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Volume 41 Issue 4
Apr.  2023
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2023  >  41(4): 71-78,115
FU Xiaoyan, LI Zhenguo, LI Xiangyu, YANG Meng, LIU Lianlian, XIA Ying, SUN Zhen, LI Zhiyuan. ANTIBIOTIC POLLUTION CHARACTERISTICS AND ECOLOGICAL RISK ASSESSMENT OF WATER BODIES AROUND LIVESTOCK AND POULTRY BREEDING IN DALIAN[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 164-169. doi: 10.13205/j.hjgc.202304023
Citation: ZHAO Puzhen, LIU Chu, HUANG Qianlin, LÜ Lu. FABRICATION OF NICKEL FOAM BASED MnO2 MONOLITHIC CATALYSTS AND ITS APPLICATION IN CATALYTIC ELIMINATION OF TOLUENE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 71-78,115. doi: 10.13205/j.hjgc.202304010
shu

FABRICATION OF NICKEL FOAM BASED MnO2 MONOLITHIC CATALYSTS AND ITS APPLICATION IN CATALYTIC ELIMINATION OF TOLUENE

doi: 10.13205/j.hjgc.202304010

  • 1. State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210046, China;

  • 2. Jiujiang Ecological Environment Early Warning Emergency Control Center, Jiujiang 332000, China

  • Received Date: 2022-05-14
    Available Online: 2023-05-26
  • Publish Date: 2023-04-01
    Abstract
  • The crucial point of the industrial application of VOCs catalytic oxidation is to develop efficient and stable monolithic catalysts. Traditional monolithic catalysts were prepared by coating and impregnating the ceramic carrier, which led to uneven distribution of active components, low utilization rate, and even deactivation, thereby reducing the performance of monolithic catalysts. In this study, a MnO2 monolithic catalyst (MnO2/NF-IS) was prepared in situ by the redox reaction between nickel foam and KMnO4. The catalytic performance of the as-obtained catalysts for toluene oxidation was investigated. Besides, the catalysts were characterized by XRD, SEM, TEM, H2-TPR, O2-TPD, and XPS, and the degradation pathway of toluene oxidation was investigated. It has been shown that MnO2/NF-IS had a special structure of porous nanosheet arrays and abundant oxygen vacancies, delivering the best performance for toluene oxidation (T90=248 ℃), which was better than that of powder MnO2 (T90=271 ℃) as well as the integrated MnO2/NF-WC (T90=293 ℃) prepared by the coating method. Therefore, a new strategy for the synthesis of MnO2 monolithic catalysts was provided in this study.
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    • References(15)
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