685.
[16]	杜重麟, 桂来, 李芬锐, 等. 不锈钢基ZnO/PbO₂阵列电极的制备及其析氧电催化性能[J]. 电镀与涂饰, 2021, 40(21): 1659-1665.
[17]	徐浩, 延卫, 游莉. 不同酸处理对钛基体性能的影响[J]. 稀有金属材料与工程, 2011, 40(9): 1550-1554.
[18]	丁奇, 王建凤, 王颖, 等. MIL-88A光芬顿催化体系中羟基自由基的检测[J]. 分析仪器, 2021(4): 132-138.
[19]	杨卫华, 王鸿辉, 付芳, 等. 电沉积条件对Ti/Sb-SnO₂/β-PbO₂电极性能的影响[J]. 华侨大学学报(自然科学版), 2010, 31(3): 297-301.
[20]	李会喜, 崔文蓉, 朱薇, 等. 电流密度对Ti/β-PbO₂-WC复合电极材料在电解锌液中耐蚀性影响研究[J]. 化学研究与应用, 2018, 30(2): 226-230.
[21]	杜炳谦, 陈阵, 余强, 等. 温度对Ti/β-PbO₂-WC复合电极材料耐蚀性的影响[J]. 材料保护, 2017, 50(5): 42-44 ,63.
[22]	TAN X D, MA L, HAN P W, et al. Fabrication of boron-doped diamond films electrode for efficient electrocatalytic degradation of cresols[J]. Chemosphere, 2020, 246: 125786.
[23]	李晓良, 徐浩, 延卫. 十二烷基二甲基甜菜碱对Ti/PbO₂电极的改性研究[J]. 西安交通大学学报, 2017, 51(5): 142-148.
[24]	GUO H, XU Z C, QIAO D, et al. Fabrication and characterization of titanium-based lead dioxide electrode by electrochemical deposition with Ti₄O₇ particles[J]. Water Environment Research, 2021, 93: 42-50.
[25]	ZHANG R R, HUA S G, DANG Y, et al. Strategy for enhancing the electrocatalytic performance of Ti/β-PbO₂ anode: optimizing SnO₂ intermediate layer by Cs doping and application for the efficient removal of mixed fluoroquinolones[J]. Journal of Alloys and Compounds, 2022, 895: 162528.
[26]	王鸿辉, 杨卫华, 黄龙, 等. Ti/α-PbO₂/β-PbO₂电极电催化氧化处理苯酚废水[J]. 华侨大学学报(自然科学版), 2008,29(2): 263-266.
[27]	QIAO D, XU Z C, GUO H, et al. Non-traditional power supply mode: investigation of electrodeposition towards a better understanding of PbO₂ electrode for electrochemical wastewater treatment[J]. Materials Chemistry and Physics, 2022, 284: 126066.
[28]	XUE J Q, MA S W, BI Q, et al. Comparative study on the effects of different structural Ti substrates on the properties of SnO₂ electrodes[J]. Journal of Alloys and Compounds, 2018, 773: 1040-1047.
[29]	徐浩, 邵丹, 杨鸿辉, 等. Ti/Sb-SnO₂电极电解后的表面状态变化[J]. 西安交通大学学报, 2014, 48(2): 93-98. [31] 李鹏, 赵跃民, 王立章, 等. β-PbO₂/Sb-SnO₂/Ti电极的苯酚电催化性能研究[J]. 电化学, 2014, 20(5): 493-498. [32] 徐浩,郭午琪,王晓璇,等. 超声对二氧化铅电极性质的影响[J]. 西安交通大学学报,2015, 49(7): 82-87,148. [33] 徐浩,张倩,邵丹,等. 钛基体锑掺杂二氧化锡电极的制备与改性研究进展[J]. 化工进展, 2013, 32(增刊1): 145-151. [34] CHEN Y, HONG L, XUE H M, et al. Preparation and characterization of TiO₂-NTs/SnO₂-Sb electrodes by electrodeposition[J]. Journal of Electroanalytical Chemistry, 2010, 648(2): 119-127. [35] ZHANG Z K, WANG Z Y, SUN Y F, et al. Preparation of a novel Ni/Sb co-doped Ti/SnO₂ electrode with carbon nanotubes as growth template by electrodeposition in a deep eutectic solvent[J]. Journal of Electroanalytical Chemistry, 2022, 911: 116225. [36] YU L H, XUE J Q, ZHANG L H, et al. Fabrication of a stable Ti/Pb-TiO_<em>xNWs/PbO₂ anode and its application in benzoquinone degradation[J]. Electrochimica Acta, 2021, 368: 137532. [37] YUAN M M, SALMAN N M, GUO H, et al. A 2.5D electrode system constructed of magnetic Sb-SnO₂ particles and a PbO₂ electrode and its electrocatalysis application on Acid Red G degradation[J]. Catalysts, 2019, 9(11): 875. XU H, YAN W, YANG H H. Surface analysis of Ti/Sb-SnO₂/PbO₂ electrode after long time electrolysis[J]. Rare Metal Materials and Engineering, 2015, 44(11): 2637-2641. [30]