Source Journal of CSCD
Source Journal for Chinese Scientific and Technical Papers
Core Journal of RCCSE
Included in JST China
Volume 42 Issue 6
Jun.  2024
Turn off MathJax
Article Contents
YANG Zhixuan, LI Lanqing, LIU Huanjia, YANG Ying, XU Mengyuan, JIA Mengke, LIU Hengzhi. SEASONAL VARIATION, SOURCE AND LIGHT EXTINCTION CONTRIBUTION OF WATER-SOLUBLE INORGANIC IONS OF PM2.5 IN THE NORTHERN SUBURB OF ANYANG, CHINA[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(6): 71-81. doi: 10.13205/j.hjgc.202406009
Citation: YANG Zhixuan, LI Lanqing, LIU Huanjia, YANG Ying, XU Mengyuan, JIA Mengke, LIU Hengzhi. SEASONAL VARIATION, SOURCE AND LIGHT EXTINCTION CONTRIBUTION OF WATER-SOLUBLE INORGANIC IONS OF PM2.5 IN THE NORTHERN SUBURB OF ANYANG, CHINA[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(6): 71-81. doi: 10.13205/j.hjgc.202406009

SEASONAL VARIATION, SOURCE AND LIGHT EXTINCTION CONTRIBUTION OF WATER-SOLUBLE INORGANIC IONS OF PM2.5 IN THE NORTHERN SUBURB OF ANYANG, CHINA

doi: 10.13205/j.hjgc.202406009
  • Received Date: 2023-07-04
    Available Online: 2024-07-11
  • Seasonal variation, source characteristics as well as light extinction contribution of water-soluble inorganic ions (WSIIs) in PM2.5 were explored in the northern suburb of Anyang. Gaseous pollutants, PM2.5 samples, and their chemical components were online monitored from March 2018 to February 2019. The results showed that the annual average concentrations of PM2.5 and WSIIs were (76.68±73.00) μg/m3 and (45.60±34.17) μg/m3, respectively, which showed obvious seasonal variation with the maximum values in winter, and the minimum values in summer. NH+4 most likely existed in the form of (NH4)2SO4, NH4NO3, and NH4Cl in four seasons at the observation sites. The main sources of WSIIs were secondary nitrate, secondary sulfate, dust, and combustion source by using positive matrix factorization (PMF). Furthermore, the revised IMPROVE algorithm was used to estimate the extinction coefficient (best). The results illustrated that the extinction contribution of SNA could reach 67%. Finally, typical pollution episodes were explored in winter in this study. Continuous emission and accumulation of pollutants under unfavorable metrological conditions was the major cause of the PM2.5 pollution events at this site. Meanwhile, a rapid increase of SNA, especially SO2-4, can lead to higher PM2.5 concentrations. Hence, the control of SNA is not only conducive to the reduction of regional PM2.5 concentration, but also to improving atmospheric visibility.
  • loading
  • [1]
    ZHANG J, YUAN Q, LIU L, et al. Trans-regional transport of haze particles from the North China Plain to Yangtze River Delta during winter[J]. Journal of Geophysical Research: Atmospheres, 2021, 126(8): e2020JD033778.
    [2]
    LIAO W J, ZHOU J B, ZHU S J, et al. Characterization of aerosol chemical composition and the reconstruction of light extinction coefficients during winter in Wuhan, China[J]. Chemosphere, 2020, 241:125033.
    [3]
    XUE T, TONG M K, LI J, et al. Estimation of stillbirths attributable to ambient fine particles in 137 countries[J]. Nature Communications, 2022, 13(1): 34250-34254.
    [4]
    LIU C, CHEN R, SERA F, et al. Ambient particulate air pollution and daily mortality in 652 Cities[J]. New England Journal of Medicine, 2019, 381(8): 705-715.
    [5]
    HARMSEN M, van DORST P, van VUUREN D P, et al. Co-benefits of black carbon mitigation for climate and air quality[J]. Climatic Change, 2020, 163(3): 1519-1538.
    [6]
    LIU H J, JIA M K, TAO J, et al. Elucidating pollution characteristics, temporal variation and source origins of carbonaceous species in Xinxiang, a heavily polluted city in North China[J]. Atmospheric Environment, 2023, 298: 119626.
    [7]
    李红亮, 陶杰, 李岚清, 等. 新乡市大气PM2.5中水溶性离子污染特征及其来源解析[J]. 环境工程, 2023, 41(8): 117-126.
    [8]
    ZHAN Y ZH, XIE M, GAO D, et al. Characterization and source analysis of water-soluble inorganic ionic species in PM2.5 during a wintertime particle pollution episode in Nanjing, China[J]. Atmospheric Research, 2021, 262:105769.
    [9]
    SUN Y L, CHEN C, ZHANG Y J, et al. Rapid formation and evolution of an extreme haze episode in Northern China during winter 2015[J]. Scientific Reports, 2016, 6: 27151.
    [10]
    周变红, 冯瞧, 王锦, 等. 宝鸡市城郊冬季水溶性离子在不同等级污染天的特征及来源分析[J]. 环境化学, 2021, 40(9): 2296-2808.
    [11]
    LIU H J, TIAN H Z, ZHANG K, et al. Seasonal variation, formation mechanisms and potential sources of PM2.5 in two typical cities in the Central Plains Urban Agglomeration, China[J]. Science of the Total Environment, 2019, 657:657-670.
    [12]
    LIU J, WU D, FAN S J, et al. A one-year, on-line, multi-site observational study on water-soluble inorganic ions in PM2.5 over the Pearl River Delta region, China[J]. Science of the Total Environment, 2017, 601/602:1720-1732.
    [13]
    陈耶沙, 叶芝祥, 袁小燕, 等. 2018年成都市PM2.5中水溶性无机离子污染特征及来源解析[J]. 环境化学, 2022, 41(6): 2062-2074.
    [14]
    QIAO B Q, CHEN Y, TIAN M, et al. Characterization of water soluble inorganic ions and their evolution processes during PM2.5 pollution episodes in a small city in southwest China[J]. Science of the Total Environment, 2019, 650: 2605-2613.
    [15]
    吴丹, 蔺少龙, 杨焕强, 等. 杭州市PM2.5中水溶性离子的污染特征及其消光贡献[J]. 环境科学, 2017, 38(7): 2656-2666.
    [16]
    WU C, WU D, YU J Z. Estimation and uncertainty analysis of secondary organic carbon using 1 year of hourly organic and elemental carbon data[J]. Journal of Geophysical Research: Atmospheres, 2019, 124(5): 2774-2795.
    [17]
    DU T, WANG M, GUAN X, et al. Characteristics and formation mechanisms of winter particulate pollution in Lanzhou, Northwest China[J]. Journal of Geophysical Research: Atmospheres, 2020, 125(18): e2020JD033369.
    [18]
    TEN BRINK H, OTJES R, WEIJERS E. Extreme levels and chemistry of PM from the consumer fireworks in the Netherlands[J]. Atmospheric Environment, 2019, 212: 36-40.
    [19]
    RUMSEY I C, COWEN K A, WALKER J T, et al. An assessment of the performance of the Monitor for AeRosols and GAses in ambient air (MARGA): a semi-continuous method for soluble compounds[J]. Atmospheric Chemistry and Physics, 2014, 14(11): 5639-5658.
    [20]
    MAKKONEN U, VIRKKULA A, MÄNTYKENTTÄ J, et al. Semi-continuous gas and inorganic aerosol measurements at a Finnish urban site: comparisons with filters, nitrogen in aerosol and gas phases, and aerosol acidity[J]. Atmospheric Chemistry and Physics, 2012, 12(12): 5617-5631.
    [21]
    YANG J, LEI G, LIU C, et al. Characteristics of particulate-bound n-alkanes indicating sources of PM2.5 in Beijing, China[J]. Atmospheric Chemistry and Physics, 2023, 23(5): 3015-3029.
    [22]
    梁越, 姜红, 李弘生, 等. 中部城市秋冬季PM2.5水溶性离子的化学特征及来源[J]. 环境化学, 2022, 41(2): 470-481.
    [23]
    刘一鸣, 郑浩阳, 陈阁香, 等. 华南沿海地区夏初PM2.5水溶性离子特征及来源解析[J]. 环境科学学报, 2023, 43(1): 237-246.
    [24]
    TIAN Y Z, ZHANG Y F, LIANG Y L, et al. PM2.5 source apportionment during severe haze episodes in a Chinese megacity based on a 5-month period by using hourly species measurements: explore how to better conduct PMF during haze episodes[J]. Atmospheric Environment, 2020, 224:117364.
    [25]
    DAI Q L, LIU B S, BI X H, et al. Dispersion normalized PMF provides insights into the significant changes in source contributions to PM2.5 after the COVID-19 outbreak[J]. Environmental Science & Technology, 2020, 54(16): 9917-9927.
    [26]
    LIU J W, CHEN Y J, CHAO S H, et al. Emission control priority of PM2.5-bound heavy metals in different seasons: a comprehensive analysis from health risk perspective[J]. Science of the Total Environment, 2018, 644: 20-30.
    [27]
    程真. 长三角城市群灰霾污染与颗粒物理化性质的关系[D]. 北京:清华大学, 2013.
    [28]
    PITCHFORD M, MAIM W, SCHICHTEL B, et al. Revised algorithm for estimating light extinction from IMPROVE particle speciation data[J]. Journal of the Air & Waste Management Association, 2007, 57(11): 1326-1336.
    [29]
    WANG J J, LU X M, YAN Y T, et al. Spatiotemporal characteristics of PM2.5 concentration in the Yangtze River Delta urban agglomeration, China on the application of big data and wavelet analysis[J]. Science of the Total Environment, 2020, 724: 138134.
    [30]
    任秀龙, 牛红亚, 李淑娇, 等. 邯郸市大气细颗粒物中水溶性离子的污染特征及来源解析[J]. 环境化学, 2021, 40(11): 3510-3519.
    [31]
    ZANG L, ZHANG Y, ZHU B, et al. Characteristics of water-soluble inorganic aerosol pollution and its meteorological response in Wuhan, Central China[J]. Atmospheric Pollution Research, 2021, 12(3): 362-369.
    [32]
    BAI L, LU X, YIN S S, et al. A recent emission inventory of multiple air pollutant, PM2.5 chemical species and its spatial-temporal characteristics in central China[J]. Journal of Cleaner Production, 2020, 269:122114.
    [33]
    LIU T T, GONG S L, HE J J, et al. Attributions of meteorological and emission factors to the 2015 winter severe haze pollution episodes in China’s Jing-Jin-Ji area[J]. Atmospheric Chemistry and Physics, 2017, 17(4): 2971-2980.
    [34]
    LIU H J, JIA M K, YOU K, et al. Elucidating the chemical compositions and source apportionment of multi-size atmospheric particulate (PM10, PM2.5 and PM1) in 2019—2020 winter in Xinxiang, North China[J]. Atmosphere, 2022, 13(9): 13091400.
    [35]
    LIU T, CLEGG S L, ABBATT J P D. Fast oxidation of sulfur dioxide by hydrogen peroxide in deliquesced aerosol particles[J]. Proceedings of the Natinal Academy of Sciences of the United States of America, 2020, 117(3): 1354-1359.
    [36]
    YE C, LU K D, SONG H, et al. A critical review of sulfate aerosol formation mechanisms during winter polluted periods[J]. Journal of Environmental Sciences, 2023, 123: 387-399.
    [37]
    LIU H, WU B, LIU S, et al. A regional high-resolution emission inventory of primary air pollutants in 2012 for Beijing and the surrounding five provinces of North China[J]. Atmospheric Environment, 2018, 181: 20-33.
    [38]
    LIU L, XU W, LU X, et al. Exploring global changes in agricultural ammonia emissions and their contribution to nitrogen deposition since 1980[J]. Proceedings of the National Academy of Sciences, 2022, 119(14): e2121998119.
    [39]
    FENG S J, XU W, CHENG M M, et al. Overlooked nonagricultural and wintertime agricultural NH3 emissions in Quzhou County, North China Plain: evidence from 15N-Stable Isotopes[J]. Environmental Science & Technology Letters, 2022, 9(2): 127-133.
    [40]
    CHEN Y, ZHANG Q R, CAI X R, et al. Rapid increase in China’s industrial ammonia emissions: evidence from unit-based mapping[J]. Environmental Science & Technology, 2022, 56(6): 3375-3385.
    [41]
    GU M N, PAN Y P, WALTERS W W, et al. Vehicular emissions enhanced ammonia concentrations in winter mornings: insights from diurnal nitrogen isotopic signatures[J]. Environmental Science & Technology, 2022, 56(3): 1578-1585.
    [42]
    WANG H B, TIAN M, CHEN Y, et al. Seasonal characteristics, formation mechanisms and source origins of PM2.5 in two megacities in Sichuan Basin, China[J]. Atmospheric Chemistry and Physics, 2018, 18(2): 865-881.
    [43]
    王国祯, 任万辉, 于兴娜, 等. 沈阳市冬季大气PM2.5中水溶性离子污染特征及来源解析[J]. 环境科学, 2021, 42(1): 30-37.
    [44]
    于谨铖, 李建熹, 苏枞枞, 等. 沈阳市大气PM2.5中水溶性离子的季节变化特征[J]. 环境化学, 2021, 40(12): 3733-3742.
    [45]
    YU X N, MA J, AN J L, et al. Impacts of meteorological condition and aerosol chemical compositions on visibility impairment in Nanjing, China[J]. Journal of Cleaner Production, 2016, 131: 112-120.
    [46]
    WANG H B, SHI G M, TIAN M, et al. Aerosol optical properties and chemical composition apportionment in Sichuan Basin, China[J]. Science of the Total Environment, 2017, 577: 245-257.
    [47]
    VECCHI R, BERNARDONI V, VALENTINI S, et al. Assessment of light extinction at a European polluted urban area during wintertime: impact of PM1 composition and sources[J]. Environmental Pollution, 2018, 233: 679-689.
    [48]
    CAO J J, WANG Q Y, CHOW J C, et al. Impacts of aerosol compositions on visibility impairment in Xi’an, China[J]. Atmospheric Environment, 2012, 59: 559-566.
    [49]
    KHANNA I, KHARE M, GARGAVA P, et al. Effect of PM2.5 chemical constituents on atmospheric visibility impairment[J]. Journal of the Air & Waste Management Association, 2018, 68(5): 430-437.
    [50]
    TAN T Y, HU M, LI M R, et al. New insight into PM2.5 pollution patterns in Beijing based on one-year measurement of chemical compositions[J]. Science of the Total Environment, 2018, 621: 734-743.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (97) PDF downloads(13) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return