Source Journal of CSCD
Source Journal for Chinese Scientific and Technical Papers
Core Journal of RCCSE
Included in JST China
Volume 42 Issue 4
Apr.  2024
Turn off MathJax
Article Contents
PENG Juanjuan, LIU Shaomin, ZHU Jinglin. OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016
Citation: PENG Juanjuan, LIU Shaomin, ZHU Jinglin. OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 132-138. doi: 10.13205/j.hjgc.202404016

OXIDATION PERFORMANCE OF NITRILOTRIS (METHYLENE PHOSPHONIC ACID) BY POTASSIUM PERMANGANATE

doi: 10.13205/j.hjgc.202404016
  • Received Date: 2023-04-26
    Available Online: 2024-06-01
  • Organic pollutants could be degraded by KMnO4, and the oxidation process of phosphonates by KMnO4 is still unclear. Herein, using nitrilotris (methylene phosphonic acid, NTMP) as a model pollutant, radical capture experiments and electron paramagnetic resonance (EPR) were used to explore the dominant active oxidizing species in KMnO4 system, and the effects of solution chemical properties (such as pH, coexisting substances, actual water body, etc.) on the degradation of NTMP by KMnO4 were investigated. The results showed that direct oxidation of KMnO4 was the dominant pathway for NTMP degradation, and its degradation was greatly influenced by pH value. The best oxidation performance of NTMP by KMnO4 was obtained at pH=5.0, and 51.4% of NTMP was oxidized into PO3-4, much higher than that in UV/H2O2 and UV/potassium persulfate (PDS) system. No obvious inhibition on the degradation of NTMP was observed in the presence of coexisting substances in water (i.e., SO2-4, NO-3, HCO-3, and humic acid). In addition, KMnO4 also showed a high degradation efficiency on NTMP in actual wastewater, and its selectivity was better than that of free radical systems. The results provide an important reference for the efficient removal of phosphonates from actual wastewater.
  • loading
  • [1]
    WANG S, ZHANG B L, SHAN C, et al. Occurrence and transformation of phosphonates in textile dyeing wastewater along full-scale combined treatment processes[J].Water Research,2020,184:116173.
    [2]
    MANGHI M C, MASIOL M, CALZAVARA R, et al. The use of phosphonates in agriculture. Chemical, biological properties and legislative issues[J].Chemosphere,2021,283:131187.
    [3]
    WANG Z, CHEN G D, PATTON S, et al. Degradation of nitrilotris-methylenephosphonic acid (NTMP) antiscalant via persulfate photolysis: implications on desalination concentrate treatment[J].Water Research,2019,159:30-37.
    [4]
    ROTT E, MINKE R, STEINMETZ H, et al. Removal of phosphorus from phosphonate-loaded industrial wastewaters via precipitation/flocculation[J].Journal of Water Process Engineering,2017,17:188-196.
    [5]
    HUANG N, XU Z B, WANG W L, et al. Ozonation of phosphonate antiscalant l-hydroxyethane-1,1-diphosphonic acid in reverse osmosis concentrate: kinetics, phosphorus transformation, and anti-precipitation property changes[J].Separation and Purification Technology,2022,297:121385.
    [6]
    WANG X X, ZHANG T Y, DAO G H, et al. Assessment and mechanisms of microalgae growth inhibition by phosphonates: effects of intrinsic toxicity and complexation[J].Water Research,2020,186:116333.
    [7]
    VELKI M, MEYER-ALERT H, SEILER T B, et al. Enzymatic activity and gene expression changes in zebrafish embryos and larvae exposed to pesticides diazinon and diuron[J].Aquatic Toxicology,2017,193:187-200.
    [8]
    SARAILOO M, AFSHARI S, ASGHARIAZAR V, et al. Cognitive impairment and neurodegenerative diseases development associated with organophosphate pesticides exposure: a review study[J].Neurotoxicity Research,2022,40(5):1624-1643.
    [9]
    孟秀柔,宋青梅,王飞,等.草铵膦和草甘膦在水环境中的行为和毒性效应研究进展[J].生态毒理学报,2021,16(3):144-154.
    [10]
    高瑾,熊六凤,阮记明,等.草甘膦的水环境行为及其对水生生物毒性的研究进展[J].生态毒理学报,2022,17(3):422-433.
    [11]
    刘帅,王腾,王孜晔,等.草甘膦的水生生物水质基准及其生态风险评估[J].生态毒理学报,2023,18(1):335-350.
    [12]
    王婷庭,刘敏,崔桂榕,等.五种改性纳米纤维素吸附剂的制备及除磷性能比较[J].化工进展,2017,36(11):4279-4285.
    [13]
    吕景花,袁振祥,李婉婷,等.混凝沉淀法处理含油清洗废水中磷的实验研究[J].工业水处理,2019,39(5):37-41.
    [14]
    胡昊,潘顺龙,聂溪,等.CoFe2O4的制备及其对有机膦酸的去除性能研究[J].环境科学学报,2022,42(8):156-165.
    [15]
    刘丽娅,刘丹丹,莫华荣,等.城镇污水生物脱氮除磷研究进展[J].净水技术,2023,42(3):49-59.
    [16]
    ROTT E, MINKE R, BALI U, et al. Removal of phosphonates from industrial wastewater with UV/FeⅡ, fenton and UV/Fenton treatment[J].Water Research,2017,122:345-354.
    [17]
    XU Z B, WANG W L, HUANG N, et al. 2-Phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) degradation by ozonation: kinetics, phosphorus transformation, anti-precipitation property changes and phosphorus removal[J].Water Research,2019,148:334-343.
    [18]
    MUTKE X A M, TAVICHAIYUTH K, DREES F, et al. Oxidation of the nitrogen-free phosphonate antiscalants HEDP and PBTC in reverse osmosis concentrates: reaction kinetics and degradation rate[J].Water Research,2023,233:119571.
    [19]
    SUN S H, SHAN C, YANG Z C, et al. Self-enhanced selective oxidation of phosphonate into phosphate by Cu(Ⅱ)/H2O2: performance, mechanism, and validation[J].Environmental Science and Technology,2022,56(1):634-641.
    [20]
    ZHU J L, WANG S, LI H C, et al. Degradation of phosphonates in Co(Ⅱ)/peroxymonosulfate process: performance and mechanism[J].Water Research,2021,202:117397.
    [21]
    陈菊香,代彩琼.强化高锰酸钾氧化技术去除铜绿微囊藻的研究进展[J].广东化工,2022,49(14):67-68.
    [22]
    CAO W M, WU N N, QU R J, et al. Oxidation of benzophenone-3 in aqueous solution by potassium permanganate: kinetics, degradation products, reaction pathways, and toxicity assessment[J].Environmental Science and Pollution Research,2021,28(24):31301-31311.
    [23]
    柯水洲,章彩霞,袁辉洲.高锰酸钾去除水中甲硫醚的效能及动力学研究[J].安全与环境学报,2017,17(3):1099-1105.
    [24]
    ZHUANG J G, WANG S Y, TAN Y, et al. Degradation of sulfadimethoxine by permanganate in aquatic environment: influence factors, intermediate products and theoretical study[J].Science of The Total Environment,2019,671:705-713.
    [25]
    CHEN J, QU R J, PAN X X, et al. Oxidative degradation of triclosan by potassium permanganate: kinetics, degradation products, reaction mechanism, and toxicity evaluation[J].Water Research,2016,103:215-223.
    [26]
    XU K, BEN W W, LING W C, et al. Impact of humic acid on the degradation of levofloxacin by aqueous permanganate: kinetics and mechanism[J].Water Research,2017,123:67-74.
    [27]
    CAO W M, YU Y, WEI J Y, et al. KMnO4-mediated reactions for hexachlorophene in aqueous solutions: direct oxidation, self-coupling, and cross-coupling[J].Chemosphere,2020,259:127422.
    [28]
    PENG J L, ZHOU P, ZHOU H Y, et al. Insights into the electron-transfer mechanism of permanganate activation by graphite for enhanced oxidation of sulfamethoxazole[J].Environmental Science & Technology,2021,55(13):9189-9198.
    [29]
    WANG L H, JIANG J, PANG S Y, et al. Oxidation of bisphenol A by nonradical activation of peroxymonosulfate in the presence of amorphous manganese dioxide[J].Chemical Engineering Journal,2018,352:1004-1013.
    [30]
    WANG L H, JIANG J, PANG S Y, et al. Further insights into the combination of permanganate and peroxymonosulfate as an advanced oxidation process for destruction of aqueous organic contaminants[J].Chemosphere,2019,228:602-610.
    [31]
    LI H C, YUAN N, QIAN J S, et al. Mn2O3 as an electron shuttle between peroxymonosulfate and organic pollutants: the dominant role of surface reactive Mn(Ⅳ) species[J].Environmental Science & Technology,2022,56(7):4498-4506.
    [32]
    张静,张宏龙,王定祥,等.强化高锰酸钾氧化体系中自由基的产生与利用研究进展[J].环境化学,2021,40(2):487-496.
    [33]
    TAYLOR J E, GREEN R et al. Permanganate peroxidation of cyclohexene. Ⅲ. Hydroxide ion and salt effect studies[J].Canadian Journal of Chemistry,1985,62(10):3777-3780.
    [34]
    XIE Y W, XU R Y, LI R, et al. Adsorbable organic halogens formed during treatment of Cl--containing wastewater by sulfate and hydroxyl radical-based advanced oxidation processes[J].Chemical Engineering Journal,2020,389:124457.
    [35]
    颉亚玮,徐冉云,丁伟,等.含氯离子苯酚废水高级氧化过程AOX生成研究[J].环境工程,2022,40(5):1-8.
    [36]
    杨庆云,李青松,陈泽铭,等.UV/PMS、UV/PDS、UV/SPC工艺降解尼泊金甲酯[J].化工学报,2023,74(3):1322-1331.
    [37]
    GU D M, GUO C S, FENG Q Y, et al. Degradation of ketamine and methamphetamine by the UV/H2O2 system: kinetics, mechanisms and comparison[J].Water,2020,12(11):2999.
    [38]
    杜振齐,王永磊,田立平,等.UV/H2O2工艺降解饮用水中有机微污染物研究进展[J].山东建筑大学学报,2019,34(4):50-57.
    [39]
    许芬,张如锋,沈芷璇,等.UV/H2O2降解美罗培南的影响因素及毒性研究[J].环境科学学报,2019,39(12):4031-4038.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (60) PDF downloads(4) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return