Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 42 Issue 1
Jan.  2024
Turn off MathJax
Article Contents
Abstract
References
Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2024  >  42(1): 85-94
Huo Pan, Cao Liwen, Tian Yanfeng. APPLICATION AND COMPARISON OF AHP AND FUZZYEVALUATION METHOD IN LANDFILL SITING[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(3): 131-135. doi: 10.13205/j.hjgc.201503026
Citation: YANG Quan, LIU Sha, JIANG Chaochao, LIU Rongrong, ZHANG Peng, QIN Caihong. DEGRADATION OF CHLOROBENZENE BY NONTHERMAL PLASMA COUPLED LIQUID PHASE Fe-C CATALYSIS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(1): 85-94. doi: 10.13205/j.hjgc.202401012
shu

DEGRADATION OF CHLOROBENZENE BY NONTHERMAL PLASMA COUPLED LIQUID PHASE Fe-C CATALYSIS

doi: 10.13205/j.hjgc.202401012

  • 1. School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;

  • 2. China Qiyuan Engineering Design Institute Co., Ltd., Xi'an 710000, China

  • Received Date: 2023-06-12
    Available Online: 2024-04-29
    Abstract
  • Single non-thermal plasma technology(NTP) and single wet heterogeneous catalytic technology for the degradation of VOCs suffer from the problems of O3 emission and the need for continuous oxidant supply, respectively. To overcome the single technology bottleneck, this study combines NTP with wet heterogeneous catalytic technology for the degradation of chlorobenzene(CB), using NTP by-product O3 as the oxidant source for the wet system to achieve deep mineralization of CB. Activated carbon(AC) was used as the support for the heterogeneous catalyst, and a surface loaded with different metal fractions was injected into the wet reactor. Experimental results showed that the NTP-coupled liquid-phase heterogeneous system significantly improved the degradation of chlorobenzene(CB), compared to a single NTP. The best CB degradation performance was obtained for the coupled system when Fe was used as the active component, the Fe-C catalyst was injected at a dosage of 1 g/L, the initial pH of the solution was 7, and the supply voltage was 14 kV, and the CB removal efficiency and mineralization rate reached 81.4% and 48%, respectively. Fe-C injection increased the CB absorption mass transfer coefficient in the liquid phase from 0.0280 s-1 to 0.1207 s-1, resulting in a mass transfer enhancement factor of 9.81 for the catalytic process. Finally, the CB degradation pathway was deduced from the intermediates of each system.
    • FullText(HTML)
    • References(38)
  • [1]
    WAN J,YANG P,GUO X,et al.Elimination of 1,2-dichloroethane over (Ce,Cr)xO2/Nb2O5 catalysts:synergistic performance between oxidizing ability and acidity[J].Chinese Journal of Catalysis,2019,40(7):1100-1108.
    [2]
    LI T,LI H,LI C.A review and perspective of recent research in biological treatment applied in removal of chlorinated volatile organic compounds from waste air[J].Chemosphere,2020,250:126338.
    [3]
    YANG B,NIU X,DING C,et al.Performance of biotrickling filter inoculated with activated sludge for chlorobenzene removal[J].Procedia Environmental Sciences,2013,18:391-396.
    [4]
    CHANG T,ZHAO Z,LEUS K,et al.The remarkable oxidation of trichloroethylene in a post-plasma-catalytic system over Ag-Mn-Ce/HZSM-5 catalysts[J].Fuel,2023,334:126746.
    [5]
    JAFARI A J,MOSLEMZADEH M,ESRAFILI A,et al.Synthesis of new composite based on TiO2 immobilized in glass fibers for photo-catalytic degradation of chlorobenzene in aqueous solutions[J].Environmental Research,2022,204:112018.
    [6]
    NAZARI R,RAJI<mathml id="115"><math xmlns="http://www.w3.org/1998/Math/MathML"><mrow><mrow><mover><mstyle mathsize="140%" displaystyle="true"><mtext>C</mtext></mstyle><mo>´</mo></mover></mrow><mspace width="0.25em" /><mtext>L</mtext><mo>,</mo><mspace width="0.25em" /><mtext>C</mtext><mtext>Ι</mtext><mtext>B</mtext><mtext>L</mtext><mtext>A</mtext><mtext>Κ</mtext><mspace width="0.25em" /><mtext>A</mtext></mrow></math></mathml>,et al.Immobilized palladium-catalyzed electro-Fenton’s degradation of chlorobenzene in groundwater[J].Chemosphere,2019,216:556-563.
    [7]
    LEE B,KIM D W,PARK D W.Dielectric barrier discharge reactor with the segmented electrodes for decomposition of toluene adsorbed on bare-zeolite[J].Chemical Engineering Journal,2019,357:188-197.
    [8]
    ZHU R,MAO Y,JIANG L,et al.Performance of chlorobenzene removal in a nonthermal plasma catalysis reactor and evaluation of its byproducts[J].Chemical Engineering Journal,2015,279:463-471.
    [9]
    PHAM HUU T,SIVACHANDIRAN L,DA COSTA P,et al.Methane,propene and toluene oxidation by plasma-Pd/γ-Al2O3 hybrid reactor:investigation of a synergetic effect[J].Topics in Catalysis,2017,60(3):326-332.
    [10]
    DINH M T N,GIRAUDON J M,VANDENBROUCKE A M,et al.Post plasma-catalysis for total oxidation of trichloroethylene over Ce-Mn based oxides synthesized by a modified “redox-precipitation route”[J].Applied Catalysis B:Environmental,2015,172-173:65-72.
    [11]
    QIN C,JIANG C,GUO M,et al.Dielectric barrier discharge coupled with Fe2+,Mn2+ and Cu2+ scrubbing for toluene removal[J].Chemosphere,2022,290:133306.
    [12]
    CHAUVEAU R,GRÉVILLOT G,MARSTEAU S,et al.Values of the mass transfer coefficient of the linear driving force model for VOC adsorption on activated carbons[J].Chemical Engineering Research and Design,2013,91(5):955-962.
    [13]
    CHEN H,LIU J,PEI Y,et al.Study on the synergistic effect of UV/Fenton oxidation and mass transfer enhancement with addition of activated carbon in the bubble column reactor[J].Chemical Engineering Journal,2018,336:82-91.
    [14]
    DAI Q,WANG J,CHEN J,et al.Ozonation catalyzed by cerium supported on activated carbon for the degradation of typical pharmaceutical wastewater[J].Separation and Purification Technology,2014,127:112-120.
    [15]
    杨文清,李旭凯,李来胜,等.活性炭负载金属氧化物催化臭氧氧化甲硝唑[J].环境工程学报,2011,5(4):763-766.
    [16]
    HE C,LIAO Y,CHEN C,et al.Realizing a redox-robust Ag/MnO2 catalyst for efficient wet catalytic ozonation of S-VOCs:promotional role of Ag(0)/Ag(I)-Mn based redox shuttle[J].Applied Catalysis B:Environmental,2022,303:120881.
    [17]
    FARIA P C C,ÓRFÃO J J M,PEREIRA M F R.Ozonation of aniline promoted by activated carbon[J].Chemosphere,2007,67(4):809-815.
    [18]
    熊威.活性炭及其负载铁锰催化臭氧氧化苯酚的研究[D].北京:中国地质大学(北京),2019.
    [19]
    李宗泽.磁性纳米催化剂制备及其催化芬顿氧化降解染料性能研究[D].石家庄:河北科技大学,2017.
    [20]
    LIU Z Q,TU J,WANG Q,et al.Catalytic ozonation of diethyl phthalate in aqueous solution using graphite supported zinc oxide[J].Separation and Purification Technology,2018,200:51-58.
    [21]
    陈天翼.超细活性炭催化臭氧氧化与陶瓷膜耦合处理废水效能研究[D].北京:清华大学,2017.
    [22]
    HUANG Y,CUI C,ZHANG D,et al.Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon[J].Chemosphere,2015,119:295-301.
    [23]
    QI F,CHU W,XU B.Ozonation of phenacetin in associated with a magnetic catalyst CuFe2O4:the reaction and transformation[J].Chemical Engineering Journal,2015,262:552-562.
    [24]
    ZHANG H,JI F,ZHANG Y,et al.Catalytic ozonation of N,N-dimethylacetamide (DMAC) in aqueous solution using nanoscaled magnetic CuFe2O4[J].Separation and Purification Technology,2018,193:368-377.
    [25]
    NAWROCKI J.Catalytic ozonation in water:controversies and questions.Discussion paper[J].Applied Catalysis B:Environmental,2013,142-143:465-471.
    [26]
    WANG J,CHEN H.Catalytic ozonation for water and wastewater treatment:recent advances and perspective[J].Science of the Total Environment,2020,704:135249.
    [27]
    WANG T,QU G,REN J,et al.Evaluation of the potentials of humic acid removal in water by gas phase surface discharge plasma[J].Water Research,2016,89:28-38.
    [28]
    REN J,LI J,JIANG N,et al.Degradation of trans-ferulic acid in aqueous solution by a water falling film DBD reactor:degradation performance,response surface methodology,reactive species analysis and toxicity evaluation[J].Separation and Purification Technology,2020,235:116226.
    [29]
    IKHLAQ A,BROWN D R,KASPRZYK-HORDERN B.Catalytic ozonation for the removal of organic contaminants in water on alumina[J].Applied Catalysis B:Environmental,2015,165:408-418.
    [30]
    LIANG W,LI J,LI J,et al.Abatement of toluene from gas streams via ferro-electric packed bed dielectric barrier discharge plasma[J].Journal of Hazardous Materials,2009,170(2):633-638.
    [31]
    LIU X,LIU J,CHEN J,et al.Mn2O3/γ-Al2O3 catalysts synergistic double dielectric barrier discharge (DDBD) degradation of toluene,ethyl-acetate and acetone[J].Chemosphere,2021,284:131299.
    [32]
    SUDHAKARAN M S P,TRINH H Q,KARUPPIAH J,et al.Plasma catalytic removal of p-Xylene from air stream using γ-Al2O3 supported manganese catalyst[J].Topics in Catalysis,2017,60(12):944-954.
    [33]
    LI S,YU X,DANG X,et al.Using non-thermal plasma for decomposition of toluene adsorbed on γ-Al2O3 and ZSM-5:configuration and optimization of a double dielectric barrier discharge reactor[J].Chemical Engineering Journal,2019,375:122027.
    [34]
    TIAN X,ZHU J,TANG M,et al.Surface acidity and basicity of Mg/Al hydrotalcite for 2,4-dichlorophenoxyacetic acid degradation with ozone:mineralization,mechanism,and implications to practical water treatment[J].Journal of Hazardous Materials,2021,402:123475.
    [35]
    TIAN S Q,QI J Y,WANG Y P,et al.Heterogeneous catalytic ozonation of atrazine with Mn-loaded and Fe-loaded biochar[J].Water Research,2021,193:116860.
    [36]
    ZHOU W,YE Z,NIKIFOROV A,et al.The influence of relative humidity on double dielectric barrier discharge plasma for chlorobenzene removal[J].Journal of Cleaner Production,2021,288:125502.
    [37]
    ZAZOU H,OTURAN N,SÖNMEZ-ÇELEBI M,et al.Mineralization of chlorobenzene in aqueous medium by anodic oxidation and electro-Fenton processes using Pt or BDD anode and carbon felt cathode[J].Journal of Electroanalytical Chemistry,2016,774:22-30.
    [38]
    JOSE J,PHILIP L.Degradation of chlorobenzene in aqueous solution by pulsed power plasma:mechanism and effect of operational parameters[J].Journal of Environmental Chemical Engineering,2019,7(6):103476.
    • Relative Articles

  • Relative Articles

    [1]WU Qi, FAN Jian-wei. LANDFILL LEACHATE TREATMENT BY FENTON-LIKE PROCESS WITH Fe3O4-RGO NANO-COMPOSITE CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 25-30. doi: 10.13205/j.hjgc.202205004
    [2]ZHA Wengui, WANG Xueye, WANG Zhiwei. PILOT-SCALE STUDY ON MEMBRANE-CATHODE ELECTRO-FENTON PROCESS FOR PRETREATMENT OF SEMICONDUCTOR WASTEWATER[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(4): 153-158,208. doi: 10.13205/j.hjgc.202204022
    [3]WANG Hao, TAN Ying-feng, LIU Guo-liang, WANG Xiao-shuang, WEI Lei, YUAN Mao-mao, ZHANG Zhi-qiang, QIU Hao-ran. MBR PROCESS DESIGN IN A RECLAIMED WATER PLANT IN NORTH CHINA[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 167-172. doi: 10.13205/j.hjgc.202107023
    [4]LV Long, ZHANG Yi-xiao, ZHANG Ying, MENG Fan-long, LI Chao, WANG Han. OPERATION EFFECT ANALYSIS OF NEW ADDED MEMBRANE CASSETTES IN A MBR MEMBRANE SYSTEM IN A WASTEWATER TREATMENT PLANT[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 162-166,144. doi: 10.13205/j.hjgc.202107022
    [5]CHEN Zuo-yun. PHOTO-FENTON DEGRADATION WITH FEOCL CATALYST IN WASTEWATER FROM PASSENGER TRAIN TOILETS[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(10): 128-133,139. doi: 10.13205/j.hjgc.202010020
    [6]WANG hui, ZHANG Si-yong, WANG Ya-jun. RESEARCH PROGRESS ON TREATMENT EFFECT OF PAC ENHANCED MBR PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(8): 147-153. doi: 10.13205/j.hjgc.202008025
    [12]Gong Ming Xu Lezhong, . EXPERIMENT ON SCREENING OF SUITABLE FILLER FOR DYEING WASTEWATER ADVANCED TREATMENT[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(7): 51-55?.
    • Supplements(0)
    • Cited By

  • Cited by

    Periodical cited type(11)

    1. 赵舒. 高级氧化法在工业废水处理领域中的应用. 辽宁化工. 2024(01): 129-131+169 .
    2. 李社锋，张家琛，冯巍，陈培，辜琦，李琳. 膜生物反应器研究新进展与应用. 环境工程. 2024(01): 37-46 . 本站查看
    3. 王学良，杨永奎. 臭氧催化氧化在单晶硅切削液废水处理的工程应用. 工业水处理. 2024(03): 195-198 .
    4. 闫敏琪，韩玉，杨淳轲，史惠祥. 生物炭负载纳米零价铁催化降解亚甲基蓝性能研究及机理分析. 浙江大学学报(理学版). 2024(03): 355-369 .
    5. 李志利，王海涛，霍汉鑫，赵瑾，张艺钟，王勋亮，郭健，姜天翔，马宇辉. 废瓦楞纸基磁性生物炭气凝胶的制备及其亚甲基蓝吸附性能. 环境工程. 2024(12): 210-217 . 本站查看
    6. 王思祺，刘思乐，卜义夫，万帅龙，张延祥，迟久明. 石墨相氮化碳的制备、表征及光催化性能研究. 精细石油化工进展. 2023(02): 21-24+30 .
    7. 余琴芳，余太平，刘琪，刘海燕，镇祥华. 印染工业园区污水处理厂深度处理工艺应用综述. 净水技术. 2023(05): 29-35 .
    8. 黄发明，申超，何利，王禹来，王超涛. 混凝-沉淀法处理工业园区污水厂二级生化出水悬浮物研究. 环境工程. 2023(S1): 113-116 . 本站查看
    9. 覃建军，黄福瑶，胡振. 人工快渗工艺在污水处理厂出水深度处理的应用. 绿色科技. 2023(10): 161-165 .
    10. 贺利飞. 基于UASB/MBR的废水厌氧处理工艺优化. 化学工程师. 2023(09): 48-52 .
    11. 陈虹霖. 印染废水深度处理及回用技术探讨. 资源节约与环保. 2023(09): 88-91 .

    Other cited types(10)

  • Created with Highcharts 5.0.7Amount of accessChart context menuAbstract Views, HTML Views, PDF Downloads StatisticsAbstract ViewsHTML ViewsPDF Downloads2024-052024-062024-072024-082024-092024-102024-112024-122025-012025-022025-032025-0401020304050
    Created with Highcharts 5.0.7Chart context menuAccess Class DistributionFULLTEXT: 11.7 %FULLTEXT: 11.7 %META: 83.2 %META: 83.2 %PDF: 5.1 %PDF: 5.1 %FULLTEXTMETAPDF
    Created with Highcharts 5.0.7Chart context menuAccess Area Distribution其他: 13.8 %其他: 13.8 %China: 0.2 %China: 0.2 %[]: 0.2 %[]: 0.2 %上海: 2.1 %上海: 2.1 %东莞: 2.3 %东莞: 2.3 %临汾: 0.2 %临汾: 0.2 %佛山: 0.2 %佛山: 0.2 %北京: 3.2 %北京: 3.2 %十堰: 0.6 %十堰: 0.6 %南京: 3.2 %南京: 3.2 %南昌: 0.6 %南昌: 0.6 %南通: 1.1 %南通: 1.1 %台州: 1.5 %台州: 1.5 %合肥: 0.4 %合肥: 0.4 %嘉兴: 0.4 %嘉兴: 0.4 %天津: 1.9 %天津: 1.9 %太原: 0.4 %太原: 0.4 %威海: 0.4 %威海: 0.4 %安庆: 0.2 %安庆: 0.2 %宣城: 0.4 %宣城: 0.4 %宿迁: 0.4 %宿迁: 0.4 %常州: 0.9 %常州: 0.9 %常德: 0.2 %常德: 0.2 %广州: 0.4 %广州: 0.4 %张家口: 0.6 %张家口: 0.6 %张家界: 0.2 %张家界: 0.2 %德州: 0.2 %德州: 0.2 %惠州: 0.6 %惠州: 0.6 %成都: 1.1 %成都: 1.1 %扬州: 1.5 %扬州: 1.5 %无锡: 0.4 %无锡: 0.4 %昆明: 0.6 %昆明: 0.6 %晋城: 0.4 %晋城: 0.4 %朝阳: 0.2 %朝阳: 0.2 %杭州: 2.6 %杭州: 2.6 %武汉: 1.9 %武汉: 1.9 %泉州: 0.4 %泉州: 0.4 %济南: 0.6 %济南: 0.6 %济源: 0.4 %济源: 0.4 %海口: 0.2 %海口: 0.2 %淮南: 0.2 %淮南: 0.2 %深圳: 0.2 %深圳: 0.2 %温州: 0.6 %温州: 0.6 %湖州: 0.6 %湖州: 0.6 %漯河: 5.5 %漯河: 5.5 %漳州: 0.6 %漳州: 0.6 %潍坊: 0.4 %潍坊: 0.4 %珠海: 0.4 %珠海: 0.4 %石家庄: 0.2 %石家庄: 0.2 %肇庆: 0.2 %肇庆: 0.2 %芒廷维尤: 24.5 %芒廷维尤: 24.5 %芝加哥: 0.4 %芝加哥: 0.4 %苏州: 0.4 %苏州: 0.4 %荆州: 0.4 %荆州: 0.4 %萍乡: 0.2 %萍乡: 0.2 %蚌埠: 0.2 %蚌埠: 0.2 %衡阳: 0.2 %衡阳: 0.2 %衢州: 1.1 %衢州: 1.1 %西宁: 6.6 %西宁: 6.6 %西安: 0.6 %西安: 0.6 %诺沃克: 0.6 %诺沃克: 0.6 %贵阳: 0.9 %贵阳: 0.9 %资阳: 0.2 %资阳: 0.2 %运城: 1.9 %运城: 1.9 %遵义: 0.2 %遵义: 0.2 %邯郸: 0.6 %邯郸: 0.6 %郑州: 2.1 %郑州: 2.1 %金华: 0.4 %金华: 0.4 %长沙: 1.1 %长沙: 1.1 %长治: 0.2 %长治: 0.2 %鞍山: 0.2 %鞍山: 0.2 %其他China[]上海东莞临汾佛山北京十堰南京南昌南通台州合肥嘉兴天津太原威海安庆宣城宿迁常州常德广州张家口张家界德州惠州成都扬州无锡昆明晋城朝阳杭州武汉泉州济南济源海口淮南深圳温州湖州漯河漳州潍坊珠海石家庄肇庆芒廷维尤芝加哥苏州荆州萍乡蚌埠衡阳衢州西宁西安诺沃克贵阳资阳运城遵义邯郸郑州金华长沙长治鞍山

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (99) PDF downloads(4) Cited by(21)
    Proportional views
    Related

    Journal Online

    Authors' Center

    Links

    Copyright © 《工业建筑》杂志社有限公司 京ICP备11033253号-1

    Supported by: Beijing Renhe Information Technology Co. Ltd     百度统计

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return