HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H<sub>2</sub>O<sub>2</sub> SYSTEM FOR DEGRADATION OF ORANGE G

WANG Zhenran; PENG Yunlan; LIU Yiqing; FU Yongsheng

doi:10.13205/j.hjgc.202404013

Volume 42 Issue 4

Apr. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(4): 111-118

WANG Zhenran, PENG Yunlan, LIU Yiqing, FU Yongsheng. HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H2O2 SYSTEM FOR DEGRADATION OF ORANGE G[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 111-118. doi: 10.13205/j.hjgc.202404013

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WANG Zhenran, PENG Yunlan, LIU Yiqing, FU Yongsheng. HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H₂O₂ SYSTEM FOR DEGRADATION OF ORANGE G[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 111-118. doi: 10.13205/j.hjgc.202404013

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HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H₂O₂ SYSTEM FOR DEGRADATION OF ORANGE G

doi: 10.13205/j.hjgc.202404013

Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University,Chengdu 611756, China

Received Date: 2023-04-18
Available Online: 2024-06-01

Abstract

Abstract

To improve the shortcomings of the traditional Fenton method, such as narrow pH application range and high iron mud production, the present study developed an Fe(Ⅲ)-nitrilotriacetic acid (NTA)/hydroxylamine (HAm)/H₂O₂ system for the degradation of azo dye Orange G (OG). Experimental results demonstrated that Fe(Ⅲ)-NTA/HAm/H₂O₂ system could effectively degrade OG under neutral condition with a degradation rate of 90% above, and ·OH was the dominant reactive species responsible for OG degradation in this system. The degradation rate of OG in the Fe(Ⅲ)-NTA/HAm/H₂O₂ system decreased with the increase of solution pH. Appropriate increases in Fe(Ⅲ), NTA, HAm, and H₂O₂ concentrations were beneficial for OG degradation in this system, but excessive addition of these reagents would inhibit OG degradation. The introduction of NTA could expand the pH application range of the traditional Fenton process from acidic to weakly alkaline, and the addition of HAm remarkedly reduced the dosage of Fe by promoting the regeneration of Fe(Ⅱ) in the system. Compared with the traditional Fenton process, this Fe(Ⅲ)-NTA/HAm/H₂O₂ system showed great potential for practical applications.
- hydroxylamine,
- nitrilotriacetic acid,
- Fenton process,
- advanced oxidation technologies,
- Orange G

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References

[1]	袁思杰, 张芮铭. 染料废水处理技术研究进展[J]. 染料与染色, 2022, 59(4): 55-62.
[2]	沈九兵, 谭牛高, 李志超, 等. 印染丝光淡碱液MVR蒸馏系统研究[J]. 现代化工, 2022, 42(6): 206-210.
[3]	张庆云, 宋静茹, 谢学辉, 等. 果糖共代谢强化功能菌群/菌株降解活性黑5效能差异及机制比较[J]. 微生物学通报, 2023, 50(3): 938-953.
[4]	秦秋浦. 偶氮类合成染料的微生物脱色与降解[J]. 应用化工, 2013, 8(增刊1): 172-177.
[5]	张理军, 严群, 周子琳, 等. 硅藻土负载MnFe₂O₄纳米颗粒活化PMS降解金橙Ⅱ[J]. 环境工程, 2022, 40(11): 61-68.
[6]	张华春, 熊国臣. 偶氮染料废水处理方法研究进展[J]. 染料与染色, 2016, 53(3): 45-51.
[7]	CHENG L, WEI M Y, HUANG L H, et al. Efficient H₂O₂ oxidation of organic dyes catalyzed by simple copper(Ⅱ) ions in bicarbonate aqueous solution[J]. Industrial & Engineering Chemistry Research, 2014, 53(9): 3478-3485.
[8]	LI B, DONG Y C, ZOU C, et al. Iron(Ⅲ)-Alginate fiber complex as a highly effective and stable heterogeneous Fenton photocatalyst for mineralization of organic dye[J]. Industrial & Engineering Chemistry Research, 2014, 53(11): 4199-4206.
[9]	姚迎迎. 高级氧化技术在印染废水处理中的研究进展[J]. 广东化工, 2022, 49(4): 117-119.
[10]	LIU Y B, ZHANG X M, DENG J H, et al. A novel CNTs-Fe₃O₄ synthetized via a ball-milling strategy as efficient Fenton-like catalyst for degradation of sulfonamides[J]. Chemosphere, 2021, 277: 130305.
[11]	张波, 戚永洁, 蒋素英, 等. 铁碳微电解-生物膜法-高级氧化工艺处理印染废水中试研究[J]. 环境工程, 2018, 36(3): 44-48.
[12]	PIGNATELLO J, OLIVEROS E, MACKAY A. Advanced oxidation processes for organic contaminant destruction based on Fenton reaction and related chemistry[J]. Critical Reviews in Environmental Science and Technology, 2006, 36: 1-84.
[13]	DA Y F, LIU Y, CHEN Y, et al. Promotion of O₂ activation by ZIF-8 derived N-rich aluminum-graphite (Al-Gr-NPC) composite for non-radical degradation of antibiotic at neutral pH[J]. Separation and Purification Technology, 2023, 308: 122806.
[14]	周小银, 朱铭, 赵聚姣, 等. 紫外光/超声芬顿处理工业废水的研究进展[J]. 环境工程, 2023, 41(增刊1): 1-8.
[15]	VERMA M, HARITASH A K. Degradation of amoxicillin by Fenton and Fenton-integrated hybrid oxidation processes[J]. Journal of Environmental Chemical Engineering, 2019, 7(1): 102886.
[16]	WANG S X, WANG H B, LIU Y Q, et al. Effective degradation of sulfamethoxazole with Fe²⁺-zeolite/peracetic acid[J]. Separation and Purification Technology, 2020, 233: 115973.
[17]	LIU Y, WANG J L. Multivalent metal catalysts in Fenton/Fenton-like oxidation system: a critical review[J]. Chemical Engineering Journal, 2023, 466: 143147.
[18]	CHEN Q, LV F, ZHANG H, et al. Where should Fenton go for the degradation of refractory organic contaminants in wastewater?[J]. Water Research, 2023, 229: 119479.
[19]	WANG L H, JIANG J, MA J, et al. A review on advanced oxidation processes homogeneously initiated by copper(Ⅱ)[J]. Chemical Engineering Journal, 2022, 427: 131721.
[20]	CHEN L W, LI X C, ZHANG J, et al. Production of hydroxyl radical via the activation of hydrogen peroxide by hydroxylamine[J]. Environmental Science & Technology, 2015, 49(17): 10373-10379.
[21]	MEI S C, LI L, HUANG G X, et al. Heterogeneous Fenton water purification catalyzed by iron phosphide (FeP)[J]. Water Research, 2023, 241: 120151.
[22]	JIN Y Y, SUN S P, YANG X Y, et al. Degradation of ibuprofen in water by Fe(Ⅱ)-NTA complex-activated persulfate with hydroxylamine at neutral pH[J]. Chemical Engineering Journal, 2018, 337: 152-160.
[23]	马红芳, 杨浩宇, 田委民, 等. 氨三乙酸强化零价铁/过一硫酸盐降解橙黄G[J]. 中国环境科学, 2021, 41(4): 1597-1607.
[24]	DUAN J, PANG S-Y, WANG Z, et al. Hydroxylamine driven advanced oxidation processes for water treatment: a review[J]. Chemosphere, 2021, 262: 128390.
[25]	国家环境保护总局. 水和废水监测分析方法[M]. 4版. 北京: 中国环境科学出版社, 2002: 368-370.
[26]	姜成春, 庞素艳, 马军, 等. 钛盐光度法测定Fenton氧化中的过氧化氢[J]. 中国给水排水, 2006, 22(4): 88-91.
[27]	HU Y, LI Y L, HE J Y, et al. EDTA-Fe(Ⅲ) Fenton-like oxidation for the degradation of malachite green[J]. Journal of Environmental Management, 2018, 226: 256-263.
[28]	LI Y F, SUN J H, SUN S P. Comparison of metoprolol degradation by Fe(Ⅲ)-NTA modified Fenton-like reaction in the absence and presence of manganese: efficiency and intermediates[J]. Chemical Engineering Journal, 2017, 313: 769-776.
[29]	PENG S W, ZHANG W J, HE J, et al. Enhancement of Fenton oxidation for removing organic matter from hypersaline solution by accelerating ferric system with hydroxylamine hydrochloride and benzoquinone[J]. Journal of Environmental Sciences, 2016, 41: 16-23.
[30]	ZHANG D X, XIANG Y P, LIU G L, et al. Mechanism and controlling factors on rapid methylmercury degradation by ligand-enhanced Fenton-like reaction at circumneutral pH[J]. Chemosphere, 2023, 324: 138291.
[31]	LIU Y Q, HE X X, FU Y S, et al. Degradation kinetics and mechanism of oxytetracycline by hydroxyl radical-based advanced oxidation processes[J]. Chemical Engineering Journal, 2016, 284: 1317-1327.
[32]	DONG H Y, LI Y, WANG S C, et al. Both Fe(Ⅳ) and radicals are active oxidants in the Fe(Ⅱ)/peroxydisulfate process[J]. Environmental Science & Technology Letters, 2020, 7(3): 219-224.
[33]	LI Z Y, LIU Y L, HE P N, et al. Further understanding the role of hydroxylamine in transformation of reactive species in Fe(Ⅱ)/peroxydisulfate system[J]. Chemical Engineering Journal, 2021, 418: 129464.
[34]	MOTEKAITIS R J, MARTELL A E. The iron(Ⅲ) and iron(Ⅱ) complexes of nitrilotriacetic acid[J]. Journal of Coordination Chemistry, 1994, 31(1): 67-78.
[35]	ZHOU P, ZHANG J, LIANG J, et al. Activation of persulfate/copper by hydroxylamine via accelerating the cupric/cuprous redox couple[J]. Water Science and Technology, 2016, 73(3): 493-500.
[36]	LIU Y Q, HE X X, DUAN X D, et al. Photochemical degradation of oxytetracycline: influence of pH and role of carbonate radical[J]. Chemical Engineering Journal, 2015, 276: 113-121.
[37]	RAO Y F, QU L, YANG H, et al. Degradation of carbamazepine by Fe(Ⅱ)-activated persulfate process[J]. Journal of Hazardous Materials, 2014, 268: 23-32.
[38]	LI X, ZHOU M H, PAN Y W. Degradation of diclofenac by H₂O₂ activated with pre-magnetization Fe⁰: influencing factors and degradation pathways[J]. Chemosphere, 2018, 212: 853-862.
[39]	BAE S, KIM D, LEE W. Degradation of diclofenac by pyrite catalyzed Fenton oxidation[J]. Applied Catalysis B: Environmental, 2013, 134-135: 93-102.
[40]	ZHANG Y Q, ZHANG J F, XIAO Y J, et al. Kinetic and mechanistic investigation of azathioprine degradation in water by UV, UV/H₂O₂ and UV/persulfate[J]. Chemical Engineering Journal, 2016, 302: 526-534.