HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H<sub>2</sub>O<sub>2</sub> SYSTEM FOR DEGRADATION OF ORANGE G

WANG Zhenran; PENG Yunlan; LIU Yiqing; FU Yongsheng

doi:10.13205/j.hjgc.202404013

Volume 42 Issue 4

Apr. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(4): 111-118

WANG Zhenran, PENG Yunlan, LIU Yiqing, FU Yongsheng. HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H2O2 SYSTEM FOR DEGRADATION OF ORANGE G[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 111-118. doi: 10.13205/j.hjgc.202404013

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WANG Zhenran, PENG Yunlan, LIU Yiqing, FU Yongsheng. HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H₂O₂ SYSTEM FOR DEGRADATION OF ORANGE G[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 111-118. doi: 10.13205/j.hjgc.202404013

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HYDROXYLAMINE-NITRILOTRIACETIC ACID ENHANCED Fe(Ⅲ)/H₂O₂ SYSTEM FOR DEGRADATION OF ORANGE G

doi: 10.13205/j.hjgc.202404013

Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University,Chengdu 611756, China

Received Date: 2023-04-18
Available Online: 2024-06-01

Abstract

Abstract

To improve the shortcomings of the traditional Fenton method, such as narrow pH application range and high iron mud production, the present study developed an Fe(Ⅲ)-nitrilotriacetic acid (NTA)/hydroxylamine (HAm)/H₂O₂ system for the degradation of azo dye Orange G (OG). Experimental results demonstrated that Fe(Ⅲ)-NTA/HAm/H₂O₂ system could effectively degrade OG under neutral condition with a degradation rate of 90% above, and ·OH was the dominant reactive species responsible for OG degradation in this system. The degradation rate of OG in the Fe(Ⅲ)-NTA/HAm/H₂O₂ system decreased with the increase of solution pH. Appropriate increases in Fe(Ⅲ), NTA, HAm, and H₂O₂ concentrations were beneficial for OG degradation in this system, but excessive addition of these reagents would inhibit OG degradation. The introduction of NTA could expand the pH application range of the traditional Fenton process from acidic to weakly alkaline, and the addition of HAm remarkedly reduced the dosage of Fe by promoting the regeneration of Fe(Ⅱ) in the system. Compared with the traditional Fenton process, this Fe(Ⅲ)-NTA/HAm/H₂O₂ system showed great potential for practical applications.
- hydroxylamine,
- nitrilotriacetic acid,
- Fenton process,
- advanced oxidation technologies,
- Orange G

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References(40)

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