DEGRADATION OF BUTYLPARABEN IN WATER BY ACTIVATION OF HYDROGEN PEROXIDE BY MIL-100(Fe,Mn) DERIVATIVES

YUAN Yujie; LIN Tao

doi:10.13205/j.hjgc.202405005

Volume 42 Issue 5

May 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(5): 35-41

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YUAN Yujie, LIN Tao. DEGRADATION OF BUTYLPARABEN IN WATER BY ACTIVATION OF HYDROGEN PEROXIDE BY MIL-100(Fe,Mn) DERIVATIVES[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(5): 35-41. doi: 10.13205/j.hjgc.202405005

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DEGRADATION OF BUTYLPARABEN IN WATER BY ACTIVATION OF HYDROGEN PEROXIDE BY MIL-100(Fe,Mn) DERIVATIVES

doi: 10.13205/j.hjgc.202405005

YUAN Yujie,
LIN Tao^,

College of Environment, Hohai University, Nanjing 210098, China

Received Date: 2024-04-24
Available Online: 2024-07-11

Abstract

Abstract

The MIL-100 (Fe, Mn) derivative catalyst, with new established active sites and regulated structure, was synthesized by hydrothermal method and calcination method to activate H₂O₂ for the removal of the typical new pharmaceutical pollutants, butylparaben (BPB) in water. The effects of catalyst dosage and water environmental chemical conditions (such as initial pH, reaction temperature, co-existing ions, etc.) on the degradation of BPB in water by MIL-100 (Fe, Mn) derivatives were detailly investigated, and the active species in the reaction system were also analyzed. The results showed that the MIL-100 (Fe, Mn) derivative catalytic system showed good catalytic performance in a wide range of pH and solution temperature, and increasing the catalyst dosage was conducive to the activation of H₂O₂ oxidation of BPB in water. Preferably, 96% of BPB could be oxidized within 15 min by the MIL-100 (Fe, Mn) derivative catalytic system under the conditions of pH=7.0, 298 K (25 ℃), 0.2 g/L catalyst and 1 mmol/L H₂O₂. In addition, the introduction of HCO₃^- in the reaction system significantly inhibited the degradation of BPB, but different concentration of NO₃^- and Cl^- had little effect on the degradation of BPB in water. The synergistic interaction between Fe/Mn metal ions on the surface of MIL-100 (Fe, Mn) derivative catalyst could promote the decomposition of H₂O₂ to generate ·OH, and then rapidly oxidize BPB in water.
- MOFs,
- heterogeneous catalytic oxidation,
- H₂O₂,
- butylparaben (BPB),
- metal oxide

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References

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