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Volume 42 Issue 2
Feb.  2024
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2024  >  42(2): 121-127
LI Xuan, WANG Yan, FANG Hua, ZHANG Tingting, ZHAO Yi. INFLUENCING FACTORS OF STABILITY OF GRAPHENE OXIDE IN WATER[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(2): 121-127. doi: 10.13205/j.hjgc.202402014
Citation: LI Xuan, WANG Yan, FANG Hua, ZHANG Tingting, ZHAO Yi. INFLUENCING FACTORS OF STABILITY OF GRAPHENE OXIDE IN WATER[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(2): 121-127. doi: 10.13205/j.hjgc.202402014
shu

INFLUENCING FACTORS OF STABILITY OF GRAPHENE OXIDE IN WATER

doi: 10.13205/j.hjgc.202402014

  • 1. Jiangsu Environmental Engineering Technology Co., Ltd., Nanjing 210019, China;

  • 2. School of Environmental Science & Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China

  • Received Date: 2023-06-27
    Available Online: 2024-04-28
    Abstract
  • Based on the analysis of the physicochemical properties of graphene oxide(GO), the effects of electrolyte, natural organic matter(NOM), and stable solution concentration on its aggregation and sedimentation in water were studied. The results showed that the concentration of GO stable solution had little effect on its physicochemical properties and stability in water. Electrolytes induced the GO aggregation by reducing Zeta potential in water. The aggregation process presented two stages: reaction limited and diffusion limited. The critical condensation concentrations(CCC) of each electrolyte were 180 mmol/L of Na+, 4.5 mmol/L of Mg2+ and 1.8 mmol/L of Ca2+, respectively. Compared with Mg2+, Ca2+ could strengthen the aggregation process by adsorption bridging. The sedimentation process of GO was also divided into two stages: rapid sedimentation and slow sedimentation, and aggregation was the main factor affecting GO sedimentation. The presence of natural organic matter could effectively inhibit coagulation and enhance the stability of GO in water. However, HA has a complex correlation with GO and Ca2+, which further accelerates the aggregation process. With the increase of GO concentration in water, the aggregation and sedimentation rate were accelerated. In the presence of a lower concentration, GO had higher stability in the water environment.
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    • References(19)
  • [1]
    ZHAO J,LIN M,WANG Z,et al.Engineered nanomaterials in the environment:are they safe?[J].Critical Reviews in Environmental Science and Technology,2020:1-36.
    [2]
    BOULANGER N,KUZENKOVA A,IAKUNKOV A,et al.Enhanced sorption of radionuclides by defect-rich graphene oxide[J].ACS Applied Materials & Interfaces,2020,12 (40):45122-45135.
    [3]
    张婷婷,孔祥清,付莹,等.以城市污泥为基质制备氧化石墨烯的响应面优化[J].环境工程,2022,40(7):25-30

    ,51.
    [4]
    MA C,WHITE J C,DHANKHER O P,et al.Metal-based nanotoxicity and detoxification pathways in higher plants[J].Environmental Science & Technology,2015,49(12):7109-7122.
    [5]
    BARRIOS A,WANG Y,GILBERTSON L,et al.Structure-property-toxicity relationships of graphene oxide:role of surface chemistry on the mechanisms of interaction with bacteria[J].Environmental Science & Technology,2019,53(24):14679-14687.
    [6]
    LANPHERE J D,LUTH C J,WALKER S L.Effects of solution chemistry on the transport of graphene oxide in saturated porous media[J].Environmental Science & Technology,2013,47(9):4255-4261.
    [7]
    杨艺,张焕祯,刘俊峰.纳米颗粒在水环境中的团聚行为和毒性效应研究[J].环境工程,2016,34(9):17-21.
    [8]
    方华,章婷婷,于江华,等.天然有机物对水中氧化石墨烯凝聚的影响[J].环境化学,2019,38(6):1251-1257.
    [9]
    赖奇,罗学萍.氧化石墨烯的制备和定性定量分析[J].材料研究学报,2015,29(2):155-160.
    [10]
    CHEN K L,ELIMELECH M.Aggregation and deposition kinetics of fullerene (C60) nanoparticles[J].Langmuir:the ACS Journal of Surfaces & Colloids,2006,22(26):10994-11001.
    [11]
    LEE M C,SNOEYINK V L,CRITTENDEN J C.Activated carbon adsorption of humic substances[J].Journal American Water Works Association,1981(8):440-446.
    [12]
    TANG H,ZHAO Y,YANG X,et al.New insight into the aggregation of graphene oxide using molecular dynamics simulations and extended Derjaguin-Landau-Verwey-Overbeek theory[J].Environmental Science & Technology,2017,51(17):9674-9682.
    [13]
    SU Y,YANG G,LU K,et al.Colloidal properties and stability of aqueous suspensions of few-layer graphene:importance of graphene concentration[J].Environmental Pollution,2017,220(PT A):469-477.
    [14]
    CHOWDHURY I,DUCH M C,MANSUKHANI N D,et al.Colloidal properties and stability of graphene oxide nanomaterials in the aquatic environment[J].Environmental Science& Technology,2013,47(12):6288-6296.
    [15]
    石磊,庞宏伟,王祥学,等.氧化石墨烯在水体中的迁移转化机制研究[J].化学学报,2019,77(11):1177-1183.
    [16]
    PETOSA A R,JAISI D P,QUEVEDO I R,et al.Aggregation and deposition of engineered nanomaterials in aquatic environments:role of physicochemical interactions[J].Environmental Science & Technology,2010,44(17):6532-6549.
    [17]
    WANG X,SHU L,WANG Y,et al.Sorption of peat humic acids to multi-walled carbon nanotubes[J].Environmental Science & Technology,2011,45(21):9276-9283.
    [18]
    TAN X,FANG M,LI J,et al.Adsorption of Eu(Ⅲ) onto TiO2:effect of pH,concentration,ionic strength and soil fulvic acid[J].Journal of Hazardous Materials,2009,168(1):458-465.
    [19]
    CHEN K L,ELIMELECH M.Influence of humic acid on the aggregation kinetics of fullerene (C60) nanoparticles in monovalent and divalent electrolyte solutions[J].Journal of Colloid and Interface Science,2007,309(1):126-134.
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