DEVELOPMENT AND BARRIER PERFORMANCE OF A POLYVINYLPYRROLIDONE/ HYDROXYPROPYL METHYLCELLULOSE/NANOCELLULOSE TERNARY ODOR GAS BARRIER SPRAY FILM

FU Jiahui; GUO Jie; LIU Airong; ZHOU Tao; ZHAO Youcai

doi:10.13205/j.hjgc.202412015

Volume 42 Issue 12

Dec. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(12): 116-125

FU Jiahui, GUO Jie, LIU Airong, ZHOU Tao, ZHAO Youcai. DEVELOPMENT AND BARRIER PERFORMANCE OF A POLYVINYLPYRROLIDONE/ HYDROXYPROPYL METHYLCELLULOSE/NANOCELLULOSE TERNARY ODOR GAS BARRIER SPRAY FILM[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 116-125. doi: 10.13205/j.hjgc.202412015

Citation:

FU Jiahui, GUO Jie, LIU Airong, ZHOU Tao, ZHAO Youcai. DEVELOPMENT AND BARRIER PERFORMANCE OF A POLYVINYLPYRROLIDONE/ HYDROXYPROPYL METHYLCELLULOSE/NANOCELLULOSE TERNARY ODOR GAS BARRIER SPRAY FILM[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 116-125. doi: 10.13205/j.hjgc.202412015

Citation:

FU Jiahui, GUO Jie, LIU Airong, ZHOU Tao, ZHAO Youcai. DEVELOPMENT AND BARRIER PERFORMANCE OF A POLYVINYLPYRROLIDONE/ HYDROXYPROPYL METHYLCELLULOSE/NANOCELLULOSE TERNARY ODOR GAS BARRIER SPRAY FILM[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 116-125. doi: 10.13205/j.hjgc.202412015

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DEVELOPMENT AND BARRIER PERFORMANCE OF A POLYVINYLPYRROLIDONE/ HYDROXYPROPYL METHYLCELLULOSE/NANOCELLULOSE TERNARY ODOR GAS BARRIER SPRAY FILM

doi: 10.13205/j.hjgc.202412015

FU Jiahui^1,2,
GUO Jie^1,2,
LIU Airong^{1,2
,
,},
ZHOU Tao^1,2,
ZHAO Youcai^1,2

1. College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China;
2. State Key Laboratory for Pollution Control and Resource Reuse, Shanghai 200092, China

Received Date: 2023-10-09
Available Online: 2025-01-18

Abstract

Abstract

Gases with bad odor are produced during the landfill treatment process, and with a large production, long lifetime, and broad impact range. Among them, hydrogen sulfide and ammonia are the typical pungent gases released by landfills for municipal solid waste. To deal with odorous gases, this article used a polymer blend based on polyvinylpyrrolidone (PVP), hydroxypropyl methylcellulose (HPMC), cellulose nanofiber (CNF), and cellulose nanocrystal (CNC) as the membrane substrates. There is a strong intermolecular hydrogen bond between the carbonyl group of polyvinylpyrrolidone and the free hydroxyl group of hydroxypropyl methylcellulose, forming a miscible blend throughout the entire composition range with good compatibility. The polymer mixed solution was sprayed into a film, and a simulated upflow reactor was used to isolate hydrogen sulfide and ammonia gas. Single-factor experiments were conducted, response surface analysis was designed, and the optimal composite membrane liquid ratio was obtained as follows: 4.20% PVP, 1.20% HPMC, 0.40% CNF, and 0.06% CNC. A plasticizer of 1.5% glycerol, a surfactant of 1.0% Tween 80, a fly repellent and deodorant of 3.0% limonene, and a fragrance of 0.5% tea tree essential oil were added to optimize the comprehensive performance of the composite membrane. The retention rate of H₂S and NH₃ in the composite membrane can be guaranteed to be 95% above in 30 minutes.
- odorous gas,
- deodorization composite membrane,
- orthogonal experiment,
- gas retention rate,
- optimize preparation

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References(49)

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