ADSORPTION PERFORMANCE AND MECHANISM OF SULFAMETHOXAZOLE BY ACID/ALKALI MODIFIED <i>CANNA INDICA</i> BIOCHARS

XIE Wei; YUAN Jiajia; YUAN Huizhou; KE Shuizhou

doi:10.13205/j.hjgc.202412024

Volume 42 Issue 12

Dec. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(12): 201-209

XIE Wei, YUAN Jiajia, YUAN Huizhou, KE Shuizhou. ADSORPTION PERFORMANCE AND MECHANISM OF SULFAMETHOXAZOLE BY ACID/ALKALI MODIFIED CANNA INDICA BIOCHARS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 201-209. doi: 10.13205/j.hjgc.202412024

Citation:

XIE Wei, YUAN Jiajia, YUAN Huizhou, KE Shuizhou. ADSORPTION PERFORMANCE AND MECHANISM OF SULFAMETHOXAZOLE BY ACID/ALKALI MODIFIED CANNA INDICA BIOCHARS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 201-209. doi: 10.13205/j.hjgc.202412024

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ADSORPTION PERFORMANCE AND MECHANISM OF SULFAMETHOXAZOLE BY ACID/ALKALI MODIFIED CANNA INDICA BIOCHARS

doi: 10.13205/j.hjgc.202412024

1. College of Civil Engineering, Hunan University, Changsha 410000, China;
2. School of Materials and Environmental Engineering, Shenzhen Polytechnic University, Shenzhen 518000, China

Received Date: 2023-12-26
Available Online: 2025-01-18

Abstract

Abstract

In this paper, biochar was prepared by pyrolysis with Canna indica as raw material, and then modified with HNO₃ and KOH, respectively. The structures and properties of the biochar were characterized by using scanning electron microscopy (SEM), specific surface area and porosity analyzer (SSAP), and Fourier transform infrared spectroscopy (FTIR). The adsorption performance and mechanism of sulfamethoxazole (SMX) by biochars were investigated, and the effects of pH and biochar dosage on the adsorption of SMX were investigated as well. The results showed that compared with the unmodified biochar, the specific surface area of acid/alkali modified biochar was greatly increased, the pore structure was deeply developed, and the adsorption performance was significantly improved. The adsorption process of SMX by the biochar follows the pseudo-second-order kinetics model; the Langmuir model can describe the adsorption isotherm of SMX onto acid-modified biochar better, but adsorption process one the unmodified and alkali modified biochar fit better with the Freundlich model. The adsorption process of SMX by the biochar was endothermic and spontaneous. pH and the dosage of biochar added has a significant effect on the adsorption of SMX by the biochar. The adsorption process was jointly influenced by pore filling, hydrogen bonding, π-π EDA, and electrostatic interactions.
- Canna indica,
- biochar,
- sulfamethoxazole,
- acid/alkali modified,
- adsorption mechanism

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References

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