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Wang Peng Wang Xiaofeng Wu Guiwu, . RESEARCH ON GROUNDWATER POLLUTION IN AN INDUSTRIAL SITE IN THE UPPERCAMBRIAN STRATA[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(6): 35-38. doi: 10.13205/j.hjgc.201506008
Citation: CAO Qiang, LI Yuran, WANG Bin, WANG Jiancheng, ZHU Tingyu. DEACTIVATION MECHANISM OF γ-Al2O3 BASED CATALYSTS FOR THE CATALYTIC HYDROLYSIS OF CARBONYL SULFIDE IN PRESENCE OF HCl[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(12): 182-189. doi: 10.13205/j.hjgc.202312022

DEACTIVATION MECHANISM OF γ-Al2O3 BASED CATALYSTS FOR THE CATALYTIC HYDROLYSIS OF CARBONYL SULFIDE IN PRESENCE OF HCl

doi: 10.13205/j.hjgc.202312022
  • Received Date: 2023-03-28
    Available Online: 2024-03-08
  • With the implementation of ultra-low emissions in the iron and steel industry, applying blast furnace gas desulfurization technology is very urgent. The sulfur-containing component in blast furnace gas mainly is carbonyl sulfide (COS), and the catalytic hydrolysis method on the γ-Al2O3-based catalyst is usually selected to generate H2S and then further removed. However, the hydrolysis catalyst is easily deactivated in the presence of HCl from the blast furnace gas. In this work, the γ-Al2O3-based catalyst was prepared by the impregnation method supported with alkali metals, Na or K, as an active component. The effect of HCl on the hydrolysis activity and deactivation mechanism of the catalyst was investigated through the combined platform of a fixed-bed reactor and gas chromatography. The hydrolysis efficiency of COS was tested at 120 ℃, gas hourly space velocity (GHSV) of 150000 h-1. The results showed that hydrolysis efficiency and chlorine resistance on catalysts Na/Al2O3 and K/Al2O3 were higher than that on γ-Al2O3, and the chlorine resistance on Na/Al2O3 was higher than that on K/Al2O3. The active components, Na and K increased the content of alkaline centers of the catalyst, promoted the COS hydrolysis reaction and improved the catalyst activity. The active component Na or K preferentially reacts with HCl to form metal chloride, weakens the chlorination effect of HCl on the support components and improves the chlorine resistance of the catalyst. The deactivation mechanism of Na/Al2O3 and K/Al2O3 catalysts in the presence of HCl was investigated. HCl occupied the medium-strong alkaline center (M—O) of the catalysts and reacted with the active components of alkali metals to form metal chloride (M—Cl), and then reduced the catalyst activity. The loss of Na in Na/Al2O3 in the presence of HCl was significantly lower than K in K/Al2O3, which improved the chlorine resistance of Na/Al2O3 catalyst.
  • [1]
    World Steel in Figures 2023[EB/OL] https://worldsteel.org/steel-topics/statistics/world-steel-in-figures-2023/.
    [2]
    郭玉华.高炉煤气净化提质利用技术现状及未来发展趋势[J].钢铁研究学报, 2020, 32(7): 525-531.
    [3]
    王斌,林玉婷,李玉然,等.高炉煤气羰基硫催化水解过程影响因素[J].洁净煤技术, 2021, 27(5): 233-238.
    [4]
    CAO R, NING P, WANG X Q, et al. Low-temperature hydrolysis of carbonyl sulfide in blast furnace gas using Al2O3-based catalysts with high oxidation resistance[J]. Fuel, 2021,310: 122295.
    [5]
    刘艳敏,辛渊,李保良,等.氯元素对高炉煤气管道的腐蚀与预防[J].天津冶金,2022(5):8-10,14.
    [6]
    程正霖,朱晓华,李鹏飞.高炉生产过程中氯的来源、迁移转化及影响[J].环境工程,2021,39(4):86-91.
    [7]
    李雯博,史连军,王梦,等.合成气制甲醇CuZnAl催化剂失活因素研究[J].天然气化工(C1化学与化工),2020,45(5):31-38.
    [8]
    李春虎,郭汉贤,谈世韶.碱改性γ-Al2O3催化剂表面碱强度分布与COS水解活性的研究[J].分子催化,1994(4):305-312.
    [9]
    YAO X J, GAO F, DONG L. The application of incorporation model in γ-Al2O3 supported single and dual metal oxide catalysts: a review[J]. Chin J Catal, 2013,34: 1975-1985.
    [10]
    LI C M, ZHAO S Y, YAO X L, et al. The catalytic mechanism of intercalated chlorine anions as active basic sites in MgAl-layered double hydroxide for carbonyl sulfide hydrolysis[J]. Environmental Science and Pollution Research, 2022, 29(7):10605-10616.
    [11]
    CHANG F Y, CHEN J C, WEY M Y. Effects of oxygen and hydrogen chloride on NO removal efficiency by Rh/Al2O3 and Rh-Na/Al2O3 catalysts[J]. Applied Catalysis A: General, 2009, 359(1/2): 88-95.
    [12]
    ZHAO S Z, YI H H, TANG X L, et al. Calcined ZnNiAl hydrotalcite-like compounds as bifunctional catalysts for carbonyl sulfide removal[J]. Catalysis Today, 2019, 327: 161-167.
    [13]
    YI H H, ZHAO S Z, TANG X L, et al. Influence of calcination temperature on the hydrolysis of carbonyl sulfide over hydrotalcite-derived Zn-Ni-Al catalyst[J]. Catalysis Communications, 2011, 12(15): 1492-1495.
    [14]
    ZHAO S Z, YI H H, TANG X L, et al. Low temperature hydrolysis of carbonyl sulfide using Zn-Al hydrotalcite-derived catalysts[J]. Chemical Engineering Journal, 2013, 226: 161-165.
    [15]
    KIM S, GUPTA N K, BAE J, et al. Fabrication of coral-like Mn2O3/Fe2O3 nanocomposite or room temperature removal of hydrogen sulfide[J]. Journal of Environmental Chemical Engineering, 2021, 9(3): 105216.
    [16]
    GUPTA N K, BAE J, KIM K S. Metal organic framework derived NaCoxOy for room temperature hydrogen sulfide removal[J]. Scientific Reports, 2021, 11(1): 14740.
    [17]
    MENG W, WANG X, DAI Q, et al. Catalytic combustion of chlorobenzene over Mn-Ce/Al2O3 catalyst promoted by Mg[J]. Catalysis Communications, 2010, 11(12):1022-1025.
    [18]
    WANG Q, LIN F, ZHOU J, et al. Effect of HCl and o-DCBz on NH3-SCR of NO over MnOx/TiO2 and MnOx-CeO2/TiO2 catalysts[J]. Applied Catalysis A: General, 2020, 605: 117801.
    [19]
    LIN F, WANG Q L, HUANG X L, et al. Investigation of chlorine-poisoning mechanism of MnOx/TiO2 and MnOx-CeO2/TiO2 catalysts during o-DCBz catalytic decomposition: experiment and first-principles calculation[J]. Journal of Environmental Management,2021: 298.
    [20]
    李凯. COS、CS2水解催化剂的开发及机理研究[D].昆明:昆明理工大学,2013.
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